Composition for SCR catalysts
The present invention relates to a composition comprising a non-zeolitic oxidic material comprising alumina; an 8-membered ring pore zeolitic material comprising one or more of copper and iron, wherein the framework structure of the zeolitic material comprises a tetravalent element Y, a trivalent element X and oxygen, wherein the molar ratio of Y:X, calculated as YO 2 X 2 O 3 , is in the range of from 2:1 to 40:1; wherein at least part of the outer surface of the zeolitic material is covered by a layer comprising the non-zeolitic oxidic material; wherein Y comprises one or more of Si, Sn, Ti, Zr and Ge and X comprises one or more of Al, B, In and Ga.
1 . A composition comprising:
(i) a non-zeolitic oxidic material comprising alumina; and
(ii) an 8-membered ring pore zeolitic material comprising one or more of copper and iron, wherein a framework structure of the zeolitic material comprises a tetravalent element Y, a trivalent element X and oxygen, wherein the molar ratio of Y:X, calculated as YO 2 :X 2 O 3 , ranges from 2:1 to 40:1;
wherein at least part of the outer surface of the zeolitic material according to (ii) is covered by a layer comprising the non-zeolitic oxidic material according to (i); and
wherein Y comprises one or more of Si, Sn, Ti, Zr and Ge and X comprises one or more of Al, B, In and Ga;
wherein the composition is obtainable or obtained by a process, the process comprising:
(a) providing an 8-membered ring pore zeolitic material, comprising one or more of copper and iron, wherein the framework structure of the zeolitic material comprises a tetravalent element Y, a trivalent element X and oxygen, wherein the molar ratio of Y:X, calculated as YO2:X2O3, is in the range of from 2:1 to 40:1;
(b) providing a source of a non-zeolitic oxidic material comprising alumina, wherein the source of the non-zeolitic oxidic material is a colloid dispersion comprising particles of the non-zeolitic oxidic material, wherein the particles of the non-zeolitic oxidic material have a Dv50 in the range of from 30 to 200 nm;
(c) admixing the zeolitic material obtained in (a) with the source of the non-zeolitic oxidic material comprising alumina obtained in (b), forming a mixture;
(d) calcining the mixture obtained in (c) in a gas atmosphere having a temperature in the range of from 400 to 800° C.
2 . The composition of claim 1 , wherein from 98 weight-% to 100 weight of the non-zeolitic oxidic material according to (i) consist of alumina.
3 . The composition of claim 1 , wherein the layer comprising the non-zeolitic oxidic material according to (i) has an average thickness ranging from 2 nm to 100 nm.
4 . The composition of claim 1 , wherein from 99 weight-% to 100 weight-%, of the layer consist of the non-zeolitic oxidic material according to (i).
5 . The composition of claim 1 , wherein the 8-membered ring pore zeolitic material according to (ii) has a framework type selected from the group consisting of CHA, AEI, RTH, LEV, DDR, KFI, ERI, AFX, LTA, a mixture of two or more thereof and a mixed type of two or more thereof, preferably selected from the group consisting of CHA, AEI, RTH, a mixture of two or more thereof and a mixed type of two or more thereof, more preferably selected from the group consisting of CHA and AEI.
6 . The composition of claim 1 , wherein from 20% to 100%, of the outer surface of the zeolitic material according to (ii) are covered by the layer comprising the non-zeolitic oxidic material according to (i).
7 . A slurry comprising a composition according to claim 1 and a dispersion agent, wherein the dispersion agent is one or more of water, ethanol, acetic acid, nitric acid, lactic acid, and a mixture of two or more thereof.
8 . A selective catalytic reduction catalyst for treating an exhaust gas of a combustion engine, the catalyst comprising:
(1) a substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the substrate extending therethrough;
(2) a coating disposed on the substrate (i), the coating comprising a composition according to claim 1 .
9 . The catalyst of claim 8 , wherein the coating ( 2 ) further comprises an oxidic binder, wherein the oxidic binder comprises one or more of zirconia, alumina, titania, silica, and a mixed oxide comprising two or more of Zr, Al, Ti, and Si.
10 . The catalyst of claim 8 , wherein the coating ( 2 ) comprises the composition in an amount ranging from 80 weight-% to 100 weight-%, based on the weight of the coating ( 2 ).
11 . The catalyst of claim 8 , wherein the substrate is a wall-flow filter substrate, wherein the plurality of passages comprises inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end.
12 . A process for preparing the selective catalytic reduction catalyst for treating an exhaust gas of a combustion engine, the process comprising
(A) preparing a mixture comprising water and a composition according to claim 1 ;
(B) disposing the mixture obtained according to (A) on a substrate, the substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the substrate extending therethrough, obtaining a mixture-treated substrate;
(C) calcining the mixture-treated substrate obtained according to (B), obtaining the substrate having a coating disposed thereon.
13 . A process for preparing a composition, the process comprising:
(a) providing an 8-membered ring pore zeolitic material, comprising one or more of copper and iron, wherein a framework structure of the zeolitic material comprises a tetravalent element Y, a trivalent element X and oxygen, wherein the molar ratio of Y:X, calculated as YO 2 :X 2 O 3 , ranges from 2:1 to 24:1, wherein the zeolitic material comprises crystals having an average crystal size in the range of from 0.05 micrometers to 5 micrometers;
(b) providing a source of a non-zeolitic oxidic material comprising alumina, wherein the source of the non-zeolitic oxidic material is a colloid dispersion comprising particles of the non-zeolitic oxidic material, wherein the particles of the non-zeolitic oxidic material have a Dv50 ranging from 30 nm to 200 nm;
(c) admixing the zeolitic material obtained in (a) with the source of the non-zeolitic oxidic material comprising alumina obtained in (b), forming a mixture; and
(d) calcining the mixture obtained in (c) in a gas atmosphere having a temperature ranging from 400° C. to 800° C.
14 . The process of claim 13 , wherein the crystals of the 8-membered ring pore zeolitic material have an average crystal size ranging from 0.06 micrometers to 2 micrometers.
15 . The process of claim 13 , wherein the 8-membered ring pore zeolitic material comprises particles having a Dv50 ranging from 0.5 micrometers to 4 micrometers.
16 . The process of claim 13 , wherein the colloid dispersion comprising particles of the non-zeolitic oxidic material provided in (b) is alumina sol.
17 . The process of claim 13 , wherein the particles of the non-zeolitic oxidic material, the particles of alumina, have a Dv50 ranging from 50 nm to 150 nm.