ELASTIC MATERIALS PREPARED FROM CURABLE LIQUID COMPOSITIONS

1 . An elastic material, wherein the elastic material has a rebound resilience greater than 10% as measured according to JIS K 6255:1996 and wherein the elastic material is an energy-cured reaction product of a curable composition comprising components a) and b):

a) 30 to 90% by weight, based on the total weight of components a) and b) of at least one urethane (meth)acrylate having a number average molecular weight of at least 4,700 g/mol and comprising oxybutylene units;

b) 10 to 70% by weight, based on the total weight of components a) and b), of at least one (meth)acrylate monomer having one or two (meth)acrylate functional groups per molecule.

2 . The elastic material of claim 1 , wherein the weight content of oxybutylene units in the urethane (meth)acrylate is at least 45% based on the total weight of urethane (meth)acrylate.

3 . The elastic material of claim 1 , wherein component a) comprises a urethane (meth)acrylate having two or more urethane bonds per molecule on average.

4 . The elastic material of claim 1 , wherein component a) comprises a urethane (meth)acrylate having at least one acrylate functional group.

5 . The elastic material of claim 1 , wherein component a) comprises a urethane (meth)acrylate having no more than two (meth)acrylate functional groups per molecule on average.

6 . The elastic material of claim 1 , wherein component a) comprises a urethane (meth)acrylate having a number average molecular weight from 4,700 to 50,000 g/mol.

7 . The elastic material of claim 1 , wherein component a) comprises a urethane (meth)acrylate having a number average molecular weight from 5,500 to 20,000 g/mol.

8 . The elastic material of claim 1 , wherein component a) comprises a urethane (meth)acrylate having the following formula (I):

wherein

each A is independently the residue of a diol and at least one A comprises oxybutylene units;

each R is independently the residue of a diisocyanate;

each B is independently the residue of a hydroxylated mono(meth)acrylate;

each X is independently H or methyl;

n is 1 to 9.

9 . The elastic material of claim 1 , wherein component a) comprises a urethane (meth)acrylate which is the reaction product of one or more diols, one or more diisocyanates and one or more hydroxylated mono(meth)acrylates, wherein at least one diol comprises oxybutylene repeating units.

10 . The elastic material of claim 8 , wherein the diol is a polytetramethylene ether glycol.

11 . The elastic material of claim 8 , wherein the diol has a number average molecular weight of at least 1,100 g/mol.

12 . The elastic material of claim 8 , wherein the diisocyanate is an aliphatic or cycloaliphatic diisocyanate.

13 . The elastic material of claim 1 , wherein component b) comprises a mono(meth)acrylate monomer having a glass transition temperature Tg of more than 20° C., and the mono(meth)acrylate monomer is selected from the group consisting of tert-butylcyclohexyl acrylate, tert-butylcyclohexyl methacrylate, trimethylcyclohexyl acrylate, trimethylcyclohexyl methacrylate, isobornyl acrylate, isobornyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, cyclohexyl methacrylate, benzyl methacrylate, tricyclodecane methanol monoacrylate and mixtures thereof.

14 . The elastic material of claim 1 , wherein component b) comprises a sterically hindered mono(meth)acrylate monomer.

15 . The elastic material of claim 14 wherein the sterically hindered mono(meth)acrylate monomer is selected from tert-butyl (meth)acrylate, 2-phenoxyethyl (meth)acrylate, benzyl (meth)acrylate, isobornyl (meth)acrylate, tert-butyl cyclohexyl (meth)acrylate, 3,3,5-trimethyl cyclohexyl (meth)acrylate, dicyclopentadienyl (meth)acrylate, tricyclodecane methanol mono(meth)acrylate, tetrahydrofurfuryl (meth)acrylate, cyclic trimethylolpropane formyl (meth)acrylate (also referred to as 5-ethyl-1,3-dioxan-5-yl)methyl (meth)acrylate), (2,2-dimethyl-1,3-dioxolan-4-yl)methyl (meth)acrylate, (2-ethyl-2-methyl-1,3-dioxolan-4-yl)methyl (meth)acrylate, glycerol formal methacrylate, the alkoxylated derivatives thereof and mixtures thereof.

16 . The elastic material of claim 1 , wherein component b) comprises at least 80% by weight of mono(meth)acrylate monomer based on the total weight of component b).

17 . The elastic material of claim 1 , wherein component b) comprises at least 10% by weight of mono(meth)acrylate monomer having a glass transition temperature Tg of more than 20° C., based on the total weight of component b).

18 . The elastic material of claim 14 , wherein component b) comprises at least 10% by weight of the sterically-hindered mono(meth)acrylate monomer based on the total weight of component b).

19 . (canceled)

20 . The elastic material of claim 1 , wherein the curable composition further comprises an initiator system.

21 . (canceled)

22 . The elastic material of claim 1 , wherein the curable composition is liquid at 25° C.

23 . (canceled)

24 . The elastic material of claim 1 , wherein the elastic material has an elongation greater than 300% as measured according to JIS K 7127:1999.

25 . The elastic material of claim 1 , wherein the elastic material has a rebound resilience greater than 22% as measured according to JIS K 6255:1996.

26 . The elastic material of claim 1 , wherein the elastic material has a Shore A hardness of at least 15 as measured according to JIS K 6253-3:2012.

27 . A method of making an elastic material having a rebound resilience greater than 10% as measured according to JIS K 6255:1996, comprising curing a curable composition comprising components a) and b):

a) 30 to 90% by weight, based on the total weight of components a) and b), of at least one urethane (meth)acrylate having a number average molecular weight of at least 4,700 g/mol and comprising oxybutylene units;

b) 10 to 70% by weight, based on the total weight of components a) and b), of at least one (meth)acrylate monomer having one or two (meth)acrylate functional groups per molecule.

28 . (canceled)