Processes for producing trifluoroiodomethane and trifluoroacetyl iodide
The present disclosure provides a process for producing trifluoroiodomethane, the process comprising providing a reactant stream comprising hydrogen iodide and at least one trifluoroacetyl halide selected from the group consisting of trifluoroacetyl chloride, trifluoroacetyl fluoride, trifluoroacetyl bromide, and combinations thereof, reacting the reactant stream in the presence of a first catalyst at a first reaction temperature from about 25° C. to about 400° C. to produce an intermediate product stream comprising trifluoroacetyl iodide, and reacting the intermediate product stream in the presence of a second catalyst at a second reaction temperature from about 200° C. to about 600° C. to produce a final product stream comprising the trifluoroiodomethane.
1. A gas-phase process for producing trifluoroiodomethane, comprising:
providing a reactant stream comprising trifluoroacetyl iodide; and
reacting the reactant stream in the presence of a catalyst at a reaction temperature from about 200° C. to about 600° C. and in the presence of less than 100 ppm of oxygen to produce a product stream comprising the trifluoroiodomethane.
2. The method of claim 1 , wherein in the step of reacting the reactant stream, the reaction temperature is from about 250° C. to about 500° C.
3. The method of claim 1 , wherein in the step of reacting the reactant stream, the reaction temperature is from about 300° C. to about 400° C.
4. The method of claim 1 , wherein in the step of reacting the reactant stream, the reactant stream may be in contact with the catalyst for a contact time from about 0.1 seconds to about 300 seconds.
5. The method of claim 1 , wherein in the step of reacting the reactant stream, the catalyst comprises activated carbon or about 0.3 wt. % to about 0.7 wt. % palladium on a support.
6. The method of claim 1 , wherein in the step of reacting the reactant stream, the catalyst comprises activated carbon.
7. The method of claim 1 , wherein in the step of reacting the reactant stream, the catalyst consists of surfaces of a reactor in contact with the reactant stream.
8. The method of claim 1 , wherein the step of reacting the reactant stream is at a pressure from about 5 psig (34 kPaG) to about 300 psig (2,068 kPaG).
9. A composition comprising:
at least 99 wt. % of trifluoroiodomethane; and
at least one of the following:
greater than 0 to less than 500 ppm hexafluoroethane;
greater than 0 to less than 500 ppm trifluoromethane;
greater than 0 to less than 100 ppm carbon monoxide; and
greater than 0 to less than 1 ppm hydrogen chloride.
10. The composition of claim 9 , comprising:
at least 99.5 wt. % of trifluoroiodomethane; and
at least one of the following:
greater than 0 to less than 250 ppm hexafluoroethane;
greater than 0 to less than 250 ppm trifluoromethane;
greater than 0 to less than 50 ppm carbon monoxide; and
greater than 0 to less than 0.5 ppm hydrogen chloride.
11. The composition of claim 9 , comprising:
at least 99.7 wt. % of trifluoroiodomethane; and
at least one of the following:
greater than 0 to less than 100 ppm hexafluoroethane;
greater than 0 to less than 100 ppm trifluoromethane;
greater than 0 to less than 20 ppm carbon monoxide; and
greater than 0 to less than 0.2 ppm hydrogen chloride.
12. The composition of claim 9 , comprising:
at least 99.9 wt. % of trifluoroiodomethane; and
at least one of the following:
greater than 0 to less than 100 ppm hexafluoroethane;
greater than 0 to less than 100 ppm trifluoromethane;
greater than 0 to less than 20 ppm carbon monoxide; and
greater than 0 to less than 0.2 ppm hydrogen chloride.
13. A gas-phase process for producing trifluoroiodomethane, comprising:
providing a reactant stream comprising trifluoroacetyl iodide; and
reacting the reactant stream in the presence of a catalyst at a reaction temperature from about 200° C. to about 600° C. and in the presence of less than 100 ppm of water to produce a product stream comprising the trifluoroiodomethane.
14. The method of claim 13 , wherein in the step of reacting the reactant stream, the reaction temperature is from about 250° C. to about 500° C.
15. The method of claim 13 , wherein in the step of reacting the reactant stream, the reaction temperature is from about 300° C. to about 400° C.
16. The method of claim 13 , wherein in the step of reacting the reactant stream, the reactant stream may be in contact with the catalyst for a contact time from about 0.1 seconds to about 300 seconds.
17. The method of claim 13 , wherein in the step of reacting the reactant stream, the catalyst comprises activated carbon or about 0.3 wt. % to about 0.7 wt. % palladium on a support.
18. The method of claim 13 , wherein in the step of reacting the reactant stream, the catalyst comprises activated carbon.
19. The method of claim 13 , wherein in the step of reacting the reactant stream, the catalyst consists of surfaces of a reactor in contact with the reactant stream.
20. The method of claim 13 , wherein the step of reacting the reactant stream is at a pressure from about 5 psig (34 kPaG) to about 300 psig (2,068 kPaG).