SUBSTITUTED TOLYL FUNGICIDES AND THEIR MIXTURES

1 . A fungicidal composition comprising:

(a) at least one compound selected from the compounds of Formula 1 (including all stereoisomers), N-oxides, and salts thereof,

wherein

A is a radical selected from the group consisting of

wherein the bond extending to the right is attached to the ring containing Q and the bond extending to the left is attached to the phenyl ring bearing the Y—N(R 3 )C(═W)R 4 substituent;

Q is CR 6 or N;

Y is CR 7a R 7b , O or NR 8 ;

W is O or S;

R 1 and R 2 are each independently halogen, cyano, hydroxy, nitro, amino, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, C 2 -C 6 cyanoalkyl, C 3 -C 6 cycloalkyl, C 3 -C 6 halocycloalkyl, C 4 -C 8 cycloalkylalkyl, C 2 -C 6 alkoxyalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, C 2 -C 6 alkenyloxy, C 2 -C 6 haloalkenyloxy, C 2 -C 6 alkynyloxy, C 2 -C 6 haloalkynyloxy, C 2 -C 6 cyanoalkoxy, C 3 -C 6 cycloalkoxy, C 4 -C 8 cycloalkylalkoxy, C 2 -C 6 alkoxyalkoxy, C 1 -C 6 alkylthio, C 1 -C 6 haloalkylthio, C 1 -C 6 alkylsulfinyl, C 1 -C 6 haloalkylsulfinyl, C 1 -C 6 alkylsulfonyl or C 1 -C 6 haloalkylsulfonyl;

R 3 is H, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, cyclopropyl, C 2 -C 4 alkylcarbonyl, C 2 -C 4 haloalkylcarbonyl, C 2 -C 4 alkoxycarbonyl or C 2 -C 4 haloalkoxycarbonyl;

R 4 is C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylamino or C 2 -C 4 dialkylamino;

each R 5 is independently halogen, cyano, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy or C 1 -C 3 haloalkoxy;

n is 0, 1 or 2;

R 6 is H, halogen, cyano, hydroxy, nitro, amino, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, C 2 -C 6 cyanoalkyl, C 1 -C 6 hydroxyalkyl, C 2 -C 6 alkoxyalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, C 2 -C 6 alkenyloxy, C 2 -C 6 haloalkenyloxy, C 2 -C 6 alkynyloxy, C 2 -C 6 haloalkynyloxy, C 2 -C 6 cyanoalkoxy, C 2 -C 6 alkoxyalkoxy, C 1 -C 6 alkylamino, C 1 -C 6 haloalkylamino, C 2 -C 6 dialkylamino, C 1 -C 6 alkylthio, C 1 -C 6 haloalkylthio, C 1 -C 6 alkylsulfinyl, C 1 -C 6 haloalkylsulfinyl, C 1 -C 6 alkylsulfonyl, C 1 -C 6 haloalkylsulfonyl, —ZC(═O)V, CR 10a ═NOR 10b , ON═CR 11a R 11b , CR 12a ═NNR 12b R 12c or -L-J;

R 7a is H, hydroxy, halogen, cyano, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 2 -C 3 alkoxyalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylsulfinyl or C 1 -C 3 alkylsulfonyl;

R 7b is H, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 2 -C 3 alkoxyalkyl, C 1 -C 3 alkoxy or C 1 -C 3 haloalkoxy;

R 8 is H, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 2 -C 3 alkylcarbonyl or C 2 -C 3 haloalkylcarbonyl;

Z is a direct bond, O, S or NH; or CH 2 optionally substituted with up to 2 substituents independently selected from halogen, methyl or methoxy;

V is R 9 or OR 9 ;

R 9 , R 10b , R 11a and R 12c are each H, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 2 -C 4 alkenyl, C 2 -C 4 haloalkenyl, C 2 -C 4 alkynyl, C 3 -C 6 cycloalkyl, C 3 -C 6 halocycloalkyl or C 4 -C 8 cycloalkylalkyl;

