BHM in adhesive compositions
View Patent ↗An adhesive composition comprising a first part comprising an epoxy resin and a second part comprising a multifunctional amine package. The multifunctional amine package comprises bis(hexamethylene)triamine and a synergist. The amine concentration is at least 10% less than the epoxy resin concentration and the adhesive composition demonstrates a sag resistance of greater than 40 mm.
1. An adhesive composition comprising:
a first part comprising an epoxy resin; and
a second part comprising a multifunctional amine package comprising:
bis(hexamethylene)triamine; and
a synergist;
wherein, in the adhesive composition, the amine concentration is at least 10% less than the epoxy resin concentration, and
wherein the adhesive composition demonstrates a sag resistance ranging from 10 mm to 300 mm; and
wherein, when cured, the cured composition demonstrates a Koenig hardness from 2 to 70, with a Koenig Hardness (1 day) from 2 to 20.
2. The composition of claim 1 , wherein the synergist comprises acetonitrile, caprolactam, aminohexanol, aminocephalosporanic acid, aminocapronitrile, or adiponitrile, or combinations thereof.
3. The composition of claim 1 , wherein the adhesive composition comprises less than 35 wt % cyclic amines, based on the total amine content.
4. The composition of claim 1 , wherein the adhesive composition comprises a solvent, and wherein the solvent to bis(hexamethylene) triamine weight ratio ranges from 0.1 to 4.0.
5. The composition of claim 1 , wherein the first part and the second part each has a volume, and wherein the volume ratio of the first part to the second part ranges from 0.2 to 5.
6. The composition of claim 1 , wherein the adhesive composition, when mixed, has a Brookfield viscosity from 100 to 2000 cps.
7. The composition of claim 1 , wherein the adhesive composition further comprises a solvent, a rheology modifier, or combinations thereof.
8. The composition of claim 1 , wherein the adhesive composition comprises from 40 wt % to 90 wt % epoxy resin, based on the total weight of the adhesive composition.
9. The composition of claim 1 , wherein the adhesive composition comprises from 1 wt % to 35 wt % bis(hexamethylene) triamine, based on the total weight of the adhesive composition.
10. The composition of claim 1 , wherein the adhesive composition comprises from 1 wt % to 50 wt % of a phenol solvent based on the total weight of the adhesive composition.
11. The composition of claim 10 , wherein the phenol comprises a nonyl phenol.
12. The composition of claim 1 , wherein the adhesive composition comprises from 0.1 wt % to 20 wt % of a silica rheology modifier based on the total weight of the adhesive composition.
13. The composition of claim 1 , wherein the second part is not a solid.
14. The composition of claim 1 , wherein the adhesive composition has a hydrogen active equivalent weight less than 65.
15. The composition of claim 1 , wherein the adhesive composition demonstrates a cross hatch adhesion score of at least 2B, as measured via ASTM D3359 method B.
16. The composition of claim 1 , wherein the adhesive composition demonstrates a gel time greater than 10 minutes.
17. The composition of claim 1 , wherein the adhesive composition, when cured, demonstrates yellowing index greater than 1.
18. A process for making an adhesive composition, comprising:
dissolving in a solvent a multifunctional amine package comprising bis(hexamethylene) triamine and a synergist to form a second part;
contacting the second part with a first part comprising an epoxy resin to form the adhesive composition; and
wherein, when cured, the cured composition demonstrates a Koenig hardness from 2 to 70, with a Koenig Hardness (1 day) from 2 to 20.
19. The process of claim 18 , further comprising adding a rheology modifier to the second part, such that the second part has a viscosity less than 1500 cps.
20. The process of claim 18 , wherein the adhesive composition has a viscosity from 100 to 2000 cps.
21. The process of claim 18 , wherein the synergist comprises acetonitrile, caprolactam, aminohexanol, aminocephalosporanic acid, aminocapronitrile, or adiponitrile, or combinations thereof.