Solvent mixtures for downhole elemental sulfur removal and formation stimulation
View Patent ↗Solvent mixtures for downhole elemental sulfur removal and formation stimulation, and methods for utilizing such solvent mixtures, are described herein. One method includes providing a solvent mixture that includes an elemental sulfur solvent fraction and an odorant fraction that includes a lactate ester solvent. The method also includes injecting the solvent mixture into a hydrocarbon well such that the elemental sulfur solvent fraction of the solvent mixture dissolves elemental sulfur deposited on well components, and contacting the solvent mixture with water such that the lactate ester solvent within the odorant fraction reacts with the water to generate lactic acid. The method further includes stimulating a formation through which the hydrocarbon well extends by flowing the solvent mixture including the lactic acid through the hydrocarbon well and into the formation.
1. A solvent mixture, the solvent mixture having a mixture odor and comprising:
an elemental sulfur solvent fraction comprising at least one elemental sulfur solvent with a solvent odor and a solvent sulfur solubility of at least 10 weight percent (wt %) at standard temperature and pressure (STP); and
an odorant fraction comprising at least one odorant with an odorant odor that differs from the solvent odor, wherein the at least one odorant comprises at least 20 wt % and at most 70 wt % of a lactate ester solvent;
wherein the elemental sulfur solvent fraction forms at least 20 wt % and at most 80 wt % of the solvent mixture, and the odorant fraction forms at least 20 wt % and at most 80 wt % of the solvent mixture;
wherein the presence of the odorant fraction within the solvent mixture decreases at least one of an intensity or an offensiveness of the mixture odor relative to the solvent odor; and
wherein the lactate ester solvent within the odorant fraction reacts with water to form lactic acid.
2. The solvent mixture of claim 1 , wherein the lactate ester solvent comprises at least one of ethyl lactate or methyl lactate.
3. The solvent mixture of claim 1 , wherein the solvent mixture further comprises at least 5 wt % and at most 20 wt % water.
4. The solvent mixture of claim 1 , wherein the at least one odorant within the odorant fraction also comprises at least 5 wt % and at most 15 wt % of a catalyst that increases a reaction rate between the lactate ester solvent and the water.
5. The solvent mixture of claim 1 , wherein the elemental sulfur solvent fraction comprises dimethyl disulfide (DMDS).
6. The solvent mixture of claim 5 , wherein the DMDS comprises at least 20 wt % and at most 40 wt % of the elemental sulfur solvent fraction.
7. The solvent mixture of claim 1 , wherein the odorant fraction further comprises at least one of:
at least 5 wt % and at most 15 wt % acetone; or
at least 10 wt % and at most 30 wt % methyl ethyl ketone (MEK).
8. The solvent mixture of claim 1 , wherein the odorant fraction further comprises at least 3 wt % and at most 22 wt % of an amine.
9. The solvent mixture of claim 8 , wherein the amine comprises at least one of monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), or methyldiethanolamine (MDEA).
10. The solvent mixture of claim 1 , wherein a mixture sulfur solubility of the elemental sulfur within the solvent mixture is at least 10% and at most 90% of the solvent sulfur solubility.
11. The solvent mixture of claim 1 , wherein the elemental sulfur solvent fraction comprises at least one of dimethyl disulfide (DMDS), methanol, isopropanol, diethanolamine (DEA), acetone, diaryl disulfide (DADS), carbon disulfide, toluene, or an organic elemental sulfur solvent.
12. The solvent mixture of claim 1 , wherein the presence of the odorant fraction within the solvent mixture decreases the intensity of the mixture odor, relative to the solvent odor, by at least 1 on an Odor Intensity Referencing Scale.
13. The solvent mixture of claim 1 , wherein the presence of the odorant fraction within the solvent mixture decreases the offensiveness of the mixture odor, relative to the solvent odor, by at least 1 on an Odor Offensiveness Referencing Scale.
14. The solvent mixture of claim 1 , wherein the odorant fraction further comprises at least one of a ketone, acetone, methyl ethyl ketone (MEK), an amine, monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), methyldiethanolamine (MDEA), an ester, an aromatic compound, or a sulfurous compound.