IP Library Granted Patent US 12,352,717
Granted Patent B2
US 12,352,717 · App. 17/867,031 · Granted Jul 8, 2025

Capacitance-based humidity and gas sensing RFID tags

Inventors: Brian S. Huffman (Belle Mead, NJ); Deniz Boyu (Dover, NJ); Thi N. Do (West Orange, NJ); Mohannad Abdo (Clifton, NJ)
Assignee: ZEBRA TECHNOLOGIES CORPORATION
G01N27/223G01N27/221G01N27/228A61B90/98G01N2027/222
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Quick Facts
Patent No.
US 12,352,717
App. No.
17/867,031
Granted
Jul 8, 2025
Kind
B2
Abstract

An RFID tag system includes an antenna, an integrated circuit electrically connected to the antenna, and a humidity or gas indicator being electrically connected to the antenna and the integrated circuit. The humidity or gas indicator includes a first electrode, a second electrode, a dielectric material, and a gap between the first electrode and the second electrode. At least a portion of the gap contains the dielectric material. The dielectric material is configured to have a change in its dielectric constant responsive to exposure to an environmental stimulus, which may be at least one of humidity or the presence of a gas. The change in the dielectric constant of the dielectric material changes a capacitance of the humidity or gas indicator, causing the integrated circuit to indicate the presence of the environmental stimulus.

Claims (37)

1. An RFID tag system comprising:

an antenna;

an integrated circuit electrically connected to the antenna; and

a humidity and gas indicator being electrically connected to the antenna and the integrated circuit;

wherein the humidity and gas indicator comprises:

a first electrode;

a second electrode;

a dielectric material configured to have a first change in a dielectric constant of the dielectric material responsive to an exposure to humidity and to have a second change in the dielectric constant responsive to an exposure to a gas; and

a gap between the first electrode and the second electrode, at least a portion of the gap containing the dielectric material,

wherein the first change in the dielectric constant of the dielectric material causes a capacitance between the first electrode and the second electrode to change to a capacitance in a first predetermined range, and the second change in the dielectric constant of the dielectric material causes the capacitance between the first electrode and the second electrode to change to a capacitance in a second predetermined range,

wherein the integrated circuit is configured to indicate a presence of humidity when the capacitance between the first electrode and the second electrode is in the first predetermined range and configured to indicate a presence of the gas when the capacitance between the first electrode and the second electrode is in the second predetermined range.

2. The RFID tag system of claim 1 , wherein the dielectric material comprises a material selected from the group consisting of PVA, PVP, PEG, acrylics, water reducible epoxy, cellulose, water soluble gum, PEG, hydrochromic ink, and combinations thereof.

3. The RFID tag system of claim 1 , wherein the second change in the dielectric constant occurs after exposure to a change in humidity above a first threshold change value for a first predetermined amount of time or less.

4. The RFID tag system of claim 1 , wherein the first electrode and the second electrode are in a comb shape and interleaved with each other.

5. The RFID tag system of claim 1 , wherein at least one of the first change and the second change in the dielectric constant is reversible.

6. The RFID tag system of claim 1 , further comprising:

a memory configured to record information indicating detected changes in capacitance values of the humidity and gas indicator; and

an RFID reader configured to receive a communication from the integrated circuit or the memory indicating the detected changes in capacitance values.

7. The RFID tag system of claim 6 , wherein the integrated circuit is configured to transmit a notification to the RFID reader in response to detecting a capacitance value of the humidity and gas indicator equal to or greater than a first threshold capacitance value.

8. The RFID tag system of claim 7 , wherein the first threshold capacitance value corresponds to a first humidity value in a range selected from the group consisting of from about 50% to about 55% RH, from about 55% to about 60% RH, from about 60% to about 65% RH, from about 65% to about 70% RH, from about 70% to about 75% RH, from about 75% to about 80% RH, from about 80% to about 85% RH, from about 85% to about 90% RH, and combinations thereof.

