Battery module, battery pack, electrical apparatus, and manufacturing method and manufacturing device of battery module
The present application relates to a battery module, including a first-type battery cell and a second-type battery cell electrically connected at least in series, the first-type battery cell and the second-type battery cell are battery cells of different chemical systems, the first-type battery cell includes N first battery cell(s), the second-type battery cell includes M second battery cell(s); the first battery cell includes a first negative electrode plate, the second battery cell includes a second negative electrode plate, a ratio of a conductivity of an electrolyte solution (25° C.) of the first battery cell to a coating mass per unit area of the first negative electrode plate is denoted as M1, and a ratio of a conductivity of an electrolyte solution (25° C.) of the second battery cell to a coating mass per unit area of the second negative electrode plate is denoted as M2, M1>M2, and 0.08≤M1≤11, 0.03≤M2≤4.62.
1. A battery module, comprising a first-type battery cell and a second-type battery cell electrically connected at least in series, the first-type battery cell and the second-type battery cell are battery cells of different chemical systems,
the first-type battery cell comprises N first battery cell(s),
the second-type battery cell comprises M second battery cell(s), N and M are positive integers,
the first battery cell comprises a first negative electrode plate, the second battery cell comprises a second negative electrode plate,
a ratio of a conductivity of an electrolyte solution at 25° C. of the first battery cell to a coating mass per unit area of the first negative electrode plate is denoted as M1, a ratio of a conductivity of an electrolyte solution at 25° C. of the second battery cell to a coating mass per unit area of the second negative electrode plate is denoted as M2, wherein a unit of the conductivity of the electrolyte solution is mS/cm, a unit of the coating mass per unit area is mg/cm 2 ; and
M1 and M2 satisfy: M1>M2, and 0.08≤M1≤11, 0.03≤M2≤4.62.
2. The battery module according to claim 1 , wherein 0.33≤M1≤6.42, 0.17≤M2≤2.57; and optionally, 0.63≤M1≤1.94, 0.63≤M2≤1.1.
3. The battery module according to claim 1 , wherein a state of charge-open circuit voltage (SOC-OCV) curve of the first battery cell satisfies at least one of the following conditions:
(1) in an interval of 5%-95% SOC, a slope k1 of the SOC-OCV curve of the first battery cell is ≤5 mV/% SOC;
(2) in the SOC-OCV curve of the first battery cell, there is at least a flat curve with a span not less than 10% SOC and the slope k1≤5 mV/% SOC.
4. The battery module according to claim 1 , wherein a state of charge-open circuit voltage (SOC-OCV) curve of the second battery cell satisfies at least one of the following conditions:
(1) in the interval of 5%-95% SOC, a slope k2 of the SOC-OCV curve of the second battery cell is >5 mV/% SOC, optionally, k2≥6 mV % SOC, and further optionally, k2≥9 mV/% SOC;
(2) in the SOC-OCV curve of the second battery cell, there is at least a curve with a span not less than 10% SOC and the slope k2>5 mV/% SOC.
5. The battery module according to claim 1 , wherein a compacted density of the first negative electrode plate is PD1, a compacted density of the second negative electrode plate is PD2, wherein PD1<PD2, and 0.5≤PD1≤3, 0.5≤PD2≤3, and a unit is g/cm 3 ;
optionally, 1≤PD1≤2, 1≤PD2≤2; and
further optionally, 1.2≤PD1≤1.7, 1.2≤PD2≤1.7.
6. The battery module according to claim 1 , wherein a coating mass per unit area of the first negative electrode plate is CW1, a coating mass per unit area of the second negative electrode plate is CW2, wherein 6.49≤CW1≤17, 4.54≤CW2≤25.51, and a unit is: mg/cm 2 ;
optionally, 1≤CW1≤2, 1≤CW2≤2;
further optionally, 9.09≤CW1≤11.04, 7.73≤CW2≤12.69; and
still further optionally, CW1<CW2.
7. The battery module according to claim 1 , wherein
a negative active substance of the first negative electrical sheet and a negative active substance of the second negative electrical sheet can be independently selected from one or more of artificial graphite, natural graphite, soft carbon, hard carbon, silicon-based material, tin-based material and lithium titanate.
8. The battery module according to claim 1 , wherein
a ratio of the number N of the first battery cell to the number M of the second battery cell is 0.1˜50, optionally 0.3˜30, and further optionally 0.5˜10.
9. A battery pack, comprising the battery module according to claim 1 .
10. A power consumption apparatus, comprising the battery module according to claim 1 , and the battery module can serve as a power supply or an energy storage unit of the power consumption apparatus.