POSITIVE ELECTRODE SHEET, SECONDARY BATTERY, BATTERY MODULE, BATTERY PACK, AND POWER CONSUMPTION APPARATUS
The present application provides a positive electrode sheet which may include a current collector and a positive film layer provided on at least one surface of the current collector. The positive film layer may include a lithium manganese oxide in which a trivalent manganese element and a tetravalent manganese element may coexist and a high-oxidizability additive, and the high-oxidizability additive being used to oxidize Mn 2+ to Mn 3+ and/or Mn 4+ .
1 . A positive electrode sheet, comprising:
a current collector and a positive film layer provided on at least one surface of the current collector, the positive film layer comprising a lithium manganese oxide in which a trivalent manganese element and a tetravalent manganese element coexist and a high-oxidizability additive, and the high-oxidizability additive being used to oxidize Mn 2+ to Mn 3+ and/or Mn 4+ .
2 . The positive electrode sheet according to claim 1 , wherein
a structural formula of the lithium manganese oxide is Li 8-3a-4b-3c (Mn 3+ ) a (N 3+ ) c (Mn 4+ ) b O 4 , c≥0, a>0, b≥0, N is selected from one or more of B, Al, Ga, In, TI and Fe, and a ratio of an atom number of the trivalent manganese element to an atom number of the tetravalent manganese element is α;
a mass content of the high-oxidizability additive in the positive film layer is β %; and
the α and the β satisfy 0.01≤β/α≤10.
3 . The positive electrode sheet according to claim 2 , wherein the α and the β satisfy 0.5≤β/α≤5.
4 . The positive electrode sheet according to claim 2 , wherein
the α satisfies 0.5≤α≤1.2.
5 . The positive electrode sheet according to claim 4 , wherein
the α satisfies 0.6≤α≤1.
6 . The positive electrode sheet according to claim 2 , wherein
the β satisfies 0.01≤β≤10.
7 . The positive electrode sheet according to claim 6 , wherein the β satisfies 0.5≤α≤5.
8 . The positive electrode sheet according to claim 1 , wherein
the high-oxidizability additive is one or more of Li 2 O 2 , Na 2 O 2 , K 2 O 2 , CrO 3 , V 2 O 5 and NiO x , x>1.5 and a valence of Ni is +4.
9 . The positive electrode sheet according to claim 1 , wherein
the high-oxidizability additive is irreversible L 2 NiO 2 , or the high-oxidizability additive is an irreversible composite metal oxide formed by doping an element M into the L 2 NiO 2 , M is one or more of Cu, Fe, Co and Ni, L is one or more of Li, Na and K, and a valence of the Ni is +2; wherein
the “irreversible” refers to: in the high-oxidizability additive containing a divalent nickel element, a nickel element whose valence is less than +4 is oxidized to a tetravalent nickel element in a first charging process of a secondary battery prepared from the positive electrode sheet, and the tetravalent nickel element always exists in subsequent charging and discharging processes.
10 . A secondary battery, comprising:
a negative electrode sheet, a separator, the positive electrode sheet according to claim 1 , and an electrolytic solution, wherein the electrolytic solution includes a low-impedance additive, and a mass content w % of the low-impedance additive in the electrolytic solution and a mass content β % of the high-oxidizability additive in the positive film layer satisfy 0.1≤w/β≤10.
11 . The secondary battery according to claim 10 , wherein 2≤w/β≤5.
12 . The secondary battery according to claim 10 , wherein
0.01≤w≤10.
13 . The secondary battery according to claim 12 , wherein
0.5≤w≤5.
14 . The secondary battery according to claim 10 , wherein
the low-impedance additive is fluorosulfonate and/or difluorophosphate,
the fluorosulfonate is (FSO 3 ) y M y+ , and M y+ is one or more of Li + , Na + , K + , Rb + , Cs + , Mg 2+ , Ca 2+ , Ba 2+ , Al 3+ , Fe 2+ , Fe 3+ , Ni 2+ and Ni 3+ ; and
the difluorophosphate is (F 2 PO 2 ) y M y+ , and M y+ is one or more of Li + , Na + , K + , Rb + , Cs + , Mg 2+ , Ca 2+ , Ba 2+ , Al 3+ , Fe 2+ , Fe 3+ , Ni 2+ and Ni 3+ .
15 . A battery module, comprising the secondary battery according to claim 10 .
16 . A battery pack, comprising the battery module according to claim 15 .
17 . A battery pack, comprising one or more of the secondary battery according to claim 10 .
18 . A power consumption apparatus,
comprising the battery pack according to claim 16 , the battery pack being used as a power source of the power consumption apparatus or an energy storage unit of the power consumption apparatus.
19 . A power consumption apparatus,
comprising the battery module according to claim 15 , the battery module being used as a power source of the power consumption apparatus or an energy storage unit of the power consumption apparatus.
20 . A power consumption apparatus,
comprising the secondary battery module according to claim 10 , the secondary battery being used as a power source of the power consumption apparatus or an energy storage unit of the power consumption apparatus.