9. The RFID tag system of claim 7 , wherein the first threshold capacitance value corresponds to:

an ammonia gas concentration value in a range of about 50 ppm to about 150 ppm; or

a carbon monoxide gas concentration value in a range of about 70 ppm to about 150 ppm.

10. The RFID tag system of claim 7 , wherein the first threshold capacitance value corresponds to an electrolyte gas concentration value in a range of about 50 ppm to about 2,000 ppm.

11. The RFID tag system of claim 6 , wherein the integrated circuit is configured to transmit a notification to the RFID reader in response to detecting a capacitance value of the humidity and gas indicator equal to or lower than a second threshold capacitance value.

12. The RFID tag system of claim 11 , wherein the second threshold capacitance value corresponds to:

a second humidity value in a range selected from the group consisting of from about 10% to about 15% RH, from about 15% to about 20% RH, from about 20% to about 25% RH, from about 25% to about 30% RH, from about 30% to about 35% RH, from about 35% to about 40%, and combinations thereof, or

an atmosphere with an oxygen gas concentration value in a range of about 10% to 19.5% by volume.

13. The RFID tag system of claim 1 , wherein the dielectric material is configured to change color after exposure to a change in humidity or gas concentration above a second threshold change value for a second predetermined amount of time or less.

14. The RFID tag system of claim 1 , further comprising a substrate on or in which the antenna, the integrated circuit, and the humidity and gas indicator are disposed, wherein the substrate comprises a paper, cloth, or plastic.

15. A humidity- or gas-sensitive product, comprising:

a host product; and

the RFID tag system of claim 1 ,

wherein the RFID tag is associated with the host product and communicates information indicating exposure of the host product to a change in humidity or gas concentration.

16. The RFID tag system of claim 1 , wherein the first change in the dielectric constant occurs after exposure to a change in gas concentration above a first threshold change value for a first predetermined amount of time or less.

17. The RFID tag system of claim 1 , wherein the first change in the dielectric constant occurs after exposure to a change in gas concentration above a first threshold change value for at least a first predetermined amount of time.

18. The RFID tag system of claim 1 , wherein the second change in the dielectric constant occurs after exposure to a change in humidity above a first threshold change value for at least a first predetermined amount of time.

