IP Library Granted Patent US 11,649,459
Granted Patent B2
US 11,649,459 · App. 17/852,554 · Granted May 16, 2023

Superoxide dismutase 1 (SOD1) iRNA compositions and methods of use thereof for treating or preventing superoxide dismutase 1-(SOD1-) associated neurodegenerative diseases

Inventors: Adam Castoreno (Framingham, MA); Jason Gilbert (Hingham, MA); Charalambos Kaittanis (Cambridge, MA); James D. McIninch (Burlington, MA); Stuart Milstein (Arlington, MA); Mark K. Schlegel (Boston, MA)
Assignee: Alnylam Pharmaceuticals, Inc.
C12N15/1137A61P25/00C12N9/0089C12N2310/111C12N2310/14C12N2310/53C12N2320/31C12Y115/01001
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Quick Facts
Patent No.
US 11,649,459
App. No.
17/852,554
Granted
May 16, 2023
Kind
B2
Abstract

The disclosure relates to double stranded ribonucleic acid (dsRNAi) agents and compositions targeting a SOD1 gene, as well as methods of inhibiting expression of a SOD1 gene and methods of treating subjects having a SOD1-associated neurodegenerative disease or disorder, e.g., Amyotrophic Lateral Sclerosis (ALS), Alzheimer's disease (AD), Parkinson's disease (PD), and Down's syndrome (DS), using such dsRNAi agents and compositions.

Claims (76)

1. A double stranded ribonucleic acid (dsRNA) agent, or a pharmaceutically acceptable salt thereof, comprising a sense strand and an antisense strand forming a double stranded region, wherein the nucleotide sequence of the antisense strand differs by no more than three bases from the nucleotide sequence,

(SEQ ID NO: 1369)

5′-VPusdCsugdGadTagagdGaUfuaaagugsa-3′,

wherein

VP is a 5′-vinyl phosphonate;

s is a phosphorothioate linkage;

a, g, and u are 2′-O-methyl (2′-OMe) A, G, and U;

dC, dG, and dT are 2′-deoxy C, G, and T; and

Uf is 2′-deoxy-2′-fluoro (2′-F) U.

2. The dsRNA agent, or pharmaceutically acceptable salt thereof, of claim 1 , wherein the nucleotide sequence of the antisense strand differs by no more than two bases from the nucleotide sequence

(SEQ ID NO: 1369)

5′-VPusdCsugdGadTagagdGaUfuaaagugsa-3′.

3. The dsRNA agent, or pharmaceutically acceptable salt thereof, of claim 1 , wherein the nucleotide sequence of the antisense strand differs by no more than one base from the nucleotide sequence

(SEQ ID NO: 1369)

5′-VPusdCsugdGadTagagdGaUfuaaagugsa-3′.

4. The dsRNA agent, or pharmaceutically acceptable salt thereof, of claim 1 , wherein the nucleotide sequence of the antisense strand comprises the nucleotide sequence

(SEQ ID NO: 1369)

5′-VPusdCsugdGadTagagdGaUfuaaagugsa-3′.

5. The dsRNA agent, or pharmaceutically acceptable salt thereof, of claim 1 , wherein the antisense strand comprises the nucleotide sequence 5′-VPusdCsugdGadTagagdGaUfuaaagugsasg-3′ (SEQ ID NO:12).

6. The dsRNA agent, or pharmaceutically acceptable salt thereof, of claim 1 , wherein the sense strand comprises the nucleotide sequence,

(SEQ ID NO: 11)

5′-csascuu(Uhd)aaUfCfCfucuauccasgsa-3′

wherein

(Uhd) is 2′-O-hexadecyl-uridine-3′-phosphate;

c is 2′-O-methyl (2′-OMe) C; and

Cf is 2′-deoxy-2′-fluoro (2′-F) C.

7. The dsRNA agent of claim 6 , that is a sodium salt.

8. A double stranded ribonucleic acid (dsRNA) agent, or a pharmaceutically acceptable salt thereof, comprising a sense strand and an antisense strand forming a double stranded region, wherein the antisense strand comprises the nucleotide sequence,

(SEQ ID NO: 12)

5′-VPusdCsugdGadTagagdGaUfuaaagugsasg-3′.

9. The dsRNA agent of claim 8 , or a pharmaceutically acceptable salt thereof, wherein the sense strand comprises the nucleotide sequence,

(SEQ ID NO: 11)

5′-csascuu(Uhd)aaUfCfCfucuauccasgsa-3′ 

wherein

(Uhd) is 2′-O-hexadecyl-uridine-3′-phosphate;

c is 2′-O-methyl (2′-OMe) C; and

Cf is 2′-deoxy-2′-fluoro (2′-F) C.

