INJECTION MOLDED PARTS
The invention relates to an injection molded part comprising a composition comprising: a. Polyarylene sulfide (PAS) in an amount of between 50 wt % and 90 wt %; b. Glass fibers in an amount of between 10 wt % and 50 wt %; wherein the composition has a sodium content of at most 3500 ppm as measured by Inductively coupled plasma atomic emission spectroscopy (ICP-AES) and wherein the composition has a iodine content of at most 100 ppm as measured by X-ray fluorescence (XRF) and wherein the weight percentage and ppm is with respect to the total weight of the composition. The invention further relates to a fuel cell comprising the injection molded part.
1 . Injection molded part comprising a composition comprising:
a. Polyarylene sulfide (PAS) in an amount of between 50 wt % and 90 wt %;
b. Glass fibers in an amount of between 10 wt % and 50 wt %;
wherein the composition has a sodium content of at most 3500 ppm as measured by Inductively coupled plasma atomic emission spectroscopy (ICP-AES) and wherein the composition has a iodine content of at most 100 ppm as measured by X-ray fluorescence (XRF) and wherein the weight percentage and ppm is with respect to the total weight of the composition.
2 . Injection molded part according to claim 1 , wherein the amount of PAS is between 60 wt % and 80 wt %, and the amount of glass fibers is between 20 wt % and 40 wt %, wherein the weight percentage is with respect to the total weight of the composition.
3 . Injection molded part according to claim 1 , wherein the composition has a sodium content of at most 2000 ppm as measured by Inductively coupled plasma atomic emission spectroscopy (ICP-AES)
4 . Injection molded part according to claim 1 , wherein the PAS has a sodium content of at most 500 ppm with respect to the total weight of the PAS.
5 . Injection molded part, according to claim 1 , wherein the glass fibers have a sodium content of at most 3000 ppm with respect to the total weight of the glass fiber.
6 . Injection molded part according to claim 1 , wherein the glass fibers have a sodium content of at most 800 ppm with respect to the total weight of the glass fiber.
7 . Injection molded part according to claim 1 , wherein the PAS has a crystallization temperature of at least 230° C. measured by DSC according to the method of ISO 11357-1/3 (2009) with a scan rate of 10° C./min heating the composition to 320° C., and keeping the composition for 3 mins at 320° C. under nitrogen, and subsequently cooling the composition at the same scan rate to record the cooling crystallization temperature in the first cooling cycle.
8 . Injection molded part according to claim 1 , wherein the composition has a tensile strength on an injection molded tensile bar with 4 mm thickness of at least 160 MPa, measured according to ISO 527-1A 5 mm/min at 23° C., after an exposure to water vapor in an autoclave at a temperature of 110° C. during 1000 hours, preferably at least 165 MPa, more preferred at least 170 MPa.
9 . Injection molded part according to claim 1 , wherein the composition has an elongation at break on an injection molded tensile bar with 4 mm thickness of at least 1.2%, measured according to ISO 527-1A 5 mm/min at 23° C., after an exposure to water vapor in an autoclave at a temperature of 110° C. during 1000 hours, preferably at least 1.3%, more preferably at least 1.4% even more preferred at least 1.5% and most preferred at least 1.6%.
10 . Injection molded part according to claim 1 , wherein the polyarylene sulfide is polyphenylene sulfide.
11 . Injection molded part according to claim 1 , wherein the composition further comprises a coupling agent in an amount of between 0.1 wt % and 1.0 wt %, with respect to the total weight of the composition.
12 . Injection molded part according to claim 11 , wherein the coupling agent is aminoalkoxylsilane, γ-aminopropyltriethoxysilane and/or γ-aminopropyltrimethoxysilane.
13 . Fuel cell comprising the injection molded part according to claim 1 .
14 . Method for preparing a composition comprising polyarylene sulfide and glass fibers, wherein the composition has a sodium content of at most 3500 ppm as measured by Inductively coupled plasma atomic emission spectroscopy (ICP-AES) and wherein the composition has a iodine content of at most 100 ppm as measured by X-ray fluorescence (XRF) and wherein the weight percentage and ppm is with respect to the total weight of the composition, comprising the steps of heating the PAS to a temperature above its melting temperature, for example with an extruder, and subsequently adding glass fibers to obtain a mixture, after which the mixture is cooled and may be suitably pelletized.
15 . Method according to claim 14 , wherein a coupling agent being aminoalkoxylsilane, γ-aminopropyltriethoxysilane and/or γ-aminopropyltrimethoxysilane is dosed to the PAS together with the glass fibers.