Organic-inorganic hybrid complex and coating composition comprising same, separator, secondary battery, battery module, battery pack and power consuming device
The present application provides an organic-inorganic hybrid complex which can be used in a coating of a separator for a secondary battery, wherein the organic-inorganic hybrid complex is formed from basic units represented by formula (I) being periodically assembled in at least one spatial direction: [L x-i□i ][M a C b ].A z (I), wherein a defect percentage expressed in i/x*100% is 1% to 30%. The present application further provides a coating composition comprising the organic-inorganic hybrid complex, a coating formed from the coating composition, a separator comprising the coating for a secondary battery, a secondary battery comprising the separator, a battery module, a battery pack and a device. By applying the organic-inorganic hybrid complex of the present application in a coating, the electrolyte infiltration of a separator for a secondary battery is improved while increasing the electrolyte retention rate, thereby improving the rate capability and cycling life of the secondary battery.
1. An organic-inorganic hybrid complex, formed from basic units represented by formula (I) being periodically assembled in at least one spatial direction:
[L x-i□i ][M a C b ].A z (I)
wherein in the formula (I),
M represents a metal element of the first transition series,
C represents an atom, atomic group, or anion optionally forming a metal cluster with M,
L represents an organic bridging ligand forming a coordination bond with the metal M or metal cluster M a C b ,
□ represents a ligand defect,
A represents an atom or cation capable of being intercalated and de-intercalated,
x is a number of 1-4, more optionally a number of 1-3,
a is a number of greater than 0 and less than or equal to 4, more optionally a number of 1-4,
z is a number of 0-2, more optionally a number of 0-1,
0<i<x, and 0≤b:a≤1,
wherein the defect level of the organic-inorganic hybrid complex is expressed in a defect percentage, i/x*100%, which is 1% to 30%.
2. The organic-inorganic hybrid complex according to claim 1 , wherein the defect percentage is 2% to 20%, optionally 2.5%-18%, and more optionally 5%-10%.
3. The organic-inorganic hybrid complex according to claim 1 , wherein ½≤x:a≤3.
4. The organic-inorganic hybrid complex according to claim 1 , wherein ¼≤b:a≤1.
5. The organic-inorganic hybrid complex according to claim 1 , wherein the C is selected from one or more of —O—, ═O, O 2− , S −2 , F − , Cl − , Br − , I − , CO, —OH and OH − , and more optionally selected from —O— or —OH.
6. The organic-inorganic hybrid complex according to claim 1 , wherein the L is selected from at least one of cyano, benzimidazole ligands, porphyrin ligands, pyridine ligands, pyrazole ligands, pyrimidine ligands, piperidine ligands, pyrrolidine ligands, furan ligands, thiophene ligands, pyrazine ligands, piperazine ligands, pyridazine ligands, triazine ligands, tetrazine ligands, indole ligands, quinoline ligands, carbazole ligands, morpholine ligands and polycarboxylic acid ligands, wherein one or more of the hydrogen atoms in the L are optionally substituted by one or more substituents, each of which is independently selected from at least one of cyano, nitro, amino, an aldehyde group, carboxyl, a halogen, C1-C6 alkyl, CT-C6 hydroxyalkyl, C1-C6 alkoxy, C2-C6 alkenyl, C2-C6 alkynyl, C3-C8 cycloalkyl, C6-C10 aryl, C6-C10 heteroaryl and any combination thereof; optionally, the L is selected from at least one of cyano, benzimidazole ligands and polycarboxylic acid ligands; more optionally, the L is selected from at least one of cyano, benzimidazole ligands, trimesic acid ligands and terephthalic acid ligands; and more optionally, the L is selected from at least one of cyano, a 5-chlorobenzimidazole ligand (cbIm), a trimesic acid ligand (BTC), a terephthalic acid ligand (BDC) and a tris(2-benzimidazolylmethyl)amine ligand (NTB).
7. The organic-inorganic hybrid complex according to claim 1 , wherein the A is an atom or cation of one or more metal elements selected from Li, Na, K, Rb, Cs, Sr, Zn, Mg and Ca, more optionally Li or Na.
8. The organic-inorganic hybrid complex according to claim 1 , wherein the basic units represented by formula (I) are periodically assembled in at least one of three spatial directions X′, Y′ and Z′, wherein the three spatial directions X′, Y′ and Z′ in each case form an angle of 0-75 degree, optionally 5-60 degree, with X, Y and Z directions in the cartesian coordinate system.
9. The organic-inorganic hybrid complex according to claim 8 , wherein the basic units represented by formula (I) are periodically assembled in at least one spatial direction of the X, Y and Z directions in the cartesian coordinate system.
10. The organic-inorganic hybrid complex according to claim 1 , wherein the number of the basic units represented by formula (I) that are periodically assembled in at least one spatial direction is 3 to 10,000.
11. A coating composition, wherein the coating composition comprises the organic-inorganic hybrid complex according to claim 1 .
12. The coating composition according to claim 11 , wherein the content of the organic-inorganic hybrid complex is 12 wt % to 90 wt %, optionally 17 wt % to 85 wt %, more optionally 34 wt % to 68 wt %, based on the mass of the coating composition.
13. The coating composition according to claim 11 , wherein the coating composition further comprises inorganic particles.
14. The coating composition according to claim 13 , wherein the mass percentage of the organic-inorganic hybrid complex is 15 wt % to 85 wt %, optionally 20 wt % to 80 wt %, more optionally 40 wt % to 80 wt %, based on the total mass of the organic-inorganic hybrid complex and the inorganic particles in the coating composition.
15. The coating composition according to claim 13 , wherein the inorganic particles are selected from at least one of zeolite, molecular sieves, alumina, aluminum oxyhydroxide, silica, aluminum nitride, silicon carbide, magnesia, calcium oxide, zinc oxide, zirconia, titanium oxide and mixtures thereof.
16. A separator for a secondary battery, comprising:
a polymer substrate layer; and
a coating coated onto the polymer substrate layer, wherein the coating comprises the organic-inorganic hybrid complex according to claim 1 .
17. A secondary battery, comprising:
a positive electrode;
a negative electrode;
an electrolyte; and
the separator according to claim 16 .
18. A battery module, comprising the secondary battery according to claim 17 .
19. A battery pack, comprising the battery module according to claim 18 .