IP Library Patent Application 17906449
Patent Application
App. No. 17/906,449

BINDER COMPOSITION FOR ALL-SOLID-STATE SECONDARY BATTERIES, SLURRY FOR ALL-SOLID-STATE SECONDARY BATTERIES, SOLID ELECTROLYTE SHEET FOR ALL-SOLID-STATE SECONDARY BATTERIES, METHOD FOR PRODUCING SAID SOLID ELECTROLYTE SHEET FOR ALL-SOLID-STATE SECONDARY BATTERIES, ALL-SOLID-STATE SECONDARY BATTERY, AND METHOD FOR PRODUCING SAID ALL-SOLID-STATE SECONDARY BATTERY

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Quick Facts
Patent No.
US None
App. No.
17/906,449
Abstract

A binder composition for an all-solid-state secondary battery, may have excellent long-term storage stability and lithium ion conductivity, and may be capable of achieving a satisfactory cycle life characteristic even under a high voltage. Such a binder composition for an all-solid-state secondary battery may include: a polymer (A) having an aromatic vinyl unit based on an aromatic vinyl compound and a conjugated diene unit based on a conjugated diene compound; an anti-aging agent (B) at 200 ppm or more and 5,000 ppm or less with respect to a total mass of the binder composition for an all-solid-state secondary battery; and a liquid medium (C).

Claims (39)

1 . A binder composition suitable for an all-solid-state secondary battery, the composition comprising:

a polymer (A) comprising an aromatic vinyl unit based on an aromatic vinyl compound and a conjugated diene unit based on a conjugated diene compound;

an anti-aging agent (B) at 200 ppm or more and 5,000 ppm or less with respect to a total binder composition mass; and

a liquid medium (C).

2 . The composition of claim 1 , wherein the anti-aging agent (B) comprises a phenol-based anti-aging agent and/or an amine-based anti-aging agent.

3 . The composition of claim 1 , wherein the polymer (A) has a value α, represented by equation (i):

α=( p +(0.5× r ))/( p+q +(0.5× r )+ s )  (i),

of less than 0.9,

wherein p, q, r, and s are constituent ratios (molar ratios) of a structural unit of formula (1):

a structural unit of formula (2)

a structural unit formula (3)

and

a structural unit formula (4)

—CH 2 —CH═CH—CH 2 —  (4),

in the polymer.

4 . The composition of claim 1 , wherein the polymer (A) has a bound styrene content in a range of from 5% to 40%.

5 . The composition of claim 1 , wherein the polymer (A) has a unit based on a modifier comprising a nitrogen atom, an oxygen atom, a silicon atom, a germanium atom, and/or a tin atom.

6 . The composition of claim 1 , wherein the liquid medium (C) comprising an aliphatic hydrocarbon, an alicyclic hydrocarbon, an aromatic hydrocarbon, ketone, ester, and/or ether.

7 . The composition of claim 1 , wherein the polymer (A) is dissolved in the liquid medium (C).

8 . A slurry suitable for an all-solid-state secondary battery, the slurry comprising:

the binder composition of claim 1 ; and

a solid electrolyte.

9 . The slurry of claim 8 , comprising, as the solid electrolyte, a sulfide-based solid electrolyte or an oxide-based solid electrolyte.

10 . An all-solid-state secondary battery, comprising:

a positive electrode active material layer;

a solid electrolyte layer; and

a negative electrode active material layer,

wherein the positive electrode active material layer, the solid electrolyte layer, and/or the negative electrode active material layer is a layer formed by applying and drying the slurry of claim 8 .

11 . A solid electrolyte sheet suitable for an all-solid-state secondary battery, the sheet comprising:

a substrate; and

a layer formed on the substrate by applying and drying the slurry of claim 8 .

12 . A method of producing a solid electrolyte sheet suitable for an all-solid-state secondary battery, the method comprising:

applying the slurry of claim 8 onto a substrate; and

drying the slurry.

13 . A method of producing an all-solid-state secondary battery, the method comprising:

conducting the method of claim 12 ; and

further processing and thereby producing an all-solid-state secondary battery.

14 . The composition of claim 1 , wherein the anti-aging agent (B) is at least one selected from the group consisting of a phenol-based anti-aging agent and an amine-based anti-aging agent.

15 . The composition of claim 1 , wherein the liquid medium (C) is at least one selected from the group consisting of an aliphatic hydrocarbon, an alicyclic hydrocarbon, an aromatic hydrocarbon, ketone, ester, and ether.

Assignments (2)
CHANGE OF ADDRESS Recorded Oct 3, 2024
From: ENEOS MATERIALS CORPORATION
To: ENEOS MATERIALS CORPORATION
Reel/Frame 069105/0903 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 15, 2022
From: ABE, TATSUYA; ASO, KEIGO; ITAI, SHINGO; IIDA, MASASHI
To: ENEOS MATERIALS CORPORATION
Reel/Frame 061111/0238 →