Mapping inter-well porosity using tracers with different transport properties

1. A method for mapping inter-well porosity comprising:

injecting a Type 1 tracer into a hydrocarbon-bearing reservoir via an injector well, wherein the Type 1 tracer is a passive tracer;

injecting a Type 2 tracer into the hydrocarbon-bearing reservoir via the injector well, wherein the Type 2 tracer is a porosity-sensitive tracer;

detecting a breakthrough of the Type 1 tracer and a breakthrough of the Type 2 tracer in produced fluid at a producer well; and

comparing the breakthrough of the Type 1 tracer with the breakthrough of the Type 2 tracer to provide a map of inter-well porosity.

2. The method of claim 1 , wherein the Type 1 tracer is selected from the group consisting of dipicolinic acid (DPA), 4,7-bis(sulfonatophenyl)-1,10-phenanthroline-2,9-dicarboxylic acid (BSPPDA), 2-fluorobenzoic acid, 3-fluorobenzoic acid, 4-fluorobenzoic acid, 2,3-difluorobenzoic acid, 2,4-difluorobenzoic acid, 2,5-difluorobenzoic acid, 3,4-difluorobenzoic acid, sodium thiocyanate (NaSCN), sodium bromide (NaBr), and combinations thereof.

3. The method of claim 1 , wherein the Type 1 tracer doesn't degrade in at least 100° C. for 3 to 6 months.

4. The method of claim 1 , wherein the Type 2 tracer is a polymer having a polydispersity ranging from 1.0 to 1.5.

5. The method of claim 4 , wherein the polymer has a molecular weight (Mw) ranging from 30,000 Da to 20,000,000 Da.

6. The method of claim 1 , wherein the Type 2 tracer has a size that is larger than an inaccessible pore volume (IPV) in the hydrocarbon-bearing reservoir, wherein the IPV ranges from 10 to 50% of a total pore volume in the hydrocarbon-bearing reservoir.

7. The method of claim 1 , wherein the Type 2 tracer is a polymer prepared via a controlled/living radical polymerization technique selected from the group consisting of reversible addition-fragmentation chain-transfer (RAFT), atom transfer radical polymerization (ATRP), activator regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP), and combinations thereof.

8. The method of claim 1 , wherein the Type 2 tracer is a brine soluble polymer.

9. The method of claim 1 , wherein the Type 2 tracer is a polymer including monomers selected from the group selected from saccharides, sulfonated monomers, hydroxylated monomers, zwitterionic monomers, fluorinated monomers, and combinations thereof.

10. The method of claim 1 , wherein the Type 2 tracer comprises a zwitterionic/fluorinated copolymer selected from the group consisting of poly(1-vinyl imidazole-co-4-trifluoromethylstyrene), poly(3-(1-vinyl-1H-imidazol-3-ium-3-yl)propane-1-sulfonate-co-4-trifluoromethylstyrene), and poly(3-(1-vinyl-1H-imidazol-3-ium-3-yl)propane-1-sulfonate), and combinations thereof.

11. The method of claim 1 , wherein the Type 2 tracer doesn't degrade in at least 100° C. for 3 to 6 months.

12. The method of claim 1 , wherein the breakthrough of the Type 1 tracer is slower than the breakthrough of the Type 2 tracer.

13. The method of claim 1 , wherein the detecting a breakthrough of the Type 1 tracer and a breakthrough of the Type 2 tracer in produced fluid is performed by standard analytical chemistry techniques selected from the group consisting of solid phase extraction (SPE), gas chromatography-mass spectroscopy (GC-MS), high performance liquid chromatography (HPLC), and combinations thereof.

14. The method of claim 1 , wherein the comparing the breakthrough of the Type 1 tracer and the breakthrough of the Type 2 tracer is performed using an Ensemble Smoother with Multiple Data Assimilation with Tracers (ES-MDA-Tracer) algorithm.

15. A method of reconstructing inter-well porosity of a hydrocarbon-bearing reservoir using Type 1 tracer breakthrough data and Type 2 tracer breakthrough data, the method comprising:

obtaining an initial reservoir model;

performing reservoir simulation using the initial reservoir model to predict hydrocarbon production rate, water production rate, Type 1 tracer breakthrough data, and Type 2 breakthrough data from a producer well;

obtaining a real field hydrocarbon production rate, real water production rate, real Type 1 tracer breakthrough data, and real Type 2 tracer breakthrough data from the producer well; and

performing data assimilation by comparing real field production, real field Type 1 tracer breakthrough data, and real field Type 2 tracer breakthrough data with the predicted production, the predicted Type 1 tracer breakthrough data, and the predicted Type 2 tracer breakthrough data obtained from the reservoir simulation using the initial reservoir model.

16. The method of claim 15 , wherein the Type 1 tracer is a passive tracer.

17. The method of claim 15 , wherein the Type 2 tracer is a porosity-sensitive tracer.

18. The method of claim 15 , wherein the Type 1 tracer breakthrough is slower than the Type 2 tracer breakthrough.