PARTIAL DEHYDROGENATION OF ORGANIC LIQUIDS

1 - 11 . (canceled)

12 . A process for producing hydrogen by partial dehydrogenation of an organic liquid, said process comprising:

a step of supplying at least one organic liquid having a Degree of Hydrogenation DH plus ,

a step of partially dehydrogenating said liquid,

a step of recovering firstly gaseous hydrogen and secondly said organic liquid having a Degree of Hydrogenation DH minus ,

the ratio DH plus /DH minus being between 1 and 25, endpoints excluded.

13 . The process as claimed in claim 12 , wherein the partial dehydrogenation step is carried out by implementing one or more of the following means, individually or in a combination of two or more thereof:

blocking of the reaction before a 100% dehydrogenation yield is obtained,

reaction temperature lower than the temperature commonly used for the dehydrogenation reaction,

reaction pressure lower than the pressure commonly used for the dehydrogenation reaction,

low-selectivity dehydrogenation catalyst, and

any other means for regulating the dehydrogenation reaction kinetics.

14 . The process as claimed in claim 12 , wherein the organic liquid is liquid at ambient temperature and pressure.

15 . The process as claimed in claim 12 , wherein the organic liquid is a mixture of two or more organic liquids which may have identical or different Degrees of Hydrogenation.

16 . The process as claimed in claim 12 , wherein the organic liquid possesses at least one aromatic ring, which is optionally partially dehydrogenated.

17 . The process as claimed in claim 12 , wherein the organic liquid corresponds to the general formula (1):

(A−X) n −B  (1)

in which:

A and B, which are identical or different, represent, independently of one another, an aromatic ring optionally partially dehydrogenated and optionally substituted by one or more saturated or partially or completely unsaturated hydrocarbon radicals comprising from 1 to 20 carbon atoms,

X represents a spacer group, selected from the group consisting of a single bond, an oxygen atom, a sulfur atom, the divalent radical —(CRR′) m —, the divalent radical >C═CRR′, and the divalent radical —NR″—,

R and R′, which are identical or different, are selected, independently of one another, from hydrogen and a saturated or partially or completely unsaturated hydrocarbon radical comprising from 1 to 6 carbon atoms,

R″ represents a saturated or partially or completely unsaturated hydrocarbon radical comprising from 1 to 6 carbon atoms,

m represents an integer of between 1 and 4, endpoints included, and

n can be equal to 0 or represents an integer equal to 1, 2 or 3, with the restriction that, when n is equal to 0, B is substituted by one or more hydrocarbon radicals, as defined above.

18 . The process as claimed in claim 12 , wherein the organic liquid is selected from the group consisting of benzyltoluene (BT), dibenzyltoluene (DBT), their partially dehydrogenated homologs, and mixtures thereof in any proportions.

19 . The process as claimed in claim 12 , wherein the organic liquid has a Degree of Hydrogenation DH plus conforming to the inequation 0.6≤DH plus <1.

20 . The process as claimed in claim 12 , wherein the organic liquid has a Degree of Hydrogenation DH minus conforming to the inequation 0<DH minus ≤0.6.

21 . A hydrogenation/dehydrogenation cycle comprising at least the process as claimed in claim 12 for producing hydrogen by partial dehydrogenation of an organic liquid and at least one hydrogenation reaction of said organic liquid.

22 . The cycle as claimed in claim 21 , comprising one or more dehydrogenation processes including at least one which is a process of partial dehydrogenation as claimed in claim 12 , prior to and/or consecutively with one or more hydrogenation reactions of an organic liquid capable of storing, transporting and releasing hydrogen.

23 . The process of claim 12 , wherein the ratio DH plus /DH minus is between 1.1 and 20, endpoints included.