Separator, electrical apparatus containing such separator, and preparation method thereof
This application provides a separator, an electrical apparatus containing such separator, and preparation methods thereof. The separator includes a coating layer containing an organic-inorganic hybrid composite compound and provides improved performance in a number of aspects, and the organic-inorganic hybrid composite compound is formed by periodically assembling, along at least one spatial direction, basic units expressed by formula I, L x (M a C b ) y ·A z . This application further provides a battery and an electrical device containing such separator, preparation methods thereof, and an organic-inorganic hybrid composite compound for improving performance of a separator.
1. A separator, comprising:
a polymer matrix layer; and
a coating layer applied on at least one surface of the polymer matrix layer, wherein the coating layer comprises an organic-inorganic hybrid composite compound, and the organic-inorganic hybrid composite compound is formed by periodically assembling, along at least one spatial direction, basic units expressed by formula I; wherein
L x (M a C b ) y ·A z formula I
in formula I, M is a cation of one or more metals selected from the following: Zn, Co, Cu, Fe, Cd, Mn, Ag, Rh, Ru, Be, Mg, Al, Sc, Cr, Ni, Y, Ti, Zr, Hf, Li, Na, K, In, Ca, Sr, Pb, lanthanide metals, and actinide metals, wherein a is a value ranging from 0.1 to 10;
C is selected from one or more of the following atoms, atomic groups, small molecules, or anions: O, ═O, O 2- , S 2- , Cl − , Br − , I − , CO, —OH, OH − , and H 2 O, wherein b is a value ranging from 0.1 to 20;
y is a value ranging from 1 to 50;
when M is cations of two or more metals, a product of a and y represents the number of all metal cations in a single basic unit expressed by formula I;
L is selected from one or more of the following ligands: carbazole, polycarboxylic acid compounds, and salts, acids, esters, amides, anhydrides, dimers, and trimers of these ligands, wherein one or more hydrogen atoms in the ligand are, in some embodiments, substituted by one or more substituent groups selected from the following: cyano group, nitro group, amino group, aldehyde group, carboxyl group, halogen, C 1 -C 8 alkyl group, hydroxy C 1 -C 8 alkyl group, C 1 -C 8 alkoxy group, C 2 -C 8 alkenyl group, C 2 -C 8 alkynyl group, C 3 -C 16 cycloalkyl group, C 6 -C 20 aryl group, C 6 -C 20 heterocyclic group, or any combination thereof, wherein x is a value ranging from 1 to 50; and
A is an atom or cation selected from one or more of the following metal elements: Li, Na, K, Rb, Cs, Be, Sr, Zn, Al, Mg, and Ca; or is selected from one or more of the following molecules: H 2 , O 2 , H 2 O, CO 2 , NH 3 , CH 4 , methyl formate, ethyl acetate, and propylene carbonate, wherein z is a value ranging from 0 to 100, wherein each M metal cation is bonded to oxygen atoms in a plurality of carboxyl groups in two or more polycarboxylic acid compounds and a C by coordinate bonds, to form a basic unit structure, the basic unit structure constitutes a microstructure with a three-dimensional periodic assembly through a remainder of a ligand, the basic unit has pores, and when z is not zero, A is located in the pores of the basic unit.
2. The separator according to claim 1 , wherein in the organic-inorganic hybrid composite compound, the number of basic units expressed by formula I that are periodically assembled along at least one spatial direction is an integer ranging from 3 to 10,000.
3. The separator according to claim 1 , wherein 0.5≤x:y≤6; and/or
0.5≤a:b≤8.
4. The separator according to claim 1 , wherein M is a cation of one or more metals selected from the following: Cu and Zn; and
L is selected from one or more of the following ligands: trimesic acid, 3,3′,5,5′-biphenyltetracarboxylic acid, and 4,4′,4″-tricarboxylic acid triphenylamine.
5. The separator according to claim 1 , wherein the basic unit is selected from one or more of the following: EBTC[Cu] 2 ·(H 2 O) 2 , and NTB 2 [Zn 4 O].
6. The separator according to claim 1 , wherein the coating layer further comprises one or more components selected from the following: binder, inorganic particles, stabilizer, wetting agent, rheology modifier, defoamer, thickener, pH adjuster, and preservative; and/or
the coating layer further comprises inorganic particles, and the inorganic particles are selected from at least one of the following: boehmite, molecular sieve, zeolite, alumina, aluminum oxyhydroxide, silica, aluminum nitride, silicon carbide, MgO, CaO, ZnO, ZrO 2 , TiO 2 , and a mixture thereof, and/or
a mass ratio of the organic-inorganic hybrid composite compound to the inorganic particles is 1:5 to 5:1.
7. A battery, comprising the separator according to claim 1 .
8. A preparation method of the separator according to claim 1 , wherein the method comprises:
providing a polymer matrix layer; and
forming, on at least one surface of the polymer matrix layer, a coating layer comprising an organic-inorganic hybrid composite compound.
9. The separator according to claim 2 , wherein 0.5≤x:y≤6; and/or
0.5≤a:b≤8.
10. The separator according to claim 2 , wherein M is a cation of one or more metals selected from the following: Cu and Zn; and
L is selected from one or more of the following ligands: trimesic acid, 3,3′,5,5′-biphenyltetracarboxylic acid, and 4,4′,4″-tricarboxylic acid triphenylamine.
11. The separator according to claim 2 , wherein the basic unit is selected from one or more of the following: EBTC[Cu] 2 ·(H 2 O) 2 , and NTB 2 [Zn 4 O].
12. The separator according to claim 2 , wherein the coating layer further comprises one or more components selected from the following: binder, inorganic particles, stabilizer, wetting agent, rheology modifier, defoamer, thickener, pH adjuster, and preservative; and/or
the coating layer further comprises inorganic particles, and the inorganic particles are selected from at least one of the following: boehmite, molecular sieve, zeolite, alumina, aluminum oxyhydroxide, silica, aluminum nitride, silicon carbide, MgO, CaO, ZnO, ZrO 2 , TiO 2 , and a mixture thereof, and/or
a mass ratio of the organic-inorganic hybrid composite compound to the inorganic particles is 1:5 to 5:1.
13. The separator according to claim 3 , wherein M is a cation of one or more metals selected from the following: Cu and Zn; and
L is selected from one or more of the following ligands: trimesic acid, 3,3′,5,5′-biphenyltetracarboxylic acid, and 4,4′,4″-tricarboxylic acid triphenylamine.
14. The separator according to claim 3 , wherein the basic unit is selected from one or more of the following: EBTC[Cu] 2 ·(H 2 O) 2 , and NTB 2 [Zn 4 O].
15. The separator according to claim 3 , wherein the coating layer further comprises one or more components selected from the following: binder, inorganic particles, stabilizer, wetting agent, rheology modifier, defoamer, thickener, pH adjuster, and preservative; and/or
the coating layer further comprises inorganic particles, and the inorganic particles are selected from at least one of the following: boehmite, molecular sieve, zeolite, alumina, aluminum oxyhydroxide, silica, aluminum nitride, silicon carbide, MgO, CaO, ZnO, ZrO 2 , TiO 2 , and a mixture thereof, and/or
a mass ratio of the organic-inorganic hybrid composite compound to the inorganic particles is 1:5 to 5:1.