Secondary battery, preparation method thereof, and battery module, battery pack, and apparatus associated therewith
A secondary battery, a preparation method thereof, and an apparatus including the secondary battery are described. Specifically, the secondary battery includes a negative-electrode plate, where the negative-electrode plate is of a multi-layer structure, and the multi-layer structure sequentially includes: a negative-electrode current collector, a primer layer, and a negative-electrode film layer; the negative-electrode film layer includes a first negative-electrode film layer and a second negative-electrode film layer, and the first negative-electrode film layer is located between the primer layer and the second negative-electrode film layer; and the first negative-electrode film layer includes a first negative-electrode active material, the first negative-electrode active material includes first artificial graphite, at least some particles in the first artificial graphite are secondary particles, and a quantity proportion A of the number of the secondary particles to a total number of particles of the first negative-electrode active material satisfies A≥50%.
1. A secondary battery, comprising a negative-electrode plate, wherein the negative-electrode plate is of a multi-layer structure, and the multi-layer structure sequentially comprises: a negative-electrode current collector, a primer layer, and a negative-electrode film layer;
the negative-electrode film layer comprises a first negative-electrode film layer and a second negative-electrode film layer, and the first negative-electrode film layer is located between the primer layer and the second negative-electrode film layer; and
the first negative-electrode film layer comprises a first negative-electrode active material, wherein the first negative-electrode active material comprises first artificial graphite, at least some particles in the first artificial graphite are secondary particles, and a quantity proportion A of the number of the secondary particles to a total number of particles of the first negative-electrode active material satisfies A≥50%.
2. The secondary battery according to claim 1 , wherein the primer layer comprises a conductive agent and a binder.
3. The secondary battery according to claim 1 , wherein A≥60%.
4. The secondary battery according to claim 1 , wherein a thickness of the primer layer is greater than or equal to 1 μm.
5. The secondary battery according to claim 2 , wherein a mass proportion of the conductive agent in the primer layer is greater than or equal to 50%; or
a mass proportion of the binder in the primer layer is less than or equal to 50%.
6. The secondary battery according to claim 2 , wherein the conductive agent comprises a conductive carbon material.
7. The secondary battery according to claim 2 , wherein the binder comprises one or more of styrene butadiene rubber (SBR), polyvinylidene fluoride (PVDF), a copolymer of vinylidene fluoride, polystyrene, polyacrylic acid, polytetrafluoroethylene, polyacrylonitrile, polyimide, polyurethane, polyvinyl alcohol, polyvinyl butyral (PVB), polyacrylate, acrylic acid-acrylonitrile copolymer, ethylene-vinyl acetate copolymer (EVA), acrylate-acrylonitrile copolymer, and modified compounds thereof.
8. The secondary battery according to claim 1 , wherein the first negative-electrode active material further comprises natural graphite.
9. The secondary battery according to claim 1 , wherein the first negative-electrode active material further satisfies one or more of the following conditions:
a volume-based median particle size D v 50 of the first negative-electrode active material satisfies D v 50≥15 μm;
particle size uniformity of the first negative-electrode active material is 0.20-0.60;
a specific surface area SSA of the first negative-electrode active material satisfies SSA≤1.6 m 2 /g;
a particle size distribution of the first negative-electrode active material is 0.6≤(D v 90−D v 10)/D v 50≤3.5;
a powder OI value of the first negative-electrode active material is less than or equal to 8.5; and
a gram capacity of the first negative-electrode active material is greater than or equal to 352 mAh/g.
10. The secondary battery according to claim 1 , wherein a second negative-electrode active material comprises second artificial graphite.
11. The secondary battery according to claim 10 , wherein at least some particles in the second artificial graphite are secondary particles, and a quantity proportion B of the number of the secondary particles to a total number of particles of the second negative-electrode active material satisfies B 60%.
12. The secondary battery according to claim 1 , wherein the second negative-electrode active material further satisfies one or more of the following conditions:
a volume-based median particle size D v 50 of the second negative-electrode active material satisfies 7 μm≤D v 50≤15 μm;
particle size uniformity of the second negative-electrode active material is 0.20-0.50;
a specific surface area SSA of the second negative-electrode active material satisfies SSA≤1.6 m 2 /g;
a particle size distribution of the second negative-electrode active material is 0.5≤(D v 90−D v 10)/D v 50≤3.0;
a powder OI value of the second negative-electrode active material is less than or equal to 6; and
a gram capacity of the second negative-electrode active material is greater than or equal to 345 mAh/g.
13. The secondary battery according to claim 1 , wherein the secondary battery further satisfies includes one or more of the following conditions:
a ratio of the particle size uniformity of the second negative-electrode active material to the particle size uniformity of the first negative-electrode active material is 0.6-2;
the volume-based median particle size D v 50 of the second negative-electrode active material is less than the volume-based median particle size D v 50 of the first negative-electrode active material;
a surface density of the negative-electrode film layer is greater than or equal to 0.117 m g/mm 2 , and optionally, 0.119-0.130 mg/mm 2 ;
a press density of the negative-electrode film layer is 1.4-1.75 g/cm 3 , and optionally, 1.65-1.75 g/cm 3 ;
a thickness ratio of the second negative-electrode film layer to the first negative-electrode film layer is 1:1-3:2; and
a ratio of the OI value of the second negative-electrode active material to the first negative-electrode active material is less than or equal to 1.2.
14. A method for preparing the secondary battery according to claim 1 , comprising at least the following steps of:
providing a primer layer on at least one side of a negative-electrode current collector;
providing a first negative-electrode film layer on the primer layer; and
providing a second negative-electrode film layer on the first negative-electrode film layer; wherein
the secondary battery comprises a negative-electrode plate, the negative-electrode plate is of a multi-layer structure, and the multi-layer structure sequentially comprises: a negative-electrode current collector, a primer layer, and a negative-electrode film layer; the negative-electrode film layer comprises the first negative-electrode film layer and the second negative-electrode film layer, and the first negative-electrode film layer is located between the primer layer and the second negative-electrode film layer; and
the first negative-electrode film layer comprises a first negative-electrode active material, wherein the first negative-electrode active material comprises first artificial graphite, at least some particles in the first artificial graphite are secondary particles, and a quantity proportion A of the number of the secondary particles to a total number of particles of the first negative-electrode active material satisfies A≥50%.
15. An apparatus comprising at least one of a secondary battery according to claim 1 .
16. An apparatus comprising a secondary battery prepared by the method according to claim 14 .