HYDROPHIBIC CARBON-DOTS FOR OIL TRACERS
A composition that includes an oil-soluble carbon dot and an organic fluid is provided. The oil-soluble carbon dot includes a transition metal, a rare earth element, or a combination of both. A method of making the oil-soluble carbon dot is also provided. The method includes combining an organic reactant, an amine, a dehydrating agent, and a hydrophobic organometallic compound to form a mixture, and heating the mixture such that the oil-soluble carbon dot forms. A method of determining a flow characteristic of a formation or an attribute of a fluid in a formation using the oil-soluble carbon dots is also provided.
1 . A composition comprising:
an oil-soluble carbon dot comprising an element selected from the group consisting of a transition metal, a rare earth element, and combinations thereof; and
an organic fluid.
2 . The composition of claim 1 , wherein the oil-soluble carbon dot has an average diameter ranging from 2 to 100 nm.
3 . The composition of claim 1 , wherein the carbon dot is spherical.
4 . The composition of claim 1 , wherein the carbon dot is fluorescent under ultraviolet light.
5 . The composition of claim 1 , wherein the element is a transition metal selected from the group consisting of Sc 3+ , Ti 3+ , V 4+ , Cr 3+ , Mn 3+ , Fe 3+ , Co 3+ , Ni 2+ , Cu 2+ , Zn 2+ , Ga 3+ , Ge 4+ , Sr 2+ , Y 2+ , Zr 4+ , Nb 3+ , Ru 4+ , Pd 2+ , Cd 2+ , Sn 4+ , Hf 4+ , Bi 3+ , and combinations thereof.
6 . The composition of claim 1 , wherein the element is a rare earth element selected from the group consisting of La 3+ , Ce 3+ , Ce 4+ , Pr 3+ , Nd 3+ , Pm 3+ , Sm 3+ Eu 3+ , Gd 3+ , Tb 3+ , Dy 3+ , Ho 3+ , Er 3+ , Tm 3+ , Yb 3+ , Lu 3+ , Th 3+ , U 4+ , and combinations thereof.
7 . The composition of claim 1 , wherein the element is present in the carbon dot in an amount ranging from 0.5 wt. % to 50 wt. %, based on a total weight of the carbon dot.
8 . The composition of claim 1 , wherein the organic fluid is crude oil.
9 . A method of preparing an oil-soluble carbon dot comprising:
combining an organic reactant, a diamine, a dehydrating agent, and a hydrophobic organometallic compound to form a mixture, wherein the hydrophobic organometallic compound comprises an element selected from the group consisting of a transition metal, a rare earth element, and combinations thereof; and
heating the mixture such that the oil-soluble carbon dot forms.
10 . The method of claim 9 , wherein the organic reactant is selected from the group consisting of citric acid, glucose, and combinations thereof.
11 . The method of claim 9 , wherein the diamine is selected from the group consisting of 1,4-diaminobutane, 4-amino-1-butanol, 1,3-diaminopropane, 3-amino-1-propanol, 1,2-diaminoethane, ethanolamine, 1,2-diaminobenzene, 1,3-diaminobenzene, 1,4-diaminobenzene, 1-amino-2-hydroxybenzene, 1-amino-3-hydroxybenzene, and 1-amino-4-hydroxybenzene, and combinations thereof.
12 . The method of claim 9 , wherein the dehydrating agent is a carbodiimide compound selected from the group consisting of N,N′-Diisopropylcarbodiimide, dicyclohexylcarbodiimide, and combinations thereof.
13 . The method of claim 9 , wherein the hydrophobic organometallic compound further comprises a hydrophobic ligand.
14 . The method of claim 13 , wherein the hydrophobic ligand is a β-diketone selected from the group consisting of acetylacetone, hexafluoroacetylacetone, 3,5-heptanedione, 2,2,6,6-tetramethyl-3,5-heptanedione, 1-(Thiophen-2-yl)butane-1,3-dione, 4,4,4-Trifluoro-1-(2-thienyl)-1,3-butanedione, 4,4,4-Trifluoro-1-(2-furyl)-1,3-butanedione, 1-Phenyl-1,3-butanedione, 4,4,4-Trifluoro-1-phenyl-1,3-butanedione, 4,4,4-Trifluoro-1-(4-methylphenyl)butane-1,3-dione, 4,4,4-Trifluoro-1-(2-naphthyl)-1,3-butanedione, 1,3-Diphenyl-1,3-propanedione, 1,3-Di(2-pyridyl)-1,3-propanedione, and combinations thereof.
15 . The method of claim 9 , wherein the element is a transition metal selected from the group consisting of Sc 3+ , Ti 3+ , V 4+ , Cr 3+ , Mn 3+ , Fe 3+ , Co 3+ , Ni 2+ , Cu 2+ , Zn 2+ , Ga 3+ , Ge 4+ , Sr 2+ , Y 2+ , Zr 4+ , Nb 3+ , Ru 4+ , Pd 2+ , Cd 2+ , Sn 4+ , Hf 4+ , Bi 3+ , and combinations thereof.
16 . The method of claim 9 , wherein the element is a rare earth element selected from the group consisting of La 3+ , Ce 3+ , Ce 4+ , Pr 3+ , Nd 3+ , Pm 3+ , Sm 3+ Eu 3+ , Gd 3+ , Tb 3+ , Dy 3+ , Ho 3+ , Er 3+ , Tm 3+ , Yb 3+ , Lu 3+ , Th 3+ , U 4+ , and combinations thereof.
17 . A method of determining a flow characteristic of a formation or an attribute of a fluid in a formation, comprising:
introducing an injection fluid comprising one or more oil-soluble carbon dots into an injection well associated with a formation at a first location;
recovering produced fluid from a production well associated with the formation at a second location;
detecting the presence of the one or more of oil-soluble carbon dots in the produced fluids; and
determining at least one flow characteristic of the formation or an attribute of the fluid in the formation between the first and the second location based upon the detection of the one or more oil-soluble carbon dots.
18 . The method of claim 17 , wherein the oil-soluble carbon dots comprise an element selected from the group consisting of a transition metal, a rare earth element, and combinations thereof.
19 . The method of claim 17 , wherein the presence of the one or more oil-soluble carbon dots is detected using at least one of fluorescence spectroscopy, inductively coupled plasma atomic emission spectroscopy, and inductively coupled plasma mass spectrometry.