R 10a , R 11b , R 12a and R 12b are each independently H, C 1 -C 3 alkyl or C 1 -C 3 haloalkyl;

L is a direct bond, CH 2 , O, S, NR 13 , OCH 2 , CH 2 O, C(═O), S(═O) or S(═O) 2 ;

J is a 3- to 6-membered nonaromatic carbocyclic ring, wherein up to 3 carbon atom ring members are independently selected from C(═O) and C(═S), each ring optionally substituted with up to 4 substituents independently selected from R 14 ; or

J is a 3- to 6-membered heterocyclic ring, each ring containing ring members selected from carbon atoms and 1 to 4 heteroatoms independently selected from up to 2 O, up to 2 S and up to 4 N atoms, wherein up to 3 carbon atom ring members are independently selected from C(═O) and C(═S), each ring optionally substituted with up to 4 substituents independently selected from R 14 ;

R 13 is H, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 2 -C 3 alkylcarbonyl or C 2 -C 3 haloalkylcarbonyl;

each R 14 is independently halogen, hydroxy, cyano, nitro, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 2 -C 4 alkenyl, C 2 -C 4 haloalkenyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy or C(═O)OR 15 ; and

each R 15 is independently H, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 2 -C 4 alkenyl, C 2 -C 4 haloalkenyl, C 2 -C 4 alkynyl, C 3 -C 6 cycloalkyl or C 3 -C 6 halocycloalkyl; and

(b) at least one additional fungicidal compound.

2 . The composition of claim 1 wherein component (a) comprises a compound of Formula 1 or salt thereof, wherein

A is A-1, A-3 or A-4;

Q is CR 6 ;

Y is CR 7a R 7b ;

W is O;

R 1 and R 2 are each independently halogen, cyano, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 2 -C 4 alkoxyalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 2 -C 4 alkenyloxy, C 2 -C 4 haloalkenyloxy, C 2 -C 4 alkoxyalkoxy or C 1 -C 3 alkylthio;

R 3 is H, methyl, methylcarbonyl or methoxycarbonyl;

R 4 is methyl, methoxy, ethoxy, methylamino or dimethylamino;

each R 5 is independently halogen or methyl;

R 6 is H, halogen, cyano, nitro, amino, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkynyl, C 2 -C 6 alkoxyalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, C 2 -C 6 alkenyloxy, C 2 -C 6 haloalkenyloxy, C 2 -C 6 alkynyloxy, C 2 -C 6 haloalkynyloxy, C 2 -C 6 alkoxyalkoxy, C 1 -C 6 alkylthio, C 1 -C 6 haloalkylthio,

—ZC(═O)V, CR 10a ═NOR 10b , CR 12a ═NNR 12b R 12c or -L-J;

R 7a is H, halogen, methyl or methoxy;

R 7b is H or methyl;

Z is a direct bond, O, NH, CH 2 or CH(OCH 3 );

R 9 , R 10b and R 12c are each H, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 2 -C 4 alkenyl or C 2 -C 4 haloalkenyl;

R 10a , R 12a and R 12b are each independently H, methyl or halomethyl;

L is a direct bond, CH 2 , O, OCH 2 or CH 2 O;

J is selected from J-1 through J-71

wherein the floating bond is connected to L through any available carbon or nitrogen atom of the depicted ring; and x is 0, 1, 2 or 3;

each R 14 is independently halogen, methyl, methoxy or C(═O)OR 15 ; and

each R 15 is independently C 1 -C 3 alkyl, C 1 -C 3 haloalkyl or cyclopropyl.