Assignments (2)
MERGER Recorded May 29, 2025
From: TEMPTIME CORPORATION
To: ZEBRA TECHNOLOGIES CORPORATION
Reel/Frame 071548/0054 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 29, 2022
From: HUFFMAN, BRIAN S.; BOYU, DENIZ; DO, THI N.; ABDO, MOHANNAD
To: TEMPTIME CORPORATION
Reel/Frame 060673/0821 →
Continuity (1)
Related Publication 20240027385A1 · Jan 25, 2024
References Cited (106)
US 3999946A · Patel et al. · 1976 [cited by applicant]
US 4228126A · Patel et al. · 1980 [cited by applicant]
US 4298348A · Ivory · 1981 [cited by applicant]
US 4646066A · Baughman et al. · 1987 [cited by applicant]
US 4788151A · Preziosi et al. · 1988 [cited by applicant]
US 6524000B1 · Roth · 2003 [cited by applicant]
US 6524697B1 · Furuyama et al. · 2003 [cited by applicant]
US 6642016B1 · Sjoholm et al. · 2003 [cited by applicant]
US 6720866B1 · Sorrells et al. · 2004 [cited by applicant]
US 7098794B2 · Lindsay et al. · 2006 [cited by applicant]
US 7503690B2 · Song et al. · 2009 [cited by applicant]
US 7570169B2 · Li et al. · 2009 [cited by applicant]
US 7604398B1 · Akers et al. · 2009 [cited by applicant]
US 7719404B2 · Makela et al. · 2010 [cited by applicant]
US 8040243B2 · Bommer et al. · 2011 [cited by applicant]
US 8043000B2 · Sumida et al. · 2011 [cited by applicant]
US 8111143B2 · Tong et al. · 2012 [cited by applicant]
US 8228172B2 · Collins et al. · 2012 [cited by applicant]
US 8267576B2 · Haarer et al. · 2012 [cited by applicant]
US 8357958B2 · Cummins · 2013 [cited by applicant]
US 8395521B2 · Kauffman et al. · 2013 [cited by applicant]
US 8870082B2 · Cattaneo et al. · 2014 [cited by applicant]
US 8899829B1 · Butera et al. · 2014 [cited by applicant]
US 8968662B2 · Haarer et al. · 2015 [cited by applicant]
US 9011794B2 · Haarer et al. · 2015 [cited by applicant]
US 9164052B1 · Speer · 2015 [cited by examiner]
US 9195925B2 · Potyrailo et al. · 2015 [cited by applicant]
US 9436853B1 · Meyers · 2016 [cited by applicant]
US 9494032B2 · Roberson et al. · 2016 [cited by applicant]
US 9546911B2 · Huffman et al. · 2017 [cited by applicant]
US 9581501B2 · Kozono et al. · 2017 [cited by applicant]
US 10184777B2 · Okojie · 2019 [cited by applicant]
US 10338537B2 · Braunberger · 2019 [cited by applicant]
US 20030053377A1 · Spevacek · 2003 [cited by applicant]
US 20040061655A1 · Forster et al. · 2004 [cited by applicant]
US 20060261946A1 · Himberger et al. · 2006 [cited by applicant]
US 20070210923A1 · Butler et al. · 2007 [cited by applicant]
US 20080012580A1 · Funo et al. · 2008 [cited by applicant]
US 20080078233A1 · Larson · 2008 [cited by examiner]
US 20080292507A1 · Dee et al. · 2008 [cited by applicant]
US 20090010304A1 · Skinner et al. · 2009 [cited by applicant]
US 20090066516A1 · Lazo · 2009 [cited by applicant]
US 20090131718A1 · Baughman et al. · 2009 [cited by applicant]
US 20100001745A1 · Sumida et al. · 2010 [cited by applicant]
US 20100090802A1 · Nilsson et al. · 2010 [cited by applicant]
US 20100123583A1 · Bommer et al. · 2010 [cited by applicant]
US 20110211612A1 · Branecky · 2011 [cited by applicant]
US 20120260728A1 · Bhattacharyya et al. · 2012 [cited by applicant]
US 20130033364A1 · Raz et al. · 2013 [cited by applicant]
US 20130224875A1 · Haarer et al. · 2013 [cited by applicant]
US 20140004618A1 · Chien et al. · 2014 [cited by applicant]
US 20140144366A1 · Huffman et al. · 2014 [cited by applicant]
US 20140148095A1 · Smith et al. · 2014 [cited by applicant]
US 20140154808A1 · Patel · 2014 [cited by applicant]
US 20140358099A1 · Durgin et al. · 2014 [cited by applicant]
US 20150116093A1 · Swager et al. · 2015 [cited by applicant]
US 20160011157A1 · Smyth et al. · 2016 [cited by applicant]
US 20160261005A1 · Rustomji · 2016 [cited by examiner]
US 20160349224A1 · Patel et al. · 2016 [cited by applicant]
US 20170038325A1 · Takashima et al. · 2017 [cited by applicant]
US 20170211992A1 · Yeager et al. · 2017 [cited by applicant]
US 20170255854A1 · Bhatia et al. · 2017 [cited by applicant]
