Granted Patent
B2
US 12,686,743 · App. 17/946,007 · Granted Jul 21, 2026
Structured organic films containing imidazolium having cationic charge functionality and methods thereof
Inventors:
Robert Claridge (Gilford, CA); Valerie M. Farrugia (Oakville, CA); David Lawton (Burlington, CA)
Assignee:
GENESEE VALLEY INNOVATIONS, LLC
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Abstract
A structured organic film (SOF) is disclosed including a plurality of segments, a plurality of linkers, and a plurality of ionic capping segments, where at least one or more ionic capping segments may include imidazolium. Implementations of the structured organic film (SOF) include where a concentration of ionic capping segments in the SOF is from about 0.1 to about 5.0 molar equivalents of ionic capping segments as compared to a concentration of nonionic segments in the SOF. A thickness of the SOF is from about 100 nm to about 500 μm. At least one of the plurality of ionic capping segments may include n-hydroxyethyl-1,2,4,5-tetramethylimidazolium (NETMImBr). At least one of the plurality of ionic capping segments may include n-hydroxypropyl-1,2,4,5-tetramethylimidazolium (NPTMImBr). An ion-exchange membrane may include the structured organic film (SOF).
Claims (23)
1 . A structured organic film (SOF), comprising:
a plurality of building block segments;
a plurality of linkers; and
a plurality of ionic capping segments, wherein at least one or more ionic capping segments comprises imidazolium; and
wherein a capped ionic network of the structured organic film comprises:
2 . The structured organic film (SOF) of claim 1 , wherein a thickness of the SOF is from about 100 nm to about 500 μm.
3 . The structured organic film (SOF) of claim 1 , wherein a capped ionic network of the structured organic film further comprises:
4 . An ion-exchange membrane, comprising the structured organic film (SOF) of claim 1 .
5 . The ion-exchange membrane of claim 4 , wherein the structured organic film (SOF) is free-standing.
6 . A structured organic film (SOF), comprising:
a plurality of building block segments; and
a plurality of linkers; wherein
at least one of the plurality of building block segments comprises:
and
wherein a capped ionic network of the structured organic film comprises:
7 . The structured organic film (SOF) of claim 6 , wherein a thickness of the SOF is from about 100 nm to about 500 μm.
8 . A structured organic film (SOF), comprising:
a plurality of building block segments; and
a plurality of linkers; wherein; and
at least one of the plurality of building block segments comprises:
and
wherein a capped ionic network of the structured organic film comprises:
9 . The structured organic film (SOF) of claim 8 , wherein a thickness of the SOF is from about 100 nm to about 500 μm.
Assignments (6)
ASSIGNMENT OF ASSIGNOR'S INTEREST
Recorded Oct 31, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073225/0116 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT
Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT
Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
SECURITY INTEREST
Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
SECURITY INTEREST
Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
ASSIGNMENT OF ASSIGNOR'S INTEREST
Recorded Sep 16, 2022
From: CLARIDGE, ROBERT; FARRUGIA, VALERIE M.; LAWTON, DAVID
To: XEROX CORPORATION
Reel/Frame 061122/0303 →
Continuity (1)
Related Publication
20240110008A1
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