Stabilized Heat Transfer Fluid Compositions
The present application provides stabilized compositions (e.g., stabilized heat transfer fluids) comprising methyl perfluoroheptene for use, for example, in refrigeration and heat transfer applications. The stabilized compositions of the present invention are useful in methods for producing cooling and heating, methods for replacing refrigerants and refrigeration, air conditioning, heat pump apparatuses, and as solvents or dewatering agents.
1 . A composition, comprising:
i) methyl perfluoroheptene ether; and
ii) a second component selected from the group consisting of butylated hydroxy toluene, hydroquinone monomethyl ether, 2-tert-butyl-6-methylphenol, 2-tert-butyl-5-methylphenol and 2-tert-butyl-4-ethylphenol 1,3-dioxolane, 1,2-epoxybutane and nitromethane, or any mixture thereof.
2 . The composition of claim 1 , wherein the second component is present in the composition in an amount effective to maintain a total acid number of the composition at about 0.1 mg KOH/g, or less.
3 . The composition of claim 2 , wherein the methyl perfluoroheptene ether comprises a mixture of about 50 weight percent 5-methoxy perfluoro-3-heptene, about 20 weight percent 3-methoxy perfluoro-3-heptene, about 20 weight percent 4-methoxy perfluoro-2-heptene, and about 8 weight percent 4-methoxy perfluoro-3-heptene.
4 . The composition of claim 3 , wherein the second component is selected from the group consisting of butylated hydroxy toluene and hydroquinone monomethyl ether.
5 . The composition of claim 5 , wherein the composition comprises about 100 ppm to about 550 ppm of the second component.
6 . The composition of claim 4 , wherein the second component is selected from the group consisting of:
butylated hydroxy toluene;
hydroquinone monomethyl ether;
2-tert-butyl-6-methylphenol;
2-tert-butyl-5-methylphenol;
2-tert-butyl-4-ethylphenol;
a mixture of butylated hydroxy toluene and 1,2-epoxybutane;
a mixture of hydroquinone monomethyl ether and 1,3-dioxolane;
a mixture of hydroquinone monomethyl ether and 1,2-epoxybutane;
a mixture of butylated hydroxy toluene and 1,3-dioxolane;
a mixture of 2-tert-butyl-6-methylphenol and 1,2-epoxybutane; and
a mixture of 2-tert-butyl-6-methylphenol and nitromethane.
7 . The composition of claim 6 , wherein the composition comprises about 100 ppm to about 1100 ppm of the second component.
8 . The composition of claim 6 , wherein the composition comprises methyl perfluoroheptene ether; and
about 450 ppm to about 550 ppm butylated hydroxy toluene; or
about 100 ppm to about 200 ppm hydroquinone monomethyl ether; or
about 400 ppm to about 550 ppm butylated hydroxy toluene and about 450 ppm to about 550 ppm 1,2-epoxybutane; or
about 100 ppm to about 200 ppm hydroquinone monomethyl ether and about 450 ppm to about 550 ppm 1,3-dioxolane; or
about 100 ppm to about 200 ppm hydroquinone monomethyl ether and about 450 ppm to about 550 ppm 1,2-epoxybutane; or
about 450 ppm to about 550 ppm butylated hydroxy toluene and about 450 ppm to about 550 ppm 1,3-dioxolane; or
about 50 to about 500 ppm 2-tert-butyl-6-methylphenol; or
about 50 to about 500 ppm 2-tert-butyl-5-methylphenol; or
about 50 to about 500 ppm 2-tert-butyl-4-ethylphenol; or
about 50 to about 500 ppm 2-tert-butyl-6-methylphenol and about 200 to about 600 ppm 1,2-epoxybutane; or
about 50 to about 500 ppm 2-tert-butyl-6-methylphenol and about 200 to about 600 ppm nitromethane; or
about 300 ppm 2-tert-butyl-6-methylphenol; or
about 300 ppm 2-tert-butyl-5-methylphenol; or
about 300 ppm 2-tert-butyl-4-ethylphenol; or
about 300 ppm 2-tert-butyl-6-methylphenol and about 400 ppm 1,2-epoxybutane; or
about 300 ppm 2-tert-butyl-6-methylphenol and about 400 ppm nitromethane.