10. The dsRNA agent of claim 9 , that is a sodium salt.

11. A double stranded ribonucleic acid (dsRNA) agent, or a pharmaceutically acceptable salt thereof, comprising a sense strand and an antisense strand forming a double stranded region, wherein the sense strand consists of the nucleotide sequence,

(SEQ ID NO: 11)

5′-csascuu(Uhd)aaUfCfCfucuauccasgsa-3′ 

and the antisense strand consists of the nucleotide sequence,

(SEQ ID NO: 12)

5′-VPusdCsugdGadTagagdGaUfuaaagugsasg-3′,

wherein

VP is a 5′-E-vinyl phosphonate;

s is a phosphorothioate linkage;

(Uhd) is 2′-O-hexadecyl-uridine-3′-phosphate;

a, c, g, and u are 2′-O-methyl (2′-OMe) A, C, G, and U;

dC, dG, and dT are 2′-deoxy C, G, and T; and

Cf and Uf are 2′-deoxy-2′-fluoro (2′-F) C and U.

12. The dsRNA agent of claim 11 , that is a sodium salt.

13. A pharmaceutical composition comprising the dsRNA agent of claim 11 and a pharmaceutically acceptable diluent.

14. The pharmaceutical composition of claim 13 , that is a sterile aqueous solution.

15. The pharmaceutical composition of claim 14 , comprising a buffer.

16. The pharmaceutical composition of claim 14 , wherein the diluent is saline or water.

17. A pharmaceutical composition comprising the dsRNA agent of claim 1 and a pharmaceutically acceptable diluent.

18. A pharmaceutical composition comprising the dsRNA agent of claim 8 and a pharmaceutically acceptable diluent.

19. A method of inhibiting expression of a SOD1 gene in a cell, the method comprising:

(a) contacting the cell with the dsRNA agent of claim 1 ; and

(b) maintaining the cell produced in step (a) for a time sufficient to obtain degradation of the mRNA transcript of the SOD1 gene, thereby inhibiting expression of the SOD1 gene in the cell.

20. A method of inhibiting expression of a SOD1 gene in a cell, the method comprising:

(a) contacting the cell with the dsRNA agent of claim 8 ; and

(b) maintaining the cell produced in step (a) for a time sufficient to obtain degradation of the mRNA transcript of the SOD1 gene, thereby inhibiting expression of the SOD1 gene in the cell.

21. A method of inhibiting expression of a SOD1 gene in a cell, the method comprising:

(a) contacting the cell with the dsRNA agent of claim 11 ; and

(b) maintaining the cell produced in step (a) for a time sufficient to obtain degradation of the mRNA transcript of the SOD1 gene, thereby inhibiting expression of the SOD1 gene in the cell.

22. A method for treating a SOD1-associated neurodegenerative disease, comprising administering to a patient in need thereof, a pharmaceutically effective amount of a dsRNA agent of claim 1 .

23. The method of claim 22 , wherein the SOD1-associated neurodegenerative disease is selected from the group consisting of Amyotrophic Lateral Sclerosis (ALS), Alzheimer's disease (AD), Parkinson's disease (PD), and Down's syndrome (DS).

24. The method of claim 23 , wherein the SOD1-associated neurodegenerative disease is inherited familial amyotrophic lateral sclerosis (fALS).

25. A method for treating a SOD1-associated neurodegenerative disease, comprising administering to a patient in need thereof, a pharmaceutically effective amount of a dsRNA agent of claim 8 .

26. The method of claim 25 , wherein the SOD1-associated neurodegenerative disease is selected from the group consisting of Amyotrophic Lateral Sclerosis (ALS), Alzheimer's disease (AD), Parkinson's disease (PD), and Down's syndrome (DS).

27. The method of claim 26 , wherein the SOD1-associated neurodegenerative disease is inherited familial amyotrophic lateral sclerosis (fALS).

28. A method for treating a SOD1-associated neurodegenerative disease, comprising administering to a patient in need thereof, a pharmaceutically effective amount of a dsRNA agent of claim 11 .

29. The method of claim 28 , wherein the SOD1-associated neurodegenerative disease is selected from the group consisting of Amyotrophic Lateral Sclerosis (ALS), Alzheimer's disease (AD), Parkinson's disease (PD), and Down's syndrome (DS).

30. The method of claim 29 , wherein the SOD1-associated neurodegenerative disease is inherited familial amyotrophic lateral sclerosis (fALS).

Assignments (2)
SECURITY INTEREST Recorded Oct 1, 2025
From: ALNYLAM PHARMACEUTICALS, INC.; SIRNA THERAPEUTICS, INC.
To: BANK OF AMERICA, N.A.
Reel/Frame 072996/0337 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 14, 2022
From: CASTORENO, ADAM; GILBERT, JASON; KAITTANIS, CHARALAMBOS; MCININCH, JAMES D.; MILSTEIN, STUART; SCHLEGEL, MARK
To: ALNYLAM PHARMACEUTICALS, INC.
Reel/Frame 060505/0780 →
Continuity (4)
Continuation PCTUS2022016046 · Feb 11, 2022
Provisional Application 63270176 · Oct 21, 2021
Provisional Application 63148991 · Feb 12, 2021
Related Publication 20220356478A1 · Nov 10, 2022