IP Library Granted Patent US 11,565,970
Granted Patent B1
US 11,565,970 · App. 17/856,386 · Granted Jan 31, 2023

Graphene-containing roofing materials and related methods

Inventor: Ming-Liang Shiao (Basking Ridge, NJ)
Assignee: BMIC LLC
C04B20/123C04B20/1037C04B20/1059C04B20/1074C04B26/26E04D1/20C04B2103/54C04B2111/00586E04D2001/005
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Quick Facts
Patent No.
US 11,565,970
App. No.
17/856,386
Granted
Jan 31, 2023
Kind
B1
Abstract

Some embodiments of the present disclosure relate to a roofing material, wherein the roofing material may comprise a plurality of coated roofing granules, wherein each of the plurality of the coated roofing granules may comprise a roofing granule having an outer surface; and a granule coating, wherein the granule coating is disposed on at least a portion of the outer surface of the roofing granule, and wherein the granule coating comprises graphene. Some embodiments of the present disclosure relate to a roofing material, wherein the roofing material may further comprise a reflective base coating, wherein the reflective base coating is positioned between the outer surface of the roofing granule and the granule coating.

Claims (53)

1. A roofing material, comprising:

a plurality of coated roofing granules, wherein each of the plurality of coated roofing granules comprises:

a roofing granule,

wherein the roofing granule having an outer surface;

a coating,

wherein the coating disposed on at least a portion of the outer surface of the roofing granule;

wherein the coating having an outer surface; and

a graphene particle layer,

wherein the graphene particle layer is composed of a plurality of graphene particles;

wherein the graphene particle layer is disposed on at least a portion of the outer surface of the coating.

2. The roofing material of claim 1 , wherein the graphene particle layer covers 25% to 95% of the outer surface of the coating.

3. The roofing material of claim 1 , wherein the graphene particle layer is directly exposed to an environment.

4. The roofing material of claim 1 , wherein the coating comprises at least one of a metal silicate binder, a phosphate binder, a fluoropolymer coating, an acrylic coating, a polyurethane coating, a sol-gel coating, a silica coating, or any combination thereof.

5. The roofing material of claim 1 , wherein the coating comprises at least one of a latent heat reactant, a dispersing agent, a curing agent, an accelerator, a viscosity modifier, a color pigment, or any combination thereof.

6. The roofing material of claim 1 , wherein the coating comprises a polymer.

7. The roofing material of claim 1 , wherein the coating covers 25% to 100% of the outer surface of the roofing granule.

8. The roofing material of claim 1 , wherein the roofing material has a CIELAB color value comprising an L* value of 50 or less.

9. The roofing material of claim 1 , wherein the roofing material has a CIELAB color value comprising an L* value range of 0<L*<40.

10. The roofing material of claim 1 , wherein a total solar reflectance of the plurality of coated roofing granules is at least 10% greater than a roofing granule control, wherein the roofing granule control does not comprise a graphene particle layer, wherein the total solar reflectance is measured via a spectrophotometer according to ASTM E903.

11. The roofing material of claim 1 , wherein each of the plurality of coated roofing granules further comprises:

a reflective base coating,

wherein the reflective base coating is positioned between the roofing granule and the coating.

12. The roofing material of claim 11 , wherein the reflective base coating comprises at least one of a reflective pigment, a transitional metal oxide, a cool pigment, a metallic pigment, a metallic particle, a mirrored pigment, a light scattering additive, an opacifier, a thin-film coated particle, or any combination thereof.

13. A roofing shingle comprising:

a substrate;

an asphalt filled coating on the substrate; and

a plurality of coated roofing granules disposed on the asphalt filled coating, wherein each of the plurality of coated roofing granules comprises:

a roofing granule,

wherein the roofing granule having an outer surface;

a coating,

wherein the coating disposed on at least a portion of the outer surface of the roofing granule;

wherein the coating having an outer surface; and

a graphene particle layer,

wherein the graphene particle layer is composed of a plurality of graphene particles;

wherein the graphene particle layer is disposed on at least a portion of the outer surface of the coating.

14. The roofing shingle of claim 13 , wherein the graphene particle layer covers 25% to 95% of the outer surface of the coating.

15. The roofing shingle of claim 13 , wherein the graphene particle layer is directly exposed to an environment.

16. The roofing shingle of claim 13 , wherein the coating comprises at least one of a metal silicate binder, a phosphate binder, a fluoropolymer coating, an acrylic coating, a polyurethane coating, a sol-gel coating, a silica coating, or any combination thereof.

17. The roofing shingle of claim 13 , wherein the roofing shingle having a CIELAB color value comprising an L* value range of 0<L*<40.

18. The roofing shingle of claim 13 , wherein a total solar reflectance of the roofing shingle is at least 10% greater than a roofing shingle control, wherein the roofing shingle control does not comprise a graphene particle layer, wherein the total solar reflectance is measured via a spectrophotometer according to ASTM E903.

19. The roofing shingle of claim 13 , wherein each of the plurality of coated roofing granules further comprises:

a reflective base coating,

wherein the reflective base coating is positioned between the outer surface of the roofing granule and the coating.

20. A method comprising:

obtaining a plurality of roofing granules;

obtaining a coating material;

obtaining a graphene composition,

wherein the graphene composition comprises a plurality of graphene particles;

applying the coating material to the plurality of roofing granules so as to form a plurality of coated roofing granules,

wherein the coating disposed on at least a portion of an outer surface of each of the plurality of roofing granules;

applying the graphene composition to the plurality of coated roofing granules such that a graphene particle layer covers at least a portion of an outer surface of the coating disposed on each the plurality of coated roofing granules,

wherein the graphene particle layer is composed of a plurality of graphene particles; and

heating the plurality of coated roofing granules to a first temperature.

Continuity (1)
Provisional Application 63217623 · Jul 1, 2021
Cited By (3)
US 12,305,396 US 12,365,627 US 12,486,614