Composition comprising inorganic particles dispersed in a transparent material
In particular the present invention relates to polymeric composition comprising scattering particles for lightning applications or light guides. The invention also relates to a process for manufacturing such a polymeric composition comprising scattering particles for lightning applications or light guides. More particularly the present invention relates to a polymeric (meth)acrylic composition comprising inorganic scattering particles for lightning applications or light guides.
1. A composition C1 comprising:
a) a transparent material M1; and
b) inorganic particles P1 comprising an inorganic compound of the formula AB x C 1-x X 3 ,
wherein x is from 0 to 1 and A, B, and C are cations and X is an anion;
or of the formula A′ 1-y A″ y CX 3 ,
wherein y is from 0 to 1 and A′, A″, and C are cations and X is an anion; or of the formula A′ 1-y A″ y B x C 1-x X 3 ,
wherein x is from 0 to 1, y is from 0 to 1 and A′, A″, B, and C are cations and X is an anion,
the particles P1 having a weight average particle diameter of between 1 nm and 1 μm and representing at least 1000 ppm of the composition C1 comprising the components a) and b), and
wherein the transparent material M1 comprises a copolymer comprising from 60% to 99.9% by weight of methyl methacrylate and from 0.1% to 40% by weight of at least one monomer chosen from methacrylic acid, methyl acrylate, ethyl acrylate or mixtures thereof.
2. The composition C1 according to claim 1 , wherein the composition C1 comprises between 1000 ppm and 10 wt % by weight of the inorganic particles P1 calculated on the components a) and b).
3. The composition C1 according to claim 1 , wherein the composition C1 comprises between 1.25 wt % and 10 wt % of the inorganic particles P1 calculated on the components a) and b).
4. The composition C1 according to claim 1 , wherein X in all formulas is oxygen O.
5. The composition C1 according to claim 1 , wherein A, A′ or A″ in the formulas are chosen from an alkali metal cation or alkali earth metal cation.
6. The composition C1 according to claim 1 , wherein A, A′ or A″ in the formulas are chosen from metal cations and A′ is different from A″ and is chosen from cations of calcium, strontium or barium.
7. The composition C1 according to claim 1 , wherein the cation C is chosen from a metal cation of an element of UIPAC groups 3 to 7 of the periodic table of elements or from the lanthanides series of chemical elements.
8. The composition C1 according to claim 1 , wherein the cation C is chosen from cations of niobium, tantalum, titanium or zirconium.
9. The composition C1 according to claim 1 , wherein the cation B is chosen a metal cation of an element of UIPAC groups 3 to 7 of the periodic table of elements or from the lanthanides series of chemical elements and is different from C.
10. The composition C1 according to claim 1 , wherein the cation B is chosen from cations of manganese, niobium, tantalum, titanium, zirconium or ytterbium.
11. The composition C1 according to claim 1 , wherein the inorganic compound is BaTiO 3 or Ba 1-y Sr y TiO 3 or BaZr x Ti 1-x O 3 .
12. The composition C1 according to claim 1 , wherein weight average particle size of the inorganic particle P1 is between 5 nm and 950 nm.
13. The composition C1 according to claim 1 , wherein weight average particle size of the inorganic particle P1 is between 30 nm and 900 nm.
14. A process for the preparation of a composition C1 according to claim 1 , wherein the process comprises the steps of
a) providing inorganic particles P1; and
b) incorporating the inorganic particles P1 in the transparent material M1.
15. A process for the preparation of a composition C1 according to claim 1 , wherein the process comprises the steps of
a1) providing inorganic particles P1,
a2) providing the transparent material M1, and
b) incorporating the inorganic particles P1 in the transparent material M1.
16. The process according to claim 15 , wherein the incorporating step is made by blending the inorganic particles P1 with the transparent material M1.
17. A process for the preparation of a composition C2, the process comprising the steps of
a) providing a composition C1 according to claim 1 ; and
b) blending the composition C1 with a transparent material M2,
wherein the composition C2 comprises less than 1000 ppm of inorganic particles P1.
18. A process for manufacturing an article for lighting applications comprising:
a) providing a composition C1 according to claim 1 ; and
b) transforming the composition C1.
19. An article comprising a composition C1 according to claim 1 .
20. The article according to claim 19 , wherein the article is in the form of a sheet, a wedge, a rod or a tube.
21. The article according to claim 19 , where the article is a light guide body or a light guide plate.