Method for producing copper carboxylate, a wood preservative composition comprising copper carboxylate, and a wood product produced therefrom
A method for producing copper carboxylate, a wood preservative composition comprising copper carboxylate, and a wood product produced therefrom are provided. The method comprises combining a hydrocarbon solvent, a copper compound, and carboxylic acid and contacting the copper compound with the carboxylic acid in the presence of the hydrocarbon solvent to form a reaction product comprising copper carboxylate.
1. A method for producing copper carboxylate, the method comprising:
combining a hydrocarbon solvent and a copper compound to form an intermediate mixture, wherein the hydrocarbon solvent comprises a flash point in a range of 58 degrees Celsius to 140 degrees Celsius;
heating a carboxylic acid having at least 8 carbon atoms to a temperature of at least 30 degrees Celsius to form a heated carboxylic acid; and
combining the intermediate mixture and the heated carboxylic acid to form a reaction product comprising
copper carboxylate, wherein an elemental copper concentration is in a range of 2 percent to 12 percent based on a total weight of the reaction product; and
at least 20 percent by weight hydrocarbon solvent based on the total weight of the reaction product.
2. The method of claim 1 , wherein the carboxylic acid comprises at least one of
a formula of R—COOH or R—CO 2 H, where R is an alkyl group, an alkenyl group, or an aryl group; or
a formula of C n H 2n-z O 2 , where Z is 0, 2, 4, 6, or 8 and n is in a range of 8 to 20.
3. The method of claim 1 , wherein the carboxylic acid is derived from petroleum.
4. The method of claim 1 , wherein the carboxylic acid comprises an acid value in a range of 100 mg*KOH/g to 455 mg*KOH/g, a molecular weight in a range of 120 grams per mole to 700 grams per mole, a water content of less than 0.5 percent by total weight of the carboxylic acid, and a viscosity at 70 degrees Celsius in a range of 50 cP to 1500 cP.
5. The method of claim 1 , wherein the carboxylic acid is naphthenic acid.
6. The method of claim 1 , wherein the intermediate mixture is at a temperature in a range of 55 degrees Celsius to 90 degrees Celsius prior to combining with the heated carboxylic acid.
7. The method of claim 1 , wherein the combining the intermediate mixture and the heated carboxylic acid forms a mixture with a viscosity of no greater than 2,500 cP at 25 degrees Celsius.
8. The method of claim 1 further comprising introducing a defoamer, a demulsifying agent, a biocide, or a combination thereof.
9. The method of claim 1 , wherein the hydrocarbon solvent comprises diesel, fuel oil, pole-treating oil, a creosote-petroleum mixture, or a combination thereof.
10. The method of claim 1 , wherein an elemental copper percentage in the copper compound is in a range of 55 percent to 65 percent by total weight of the copper compound.
11. The method of claim 1 , wherein the copper compound comprises copper metal, copper (I) oxide, copper (II) oxide, copper hydroxide, copper carbonate, basic copper carbonate, copper oxychloride, or a combination thereof.
12. The method of claim 1 , wherein a mean average particle size of the copper compound is in a range of 0.05 um to 500 um.
13. The method of claim 1 , wherein a yield of the copper carboxylate is at least 90 percent.
14. The method of claim 1 , wherein the copper carboxylate comprises copper naphthenate.
15. The method of claim 1 , wherein the carboxylic acid is heated to a temperature in a range of 50 degrees Celsius to 150 degrees Celsius to form the heated carboxylic acid.
16. The method of claim 1 , further comprising adding penflufen to the reaction product in a weight ratio of elemental copper: penflufen in a range of 5:1 to 250:1.
17. The method of claim 1 , wherein the hydrocarbon solvent comprises diesel and the copper compound comprises copper hydroxide.
18. The method of claim 1 , wherein the hydrocarbon solvent comprises a flash point in a range of 65 degrees Celsius to 100 degrees Celsius.
19. The method of claim 1 , wherein the hydrocarbon solvent comprises a flash point in a range of 58 degrees Celsius to 76 degrees Celsius.
20. The method of claim 19 , wherein the copper compound comprises copper hydroxide.
21. A method for producing copper naphthenate, the method comprising:
combining a hydrocarbon solvent and a copper compound to form an intermediate mixture, wherein the intermediate mixture is at a temperature in a range of 50 degrees Celsius to 125 degrees Celsius, wherein the hydrocarbon solvent comprises a flash point in a range of 58 degrees Celsius to 140 degrees Celsius;
heating naphthenic acid to a temperature in a range of 50 degrees Celsius to 150 degrees Celsius to form a heated naphthenic acid; and
combining the intermediate mixture with the heated naphthenic acid to form a reaction product comprising
copper naphthenate, wherein an elemental copper concentration is in a range of 2 percent to 12 percent based on a total weight of the reaction product; and
at least 20 percent by weight hydrocarbon solvent based on the total weight of the reaction product.
22. The method of claim 21 , wherein a weight ratio of carboxylic acid to copper compound is in a range of 3:1 to 10:1.
23. The method of claim 21 , wherein the hydrocarbon solvent comprises diesel and the copper compound comprises copper hydroxide.
24. A wood preservative composition produced by the method of claim 1 .
25. The wood preservative composition of claim 24 , further comprising penflufen.
26. A wood product produced by treating the wood product with the wood preservative composition of claim 24 .
27. The wood preservative composition of claim 25 , wherein a weight ratio of elemental copper: penflufen is in a range of 5:1 to 250:1.
28. A wood product produced by treating the wood product with the wood preservative composition of claim 25 , wherein a penflufen retention in the wood product is in a range of 0.004 kg/m 3 to 0.2 kg/m 3 and an elemental copper retention in the wood product is in a range of 0.5 kg/m 3 to 3.2 kg/m 3 .