3 . The composition of claim 2 wherein component (a) comprises a compound of Formula 1 or salt thereof, wherein

A is A-1;

R 1 and R 2 are each independently Br, Cl, F, methyl, trifluoromethyl, methoxy or trifluoromethoxy;

R 3 is H or methyl;

R 4 is methyl, methoxy or ethoxy;

each R 5 is methyl;

R 6 is H, halogen, cyano, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 2 -C 4 alkenyloxy, C 2 -C 4 haloalkenyloxy, C 2 -C 4 alkynyloxy, CR 10a ═NOR 10b or -L-J;

R 7a is H or methyl;

R 10b is H, methyl, ethyl or C 2 -C 4 alkenyl;

R 10a is H or methyl;

L is direct bond or O;

J is J-53, J-58, J-59, J-60, J-65, J-66, J-67 or J-68; and

each R 14 is independently halogen or methyl.

4 . The composition of claim 3 wherein component (a) comprises a compound of Formula 1 or salt thereof, wherein

R 1 and R 2 are each independently C 1 or F;

R 3 is H;

R 4 is methoxy;

n is 0;

R 6 is Br, Cl, methyl, i-propyl, CHF 2 , trifluoromethyl, methoxy, ethoxy, i-propyloxy, trifluoromethoxy, OCH 2 C≡CH, C(Me)═NOCH 3 or -L-J;

R 7a is H;

R 7b is H;

L is a direct bond; and

J is J-58, J-66 or J-67.

5 . The composition of claim 4 wherein component (a) comprises a compound of Formula 1 or salt thereof, wherein

R 1 and R 2 are each F;

R 6 is Br, Cl, methyl, i-propyl, CHF 2 , trifluoromethyl, i-propyloxy, C(CH 3 )═NOCH 3 or -L-J;

J is J-66;

x is 0, 1 or 2; and

R 14 is Br, Cl, F or methyl.

6 . The composition of claim 5 wherein component (a) comprises a compound of Formula 1 or salt thereof, wherein

R 6 is C 1 , i-propyl, trifluoromethyl or -L-J; and

x is 0.

7 . The composition of claim 1 wherein component (a) comprises a compound selected from the group consisting of

methyl N-[[5-[1-(2,6-difluoro-4-nitrophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(2,6-difluorophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]-methyl]carbamate;

methyl N-[[5-[1-(4-amino-2,6-difluorophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(4-chloro-2,6-difluorophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(4-bromo-2,6-difluorophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(2,6-difluoro-4-iodophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(2,6-difluoro-4-hydroxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(4-ethoxy-2,6-difluorophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[4-(cyclobutyloxy)-2,6-difluorophenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[2,6-difluoro-4-(1-methylethoxy)phenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[4-(difluoromethoxy)-2,6-difluorophenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[2,6-difluoro-4-(2-propyn-1-yloxy)phenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(4-cyclopropyl-2,6-difluorophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[4-[(1,1-dimethylethyl)thio]-2,6-difluorophenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[4-[(difluoromethyl)thio]-2,6-difluorophenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(4-ethynyl-2,6-difluorophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[2,6-difluoro-4-(1-methylethyl)phenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[2,6-difluoro-4-(trifluoromethyl)phenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(2,6-dichloro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[4-(cyclopropyloxy)-2,6-difluorophenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(2,6-difluoro-4-formylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(4-acetyl-2,6-difluorophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl 3,5-difluoro-4-[3-[3-1[[(methoxycarbonyl)amino]methyl]-4-methylphenyl]-1H-pyrazol-1-yl]benzoate;

methyl N-[[5-[1-[2,6-difluoro-4-(hydroxymethyl)phenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[2,6-difluoro-4-(trifluoromethoxy)phenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl (E)-N-[[5-[1-[2,6-difluoro-4-[1-(methoxyimino)ethyl]phenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[4-(difluoromethyl)-2,6-difluorophenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[4-(2,2-difluorocyclopropyl)-2,6-difluorophenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[4-[(1,1-dimethylethoxy)-2,6-difluorophenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl (Z)-N-[[5-[1-[2,6-difluoro-4-[1-(methoxyimino)ethyl]phenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[2-[2,6-difluoro-4-(1-methylethyl)phenyl]-2H-1,2,3-triazol-4-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[2-[2,6-difluoro-4-methylphenyl]-2H-1,2,3-triazol-4-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[2-[4-cyclopropyl-2,6-difluorophenyl)-2H-1,2,3-triazol-4-yl)-2-methylbenzyl)carbamate;

