IP Library Granted Patent US 12,006,467
Granted Patent B2
US 12,006,467 · App. 17/984,823 · Granted Jun 11, 2024

Compositions of aphron sealing lost circulation spacer

Inventors: Garrett Schultz (Spring, TX); Jordan Clark (Tomball, TX)
Assignee: SELECT CHEMISTRY, LLC
C09K8/501C09K8/00C09K8/5045C09K8/514C09K2208/04C09K2208/08
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Quick Facts
Patent No.
US 12,006,467
App. No.
17/984,823
Granted
Jun 11, 2024
Kind
B2
Abstract

A spacer fluid includes an aphron generating component, a polymer, a lost circulation material, and a weighting agent component.

Claims (18)

1. A spacer fluid comprising:

an aphron generating component;

an aphron, the aphron being a bubble between 10 and 150 microns in diameters; the aphron having a structure of one core, two layers, and three membranes;

a polymer;

a lost circulation material; and,

a weighting agent component.

2. The spacer fluid of claim 1 , wherein the aphron generating component is an alcohol ethoxylate, an alcohol ethoxysulfate, an alkyl phenol ethoxylate, an olefin sulfonates, an alkyl betaine, a glycol ether, or a combination thereof or a derivative thereof.

3. The spacer fluid of claim 2 , wherein the aphron generating component is an alpha olefin sulfonate.

4. The spacer fluid of claim 2 , wherein the alkyl betaines is selected from the group consisting of cocamidopropyl betaine, lauryl betaine, and cocamidopropyl hydroxysultaine.

5. The spacer fluid of claim 2 , wherein the aphron generating component is a combination of an alkyl betaine and an alpha-olefin sulfonate.

6. The spacer fluid of claim 5 , wherein the ratio of alkyl betaine to alpha-olefin sulfonate is between 1:1 and 1:4.

7. The spacer fluid of claim 2 , wherein the lost circulation material is plant fiber selected from the group consisting of corn cob hulls or fiber, cotton burr, walnut shells, peanut shells, coconut coir or shells, kenaf fiber and combinations thereof.

8. The spacer fluid of claim 7 , wherein the amount of aphron generating component in the spacer fluid is between 0.1-30% by weight of the lost circulation material.

9. The spacer fluid of claim 8 , wherein the aphron-generating component is used to pre-coat the lost circulation component prior to mixing with the remaining components of the spacer fluid.

10. The spacer fluid of claim 1 , wherein the polymer is a polysaccharide.

11. The spacer fluid of claim 10 , wherein the polysaccharide is xanthan, diutan, welan, schlerogucan, carrageenan, or any combination thereof.

12. The spacer fluid of claim 1 , wherein the weighting agent is sodium bentonite, barite, calcium carbonate, magnesium carbonate, or any combination thereof.

13. The spacer fluid of claim 1 , wherein the spacer fluid is blended as a solid composite.

Assignments (3)
PATENT SECURITY AGREEMENT Recorded Jan 29, 2025
From: SELECT WATER SOLUTIONS, LLC; SELECT AGUA LIBRE MIDSTREAM, LLC; SELECT CHEMISTRY, LLC
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 070048/0356 →
CHANGE OF NAME Recorded Aug 15, 2023
From: ROCKWATER ENERGY SOLUTIONS, LLC
To: SELECT CHEMISTRY, LLC
Reel/Frame 064598/0886 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 23, 2022
From: SCHULTZ, GARRETT; CLARK, JORDAN
To: ROCKWATER ENERGY SOLUTIONS, LLC
Reel/Frame 061865/0170 →