BINDER COMPOSITION FOR ALL-SOLID-STATE SECONDARY BATTERIES, SLURRY FOR ALL-SOLID-STATE SECONDARY BATTERIES, SOLID ELECTROLYTE SHEET FOR ALL-SOLID-STATE SECONDARY BATTERIES, METHOD FOR PRODUCING SAID SOLID ELECTROLYTE SHEET FOR ALL-SOLID-STATE SECONDARY BATTERIES, ALL-SOLID-STATE SECONDARY BATTERY, AND METHOD FOR PRODUCING SAID ALL-SOLID-STATE SECONDARY BATTERY
A binder composition for an all-solid-state secondary battery, may have excellent long-term storage stability and lithium ion conductivity, and may be capable of achieving a satisfactory cycle life characteristic even under a high voltage. Such a binder composition for an all-solid-state secondary battery may include: a polymer (A) having an aromatic vinyl unit based on an aromatic vinyl compound and a conjugated diene unit based on a conjugated diene compound; an anti-aging agent (B) at 200 ppm or more and 5,000 ppm or less with respect to a total mass of the binder composition for an all-solid-state secondary battery; and a liquid medium (C).
1 . A binder composition suitable for an all-solid-state secondary battery, the composition comprising:
a polymer (A) comprising an aromatic vinyl unit based on an aromatic vinyl compound and a conjugated diene unit based on a conjugated diene compound;
an anti-aging agent (B) at 200 ppm or more and 5,000 ppm or less with respect to a total binder composition mass; and
a liquid medium (C).
2 . The composition of claim 1 , wherein the anti-aging agent (B) comprises a phenol-based anti-aging agent and/or an amine-based anti-aging agent.
3 . The composition of claim 1 , wherein the polymer (A) has a value α, represented by equation (i):
α=( p +(0.5× r ))/( p+q +(0.5× r )+ s ) (i),
of less than 0.9,
wherein p, q, r, and s are constituent ratios (molar ratios) of a structural unit of formula (1):
a structural unit of formula (2)
a structural unit formula (3)
and
a structural unit formula (4)
—CH 2 —CH═CH—CH 2 — (4),
in the polymer.
4 . The composition of claim 1 , wherein the polymer (A) has a bound styrene content in a range of from 5% to 40%.
5 . The composition of claim 1 , wherein the polymer (A) has a unit based on a modifier comprising a nitrogen atom, an oxygen atom, a silicon atom, a germanium atom, and/or a tin atom.
6 . The composition of claim 1 , wherein the liquid medium (C) comprising an aliphatic hydrocarbon, an alicyclic hydrocarbon, an aromatic hydrocarbon, ketone, ester, and/or ether.
7 . The composition of claim 1 , wherein the polymer (A) is dissolved in the liquid medium (C).
8 . A slurry suitable for an all-solid-state secondary battery, the slurry comprising:
the binder composition of claim 1 ; and
a solid electrolyte.
9 . The slurry of claim 8 , comprising, as the solid electrolyte, a sulfide-based solid electrolyte or an oxide-based solid electrolyte.
10 . An all-solid-state secondary battery, comprising:
a positive electrode active material layer;
a solid electrolyte layer; and
a negative electrode active material layer,
wherein the positive electrode active material layer, the solid electrolyte layer, and/or the negative electrode active material layer is a layer formed by applying and drying the slurry of claim 8 .
11 . A solid electrolyte sheet suitable for an all-solid-state secondary battery, the sheet comprising:
a substrate; and
a layer formed on the substrate by applying and drying the slurry of claim 8 .
12 . A method of producing a solid electrolyte sheet suitable for an all-solid-state secondary battery, the method comprising:
applying the slurry of claim 8 onto a substrate; and
drying the slurry.
13 . A method of producing an all-solid-state secondary battery, the method comprising:
conducting the method of claim 12 ; and
further processing and thereby producing an all-solid-state secondary battery.
14 . The composition of claim 1 , wherein the anti-aging agent (B) is at least one selected from the group consisting of a phenol-based anti-aging agent and an amine-based anti-aging agent.
15 . The composition of claim 1 , wherein the liquid medium (C) is at least one selected from the group consisting of an aliphatic hydrocarbon, an alicyclic hydrocarbon, an aromatic hydrocarbon, ketone, ester, and ether.