US 20170370692A1 · Okojie · 2017 [cited by applicant]
US 20180100807A1 · Abdo et al. · 2018 [cited by applicant]
US 20180372663A1 · Gontard · 2018 [cited by examiner]
US 20190302047A1 · Park · 2019 [cited by examiner]
US 20200011827A1 · Zhou · 2020 [cited by examiner]
US 20200193258A1 · Hawwa et al. · 2020 [cited by applicant]
US 20200210801A1 · Oda · 2020 [cited by examiner]
US 20210109053A1 · Shiraki · 2021 [cited by applicant]
US 20220268640A1 · Bhatia et al. · 2022 [cited by applicant]
CN 103543146 · 2014 [cited by applicant]
CN 104599956 · 2015 [cited by applicant]
DE 102005061249 · 2007 [cited by applicant]
EP 3168608 · 2017 [cited by applicant]
EP 3845895A1 · 2021 [cited by examiner]
JP 5723474 · 2015 [cited by applicant]
KR 101519317 · 2015 [cited by applicant]
WO WO03044521 · 2003 [cited by applicant]
WO WO20080127044 · 2008 [cited by applicant]
WO WO2010105811 · 2010 [cited by applicant]
WO WO2013170273 · 2013 [cited by applicant]
WO WO2013186782 · 2013 [cited by applicant]
WO WO2014113247 · 2014 [cited by applicant]
WO WO2015113086 · 2015 [cited by applicant]
WO WO2017151731 · 2017 [cited by applicant]
WO WO2020231921 · 2020 [cited by applicant]
Search Report and Written Opinion dated Oct. 5, 2023 issued for International PCT Application No. PCT/US2023/027934. [cited by applicant]
Wegner et al. “Topochemical Reactions of Monomers with Conjugated Triple Bonds” 9 J. Poly. Sci.B.Poly.Letters 133-44 (1971). [cited by applicant]
Wegner “Topochemical Polymerization of Monomers with Conjugated Triple Bonds”, 154 Die Makromoleculare Chemie 35-48 (1972). [cited by applicant]
World Health Organization: Vaccine Vial Monitors: FAQs. 2011. https://www.who.int/immunization/programmes_systems/supply_chain/optimize/vaccine_vial_monitors_faqs.pdf?ua=1 (Year: 2011). [cited by applicant]
I. Gascon, J.D. Marty, T. Gharsa and C. Mingotaud, 2005. “Formation of Gold Nanoparticles in a Side-Chain Linquid Crystalline Network: Influence of the Structure and Macroscopic Order of the Material Chem. Mater. 2005, … [cited by applicant]
Bhattacharyya et al., “Low-Cost, Ubiquitous RFID-Tag-Antenna-Based Sensing”, Proceedings of the IEEE 2010, 98, 1593-1600. [cited by applicant]
Windl et al., “Reactivatable Passive Radio-Frequency Identification Temperature Indicator”, Journal of Applied Physics 117, 17C125 (2015). [cited by applicant]
Tanguy et al. “Enhanced Radio Frequency Biosensor for Food Quality Detection Using Functionalized Carbon Nanofillers”, ACS Appl. Mater. Interfaces 2015, 7, 11939-11947. [cited by applicant]
Wu et al., “3D-Printed Microelectronics for Integrated Circuitry and Passive Wireless Sensors”, Microsystems & Nanoengineering 1, 15013 (2015). [cited by applicant]
Wan et al., “A New Type of TTI Based on Electrochemical Pseudo Transistor”, J. of Food. Engin. 168, (2016) 79-83. [cited by applicant]
Search Report and Written Opinion dated Jul. 17, 2017 issued for International PCT Application No. PCT/US17/20142. [cited by applicant]
Office Action dated Sep. 19, 2019 issued for European Patent Application No. 17760694.4. [cited by applicant]
International search report and of a written opinion dated Aug. 10, 2020 issued for International PCT Application No. PCT/US20/32340. [cited by applicant]
Office Action dated Sep. 3, 2020 issued for European Patent Application No. 17760694.4. [cited by applicant]
Office Action dated Jan. 7, 2020 issued for European Patent Application No. 17760694.4. [cited by applicant]
Office Action dated Sep. 23, 2019 issued for European Patent Application No. 17760694.4. [cited by applicant]
Office Action dated Nov. 4, 2020 issued for Chinese Patent Application No. 201780014268.2. [cited by applicant]
Office Action dated Feb. 25, 2021 issued for Korean Patent Application No. 10-2018-7026541. [cited by applicant]
Moisture-Detecting UHF RFID Labels. Brady, webpage capture, printed Oct. 9, 2024. https://www.bradyid.com/rfid-labels-tags/moisture-detecting-uhf-rfid-labels-pid-tht-uhf-b423-42x85#overview. [cited by applicant]