methyl N-[[5-[2-(4-amino-2,6-difluorophenyl)-2H-1,2,3-triazol-4-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[2-(4-chloro-2,6-difluorophenyl)-2H-1,2,3-triazol-4-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[2-(2,6-difluoro-4-nitrophenyl)-2H-1,2,3-triazol-4-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(4-chloro-2,6-difluorophenyl)-1H-1,2,3-triazol-4-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(4-amino-2,6-difluorophenyl)-1H-1,2,3-triazol-4-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(2,6-difluoro-4-nitrophenyl)-1H-1,2,3-triazol-4-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[4-(1,3-dioxan-2-yl)-2,6-difluorophenyl)]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[2,6-dichloro-4-(1,1-dimethylethyl)phenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl (E)-N-[[5-[2-[2,6-difluoro-4-[1-(methoxyimino)ethyl]phenyl]-2H-1,2,3-triazol-4-yl]-2-methylphenyl]methyl]carbamate; and

methyl N-[[5-[2-[2,6-difluoro-4-(1-methylpropyl)phenyl]-2H-1,2,3-triazol-4-yl]-2-methylphenyl]methyl]carbamate.

8 . The composition of claim 7 wherein component (a) comprises a compound selected from the group consisting of

methyl N-[[5-[1-(4-chloro-2,6-difluorophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-(4-cyclopropyl-2,6-difluorophenyl)-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate;

methyl N-[[5-[1-[2,6-difluoro-4-(1-methylethyl)phenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate; and

methyl N-[[5-[1-[2,6-difluoro-4-(trifluoromethyl)phenyl]-1H-pyrazol-3-yl]-2-methylphenyl]methyl]carbamate.

9 . The composition of any one of claims 1 through 8 wherein component (b) includes at least one fungicidal compound selected from the group consisting of:

(b1) methyl benzimidazole carbamate (MBC) fungicides;

(b2) dicarboximide fungicides;

(b3) demethylation inhibitor (DMI) fungicides;

(b4) phenylamide (PA) fungicides;

(b5) amine/morpholine fungicides;

(b6) phospholipid biosynthesis inhibitor fungicides;

(b7) succinate dehydrogenase inhibitor (SDHI) fungicides;

(b8) hydroxy(2-amino)pyrimidine fungicides;

(b9) anilinopyrimidine (AP) fungicides;

(b10) N-phenyl carbamate fungicides;

(b11) quinone outside inhibitor (QoI) fungicides;

(b12) phenylpyrrole (PP) fungicides;

(b13) azanaphthalene fungicides;

(b14) cell peroxidation inhibitor fungicides;

(b15) melanin biosynthesis inhibitor-reductase (MBI-R) fungicides;

(b16a) melanin biosynthesis inhibitor-dehydratase (MBI-D) fungicides;

(b16b) melanin biosynthesis inhibitor-polyketide synthase (MBI-P) fungicides;

(b17) keto reductase inhibitor (KRI) fungicides;

(b18) squalene-epoxidase inhibitor fungicides;

(b19) polyoxin fungicides;

(b20) phenylurea fungicides;

(b21) quinone inside inhibitor (QiI) fungicides;

(b22) benzamide and thiazole carboxamide fungicides;

(b23) enopyranuronic acid antibiotic fungicides;

(b24) hexopyranosyl antibiotic fungicides;

(b25) glucopyranosyl antibiotic: protein synthesis fungicides;

(b26) glucopyranosyl antibiotic fungicides;

(b27) cyanoacetamide-oxime fungicides;

(b28) carbamate fungicides;

(b29) oxidative phosphorylation uncoupling fungicides;

(b30) organo tin fungicides;

(b31) carboxylic acid fungicides;

