PRODUCTION PROCESS OF POLYESTER MICROPOWDERS

1 . A process for preparing fine particles of aromatic copolyester (P) comprising the following steps:

a) melt-blending a mixture (M) comprising:

i) at least one aromatic copolyester (P), and

ii) at least one polyester polymer (PE) comprising units derived from:

at least one dicarboxylic acid component,

at least one diol component, wherein at least 2% by moles of the diol component is a poly(alkylene glycol) having a formula (I):

H(O—C m H 2m ) n —OH

wherein m is an integer from 2 to 4 and n varies from 2 to 10,

b) processing the mixture (M) obtained in step a) into pellets or strands,

c) optionally cooling the pellets or strands obtained in step b) at a temperature below 80° C.,

d) contacting the pellets or strands obtained in step b) or c) with water,

e) recovering fine polymeric particles of the at least one aromatic copolyester (P),

f) optionally drying the particles recovered in step e), and

g) optionally sieving the particles obtained in step e) or in step f).

2 . The process of claim 1 , wherein the at least one polyester (PE) is water-soluble or water dispersible.

3 . The process of claim 1 , wherein the polyester (PE) further comprises recurring units from a difunctional monomer containing at least one SO 3 M group attached to an aromatic nucleus, wherein the functional groups are carboxy and wherein M is H or a metal ion selected from the group consisting of sodium, lithium, potassium, and combinations thereof.

4 . The process of claim 1 , wherein the polyester (PE) comprises units from:

at least one aromatic dicarboxylic acid component,

at least one diol component,

at least 1 mol. % (based on the total number of moles in the PE) of poly(alkylene glycol) of formula (I):

H(O—C m H 2m ) n —OH

wherein m is an integer from 2 to 4 and n varies from 2 to 10,

at least one aromatic dicarboxylic acid containing at least one SO 3 M group attached to

an aromatic nucleus, wherein M is H or a metal ion selected from the group consisting of sodium, lithium, potassium, and combinations thereof.

5 . The process of claim 1 , wherein the polyester (PE) comprises:

isophthalic acid,

a diol selected from the group consisting of ethylene glycol, 1,4-cyclohexanedimethanol, propane-1,2-diol, 2,2-dimethyl-1,3-propanediol, and mixtures thereof,

at least 2% by moles (based on the total number of moles in the PE) of poly(alkylene glycol) of diethylene glycol,

an aromatic dicarboxylic acid containing at least one SO 3 M group attached to an aromatic nucleus, wherein M is H or a metal ion selected from the group consisting of sodium, lithium, potassium, and combinations thereof.

6 . The process of claim 1 , wherein the aromatic copolyester (P) is a wholly aromatic polyester that is the reaction product of at least one aromatic polyol, at least one aromatic dicarboxylic acid and at least an aromatic hydroxycarboxylic acid.

7 . The process of claim 1 , wherein the aromatic copolyester (P) is a liquid crystalline polymer (LCP).

8 . The process of claim 1 , wherein the aromatic copolyester (P) is the reaction product of at least one aromatic polyol, terephthalic acid, isophthalic acid and 4-hydroxybenzoic acid.

9 . The process of claim 1 , wherein the aromatic copolyester (P) is the reaction product of at least one aromatic polyol, terephthalic acid and 6-hydroxy-2-naphthoic acid.

10 . The process of claim 1 , wherein the mixture (M) comprises:

a) from 20 to 60% by weight of the aromatic copolyester (P), and

b) from 40 to 80% by weight of the polyester (PE).

11 . The process of claim 1 , wherein the step of melt-blending takes place at a temperature above 300° C.

12 . Fine particles of aromatic copolyester (P) obtainable by the process of claim 1 .

13 . The particles of claim 12 , wherein the particles have a D50 comprised between 0.5 μm and 50 μm.

14 . A method of making coatings and films, the method comprising adding the particles of claim 12 to varnish formulations to make coatings and films.