Lower pyrolysis temperature binder for silicon-dominant anodes
Systems and methods are provided for carbon additives for direct coating of silicon-dominant anodes. An example composition for use in directly coated anodes may include a silicon-dominated anode active material, a carbon-based binder, and a carbon-based additive, with the composition being configured for low-temperature pyrolysis. The low-temperature pyrolysis may be conducted at <600° C. An anode may be formed using a direct coating process of the composition on a current collector. The anode active material yields silicon constituting between 86% and 97% of weight of the formed anode after pyrolysis. The carbon-based additive yields carbon constituting between 2% and 6% of weight of the formed anode after pyrolysis.
1. An anode, the anode comprising:
a current collector; and
an active material layer on the current collector, the active material layer comprising:
a plurality of silicon particles providing the anode with a silicon content of greater than 95% and up to 97% by weight of the anode; and
a pyrolytic carbon structure around the plurality of silicon particles of the active material layer, wherein the pyrolytic carbon structure comprises between 2% and 6% by weight of the anode.
2. The anode of claim 1 , wherein the pyrolytic carbon structure comprises between 4% and 5% by weight of the anode.
3. The anode of claim 1 , wherein the pyrolytic carbon structure comprises between 2% and 6% by weight of the anode after pyrolysis below 600° C.
4. The anode of claim 1 , wherein the pyrolytic carbon structure comprises between 4% and 5% by weight of the anode after pyrolysis below 600° C.
5. The anode of claim 1 , wherein the pyrolytic carbon structure comprises a glassy carbon.
6. The anode of claim 1 , wherein the pyrolytic carbon structure comprises a glassy carbon from pyrolysis of polyamide-imide (PAI).
7. The anode of claim 6 , wherein an onset of pyrolysis of the PAI occurs below 500° C.
8. The anode of claim 1 , comprising an adhesive layer between the active material layer and the current collector.
9. The anode of claim 1 , wherein:
the current collector comprises copper; and
an interface between the current collector and the active material layer lacks a formation of Cu×Si material.
10. The anode of claim 1 , wherein:
the current collector comprises nickel; and
an interface between the current collector and the active material layer lacks a formation of Ni×Si material.
11. An anode, the anode comprising:
a current collector; and
an active material layer on the current collector, the active material layer comprising:
a plurality of silicon particles providing the anode with a silicon content of at least 86% by weight of the anode; and
a carbon structure around the plurality of silicon particles of the active material layer, wherein the carbon structure comprises between 2% and 6% by weight of the anode.
12. The anode of claim 11 , wherein the carbon structure comprises between 4% and 5% by weight of the anode.
13. The anode of claim 11 , wherein the carbon structure comprises between 4% and 5% by weight of the anode after pyrolysis below 600° C.
14. The anode of claim 11 , wherein:
the active material layer comprises an additive; and
the additive comprises at least one of ECP, ECP600, Super-P, and SLP.
15. A battery, comprising:
an anode;
a cathode; and
a separator between the anode and the cathode, wherein the anode comprises a current collector and an active material layer on the current collector;
wherein the active material layer comprises a silicon content of greater than 94% and up to 97% by weight of the anode;
wherein the active material layer comprises a carbon structure; and
wherein the carbon structure comprises between 4% and 5% of weight of the anode.
16. The battery of claim 15 , wherein the carbon structure comprises glassy carbon from pyrolytic decomposition of polyamide-imide (PAI) below 600° C.
17. The battery of claim 15 , wherein the carbon structure comprises glassy carbon from pyrolytic decomposition of a binder below 600° C.
18. The battery of claim 15 , wherein:
the current collector comprises copper; and
an interface between the current collector and the active material layer lacks a formation of Cu×Si material.
19. The battery of claim 15 , wherein:
the current collector comprises nickel; and
an interface between the current collector and the active material layer lacks a formation of Ni×Si material.