(b32) heteroaromatic fungicides;

(b33) phosphonate fungicides;

(b34) phthalamic acid fungicides;

(b35) benzotriazine fungicides;

(b36) benzene-sulfonamide fungicides;

(b37) pyridazinone fungicides;

(b38) thiophene-carboxamide fungicides;

(b39) complex I NADH oxidoreductase inhibitor fungicides;

(b40) carboxylic acid amide (CAA) fungicides;

(b41) tetracycline antibiotic fungicides;

(b42) thiocarbamate fungicides;

(b43) benzamide fungicides;

(b44) microbial fungicides;

(b45) quinone outside inhibitor, stigmatellin binding (QoSI) fungicides;

(b46) plant extract fungicides;

(b47) cyanoacrylate fungicides;

(b48) polyene fungicides;

(b49) oxysterol binding protein inhibitor (OSBPI) fungicides;

(b50) aryl-phenyl-ketone fungicides;

(b51) host plant defense induction fungicides;

(b52) multi-site activity fungicides;

(b53) biologicals with multiple modes of action;

(b54) fungicides other than fungicides of component (a) and components (b1) through (b53); and

salts of compounds of (b1) through (b54).

10 . The composition of claim 9 wherein component (b) comprises at least one fungicidal compound from each of two different groups selected from (b1) through (b54).

