FLAT GLASS PANE
The invention relates to a flat glass pane made of a base material, which is an alkali-containing silicate glass. The flat glass pane is characterized in that at least one surface layer is enriched with potassium and is depleted of sodium and/or lithium while an inner layer, in particular an inner layer directly adjoining the surface layer, is not enriched with potassium and is not depleted of sodium and/or lithium; and the flat glass pane has a compressive stress up to a compressive stress depth and a tensile stress starting from the compressive stress depth, wherein the tensile stress increases as the depth increases up to a tensile stress maximum arranged in the inner layer, and/or the curve of the tensile stress does not have a linear section depending on the depth, and/or the curve of the tensile stress does not have a section in which the tensile stress is constant depending on the depth.
1 . A flat glass pane ( 7 ) which is made of a base material which is an alkali-containing silicate glass, or is an aluminosilicate glass, characterized in that
a. at least one surface layer ( 10 ) is enriched in potassium and depleted in sodium and/or lithium, while an inner layer ( 11 ), more particularly an inner layer ( 11 ) directly bordering the surface layer ( 10 ), is not enriched in potassium and not depleted in sodium and/or lithium, and in that
b. the flat glass pane ( 7 ), down to a compressive stress depth ( 2 ), has a compressive stress ( 3 ) and beyond the compressive stress depth ( 2 ) has a tensile stress ( 4 ), where the tensile stress ( 4 ) rises with increasing depth up to a tensile stress maximum disposed in the inner layer ( 11 ) and/or where the profile of the tensile stress ( 4 ) as a function of the depth has no linear portion and/or where the profile of the tensile stress ( 4 ) as a function of the depth has no portion in which the tensile stress ( 4 ) is constant.
2 . The flat glass pane ( 7 ) as claimed in claim 1 , characterized in that the surface layer ( 10 ) has a thickness in the range from 0.5 μm to 60 μm, more particularly in the range from 0.5 μm to 30 μm, more particularly in the range from 0.5 μm to 15 μm.
3 . The flat glass pane ( 7 ) as claimed in claim 1 , characterized in that the flat glass pane ( 7 ) has two surface layers ( 10 ), which more particularly are parallel to one another, and in that
a. each of the two surface layers ( 10 ) is enriched in potassium and depleted in sodium and/or lithium, while an inner layer disposed between the surface layers ( 10 ) is not enriched in potassium and not depleted in sodium and/or lithium, and in that
b. the flat glass pane ( 7 ) on each of both sides, down to a compressive stress depth, has a compressive stress ( 3 ) and beyond the compressive stress depth ( 2 ) has a tensile stress ( 4 ), where the tensile stress ( 4 ) rises with increasing depth up to a tensile stress maximum disposed in the inner layer ( 11 ) and/or where the profile of the tensile stress ( 4 ) as a function of the depth has no linear portion and/or where the profile of the tensile stress ( 4 ) as a function of the depth does not have a portion in which the tensile stress ( 4 ) is constant.
4 . The flat glass pane ( 7 ) as claimed in claim 1 , characterized in that the tensile stress maximum is disposed centrically between the surface layers ( 10 ).
5 . The flat glass pane ( 7 ) as claimed in claim 1 , characterized in that the tensile stress maximum is disposed eccentrically between the surface layers ( 10 ).
6 . The flat glass pane ( 7 ) as claimed in claim 1 , characterized in that the flat glass pane ( 7 ) has two surface layers ( 10 ), which more particularly are parallel to one another, and in that
a. only a first of the two surface layers ( 10 ) is enriched in potassium and depleted in sodium and/or lithium, while the other surface layer ( 8 ) and an inner layer ( 11 ) disposed between the surface layers ( 10 ) are not enriched in potassium and not depleted in sodium and/or lithium, and in that
b. the flat glass pane ( 7 ), more particularly on each of both sides, down to a compressive stress depth ( 2 ) has a compressive stress ( 3 ) and beyond the compressive stress depth ( 2 ) has a tensile stress ( 4 ), where the tensile stress ( 4 ) rises with increasing depth up to a tensile stress maximum disposed in the inner layer and/or where the profile of the tensile stress ( 4 ) as a function of the depth has no linear portion and/or where the profile of the tensile stress ( 4 ) as a function of the depth does not have a portion in which the tensile stress ( 4 ) is constant.
7 . The flat glass pane ( 7 ) as claimed in claim 6 , characterized in that the tensile stress maximum is disposed eccentrically between the surface layers ( 10 )
8 . The flat glass pane ( 7 ) as claimed in claim 1 , characterized in that the flat glass pane has a thickness in the range from 0.03 mm to 22 mm, more particularly in the range from 0.5 mm to 10 mm or from 0.5 mm in the range to 5 mm or in the range from 0.6 mm to 3 mm or in the range from 0.68 mm to 3 mm or of 0.68 mm or in the range from 1.5 mm to 3 mm, or in that the flat glass pane has a thickness of more than 1.5 mm.
9 . The flat glass pane ( 7 ) as claimed in claim 1 , characterized in that the strength, more particularly a strength measured in accordance with DIN EN 1288-5, of the flat glass pane is at least 1.5 times, more particularly at least twice or at least three times or at least four times or at least five times, higher than the strength of an identical flat glass pane, more particularly of a flat glass pane of identical shape and size and identical base material, that does not have the features of the characterizing clause of claim 1 .
10 . The flat glass pane ( 7 ) as claimed in claim 1 , characterized in that the surface layer ( 10 ) has an increased hardness by comparison with the inner layer ( 11 ) and/or in that the surface layer ( 10 ) has a Martens hardness, more particularly measured in accordance with DIN EN ISO 14577-1 under a test force of 2 N, in the range from 3500 N/mm 2 to 3900 N/mm 2 , more particularly in the range from 3650 N/mm 2 to is 3850 N/mm 2 .
11 . The flat glass pane ( 7 ) as claimed in claim 1 , characterized in that in the surface layer ( 10 ) the fraction of potassium down to a depth in the range from 0.5 μm to 10 μm is greater than the total fraction of sodium and lithium and in that the fraction of potassium beyond a depth in the range from 0.5 μm to 10 μm is smaller than the total fraction of sodium and lithium.
12 . The flat glass pane ( 7 ) as claimed in claim 1 , characterized in that the depletion of sodium and/or lithium in the potassium-enriched surface layer down to a depth of at least one quarter of the thickness of the surface layer is at least 50% (percent by mass).
13 . The flat glass pane as claimed in claim 1 , characterized in that the flat glass pane is a float glass pane or a rolled glass pane or drawn glass.
14 . The flat glass pane as claimed in claim 1 , characterized in that the flat glass pane is embodied as a window pane or as a display pane or as a motor vehicle pane or as a sliding roof pane or as a solar glass pane or as a greenhouse pane.
15 . The flat glass pane as claimed in claim 1 , characterized in that the glass material is an alkali metal-alkaline earth metal silicate glass, especially a soda-lime glass, or a borosilicate glass.
16 . A display, more particularly computer display or mobile phone display, which comprises a flat glass pane as claimed in any of claim 1 .
17 . An electronic device, more particularly computer or tablet or mobile phone, which comprises a display as claimed in claim 16 .
18 . A motor vehicle which comprises a flat glass pane as claimed in claim 1 .
19 . The motor vehicle as claimed in claim 18 , characterized in that the flat glass pane is a windshield pane or a tailgate pane or a side pane or a roof pane, more particularly of a glass roof or of a sliding glass roof or of an opening glass roof.