9 . The composition of claim 6 , wherein the composition comprises methyl perfluoroheptene ether; and
about 140 ppm hydroquinone monomethyl ether; or
about 500 ppm butylated hydroxy toluene; or
about 140 ppm hydroquinone monomethyl ether and about 500 ppm 1,2-epoxybutane; or
about 500 ppm butylated hydroxy toluene and about 500 ppm 1,2-epoxybutane; or
about 500 ppm butylated hydroxy toluene and about 500 ppm 1,3-dioxolane
about 140 ppm hydroquinone monomethyl ether and about 500 ppm 1,3-dioxolane; or
about 450 ppm butylated hydroxy toluene and about 500 ppm 1,2-epoxybutane.
10 . A method of reducing acidic degradation of a working fluid comprising methyl perfluoroheptene ether, comprising mixing the working fluid with a second component selected from the group consisting of one or more antioxidants and one or more acid scavengers, or any mixture thereof, thereby forming a stabilized working fluid.
11 . The method of claim 10 , wherein the second component selected from the group consisting of one or more antioxidants.
12 . The method of claim 10 , wherein the second component is selected from the group consisting of butylated hydroxy toluene, hydroquinone monomethyl ether, 2-tert-butyl-6-methylphenol, 2-tert-butyl-5-methylphenol and 2-tert-butyl-4-ethylphenol, or a mixture thereof.
13 . The method of claim 10 , wherein the second component is selected from the group consisting of:
butylated hydroxy toluene;
hydroquinone monomethyl ether;
2-tert-butyl-6-methylphenol;
2-tert-butyl-5-methylphenol;
2-tert-butyl-4-ethylphenol;
a mixture of butylated hydroxy toluene and 1,2-epoxybutane;
a mixture of hydroquinone monomethyl ether and 1,3-dioxolane;
a mixture of hydroquinone monomethyl ether and 1,2-epoxybutane;
a mixture of butylated hydroxy toluene and 1,3-dioxolane;
a mixture of 2-tert-butyl-6-methylphenol and 1,2-epoxybutane; and
a mixture of 2-tert-butyl-6-methylphenol and nitromethane.
14 . A process for dissolving a solute, comprising contacting and mixing said solute with a sufficient quantity of the composition of claim 1 .
15 . A process of cleaning a surface, comprising contacting the composition of claim 1 with said surface.
16 . A process for removing at least a portion of water from the surface of a wetted substrate, comprising contacting the substrate with the composition of claim 1 , and then removing the substrate from contact with the composition.
17 . The process of claim 16 , wherein composition further comprises at least one surfactant suitable for dewatering or drying the substrate.
18 . A process of depositing a fluorolubricant on a surface, comprising:
a) combining a fluorolubricant and a solvent to form a lubricant-solvent combination, wherein the solvent comprises a composition of claim 1 ;
b) contacting the lubricant-solvent combination with the surface; and
c) evaporating the solvent from the surface to form a fluorolubricant coating on the surface.
19 . A process for producing cooling, comprising condensing the composition of claim 1 and thereafter evaporating said composition in the vicinity of a body to be cooled.
20 . A process for producing heating, comprising evaporating the composition of claim 1 and thereafter condensing said composition in the vicinity of a body to be heated.
21 . A method for producing cooling, comprising circulating a heat transfer fluid comprising a composition of claim 1 in the vicinity of a body to be cooled, wherein the heat transfer fluid is a working fluid that removes heat from, adds heat to, or maintains temperature of the vicinity of the body to be cooled.
22 . A method of replacing a heat transfer fluid in a cooling fluid distribution unit, a refrigeration system, or a heat pump system, comprising providing the composition of claim 1 as replacement for said heat transfer fluid.
23 . The method of claim 22 , wherein the refrigeration system or heat pump system comprises a single-phase chiller.
24 . The method of claim 23 , wherein the chiller is a single phase semi-conductor chiller.