11 . The composition of any one of claims 1 through 10 wherein component (b) includes at least one compound selected from acibenzolar-S-methyl, aldimorph, ametoctradin, amisulbrom, anilazine, azaconazole, azoxystrobin, benalaxyl, benalaxyl-M, benodanil, benomyl, benthiavalicarb, benthiavalicarb-isopropyl, bethoxazin, binapacryl, biphenyl, bitertanol, bixafen, blasticidin-S, boscalid, bromuconazole, bupirimate, carboxin, carpropamid, captafol, captan, carbendazim, chloroneb, chlorothalonil, chlozolinate, clotrimazole, copper salts, cyazofamid, cyflufenamid, cymoxanil, cyproconazole, cyprodinil, dichlofluanid, diclocymet, diclomezine, dicloran, diethofencarb, difenoconazole, diflumetorim, dimethirimol, dimethomorph, dimoxystrobin, diniconazole, diniconazole-M, dinocap, dithianon, dodemorph, dodine, edifenphos, enestroburin, epoxiconazole, ethaboxam, ethirimol, etridiazole, famoxadone, fenamidone, fenarimol, fenbuconazole, fenfuram, fenhexamid, fenoxanil, fenpiclonil, fenpropidin, fenpropimorph, fenpyrazamine, fentin acetate, fentin chloride, fentin hydroxide, ferbam, ferimzone, fluazinam, fludioxonil, flumetover, flumorph, fluopicolide, fluopyram, fluoroimide, fluoxastrobin, fluquinconazole, flusilazole, flusulfamide, flutianil, flutolanil, flutriafol, fluxapyroxad, folpet, fosetyl-aluminum, fuberidazole, furalaxyl, furametpyr, hexaconazole, hymexazol, guazatine, imazalil, imibenconazole, iminoctadine, iodocarb, ipconazole, ipfentrifluconazole, iprobenfos, iprodione, iprovalicarb, isoprothiolane, isopyrazam, isotianil, kasugamycin, kresoxim-methyl, mancozeb, mandipropamid, maneb, mepronil, meptyldinocap, metalaxyl, metalaxyl-M, metconazole, methasulfocarb, metiram, metominostrobin, mepanipyrim, metrafenone, myclobutanil, naftifine, neo-asozin (ferric methanearsonate), nuarimol, octhilinone, ofurace, orysastrobin, oxadixyl, oxolinic acid, oxpoconazole, oxycarboxin, oxytetracycline, penconazole, pencycuron, penflufen, penthiopyrad, pefurazoate, phosphorous acid and salts thereof, phthalide, picoxystrobin, piperalin, polyoxin, probenazole, prochloraz, procymidone, propamocarb, propamocarb-hydrochloride, propiconazole, propineb, proquinazid, prothiocarb, prothioconazole, pydiflumetofen, pyraclostrobin, pyrametostrobin, pyraoxystrobin, pyrazophos, pyribencarb, pyributicarb, pyrifenox, pyrimethanil, pyriofenone, pyrisoxazole, pyroquilon, pyrrolnitrin, quinomethionate, quinoxyfen, quintozene, sedaxane, silthiofam, simeconazole, spiroxamine, streptomycin, sulfur, tebuconazole, tebufloquin, tecloftalam, tecnazene, terbinafine, tetraconazole, thiabendazole, thifluzamide, thiophanate, thiophanate-methyl, thiram, tiadinil, tolclofos-methyl, tolylfluanid, tolnifanide, triadimefon, triadimenol, triazoxide, tricyclazole, tridemorph, triflumizole, tricyclazole, trifloxystrobin, triforine, trimorphamide, triticonazole, uniconazole, validamycin, valifenalate, vinclozolin, zineb, ziram, zoxamide, N-[4-[4-chloro-3-(trifluoromethyl)phenoxy]-2,5-dimethylphenyl]-N-ethyl-N-methylmethanimidamide, 5-chloro-6-(2,4,6-trifluorophenyl)-7-(4-methylpiperidin-1-yl)[1,2,4]triazolo[1,5a]pyrimidine (DPX-BAS600F), N-[2-[4-[[3-(4-chlorophenyl)-2-propyn-1-yl]oxy]-3-methoxyphenyl]ethyl]-3-methyl-2-[(methylsulfonyl)amino]butanamide, N-[2-[4-[[3-(4-chloro-phenyl)-2-propyn-1-yl]oxy]-3-methoxyphenyl]ethyl]-3-methyl-2-[(ethylsulfonyl)amino]-butanamide, 4-fluorophenyl N-[1-[[[1-(4-cyanophenyl)ethyl]sulfonyl]-methyl]propyl]carbamate, α-(methoxyimino)-N-methyl-2-[[[1-[3-(trifluoro-methyl)phenyl]ethoxy]imino]methyl]benzeneacetamide, N-[4-[4-chloro-3-(trifluoro-methyl)phenoxy]-2,5-dimethylphenyl]-N-ethyl-N-methylmethanimidamide, 2-[[[[3-(2,6-dichlorophenyl)-1-methyl-2-propen-1-ylidene]amino]oxy]methyl]-α-(methoxyimino)-N-methylbenzeneacetamide and 1-[(2-propenylthio)carbonyl]-2-(1-methylethyl)-4-(2-methylphenyl)-5-amino-1H-pyrazol-3-one, 5-ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine.

12 . The composition of claim 11 wherein component (b) includes at least one compound selected from azoxystrobin, benzovindiflupyr, bixafen, chlorothalonil, cyproconazole, difenoconazole, epoxiconazole, fenpropimorph, fluindapyr, flutriafol, fluxapyroxad, manzate, picoxystrobin, prothioconazole, pydiflumetofen, pyraclostrobin, tebuconazole and trifloxystrobin.

13 . A composition comprising the composition of any one of claims 1 through 12 and at least one additional component selected from the group consisting of surfactants, solid diluents and liquid diluents.

14 . A method for protecting a plant or plant seed from diseases caused by fungal pathogens comprising applying a fungicidally effective amount of the composition of any one of claims 1 through 13 to the plant or plant seed.

15 . A method for protecting a plant from a rust disease comprising applying to the plant or plant seed a fungicidally effective amount of the composition of any one of claims 1 through 13 wherein component (b) includes at least one fungicidal compound selected from (b3) demethylation inhibitor fungicides, (b5) amine/morpholine fungicides, (b7) succinate dehydrogenase inhibitor fungicides, (b11) quinone outside inhibitor (QoI) fungicides and (b52) multi-site activity fungicides.