Catalytic system for the treatment of an exhaust gas of a combustion engine
The present invention relates a system for the treatment of an exhaust gas of a diesel combustion engine, said system comprising a specific NOx adsorber component, a diesel oxidation catalyst (DOC) component, a selective catalytic reduction (SCR) component, a gas heating component, and a reductant injector, wherein in said system, the specific NOx adsorber component is arranged upstream of the gas heating component, the reductant injector is arranged up-stream of the SCR component, the gas heating component is arranged upstream of the reductant injector, the DOC component is arranged upstream of the reductant injector, and the DOC component and the gas heating component are directly consecutive components. Further, the present invention relates a process for preparing such a system and use thereof.
1. A system for the treatment of an exhaust gas of a diesel combustion engine, said system comprising an NOx adsorber component, a diesel oxidation catalyst (DOC) component, a selective catalytic reduction (SCR) component, a gas heating component, and a reductant injector, wherein in said system, the NOx adsorber component is arranged upstream of the gas heating component, the reductant injector is arranged upstream of the SCR component, the gas heating component is arranged upstream of the reductant injector, the DOC component is arranged upstream of the reductant injector, and the DOC component and the gas heating component are directly consecutive components,
wherein the NOx adsorber component is comprised in
(i) a catalyst which comprises
(i.1) a first substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end of the first substrate, and a plurality of passages defined by internal walls of the first substrate extending therethrough;
(i.2) an NOx adsorber coating being said NOx adsorber component, said coating being disposed on the surface of the internal walls of the first substrate over at least 50% of the substrate axial length of the first substrate, the NOx adsorber coating comprising a platinum group metal component and a 10-membered ring pore zeolitic material having a framework type selected from the group consisting of FER, TON, MTT, SZR, MWW, AEL, HEU, AFO, a mixture of two or more thereof and a mixed type of two or more thereof.
2. The system of claim 1 , wherein the platinum group metal component of the NOx adsorber coating according to (i.2) is comprised in the 10-membered ring pore zeolitic material of the NOx adsorber coating according to (i.2).
3. The system of claim 1 , wherein the DOC component is arranged upstream of the gas heating component.
4. The system of claim 1 , wherein the catalyst according to (i) further comprises
(i.3) a diesel oxidation catalyst (DOC) coating being said DOC component, said DOC coating being at least partially disposed on the NOx adsorber coating over at least 70% of the substrate axial length of the first substrate, the DOC coating comprising a platinum group metal component and a non-zeolitic oxidic material comprising one or more of alumina, silica, zirconia and titania.
5. The system of claim 1 , wherein
(ii) the gas heating component comprises
(ii.1) a second substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end of the second substrate, and a plurality of passages defined by internal walls of the second substrate extending therethrough;
wherein the inlet end of the second substrate according to (ii.1) and the outlet end of the first substrate according to (i.1) are coupled to allow exhaust gas exiting from the passages of the first substrate to enter the passages of the second substrate;
wherein the internal walls of the second substrate are thermally conductive to allow heating thereof for heating of exhaust gas flowing through the passages of the second substrate.
6. The system of claim 5 , wherein the gas heating component according to (ii) further comprises
(ii.2) optionally an NOx adsorber coating disposed on the surface of the internal walls of the second substrate over at least 50% of the substrate axial length of the second substrate, the NOx adsorber coating comprising a platinum group metal component and a 10-membered ring pore zeolitic material having a framework type selected from the group consisting of FER, TON, MTT, SZR, MWW, AEL, HEU, AFO, a mixture of two or more thereof and a mixed type of two or more thereof;
(ii.3) a diesel oxidation catalyst (DOC) coating at least partially disposed on the surface of the internal walls of the second substrate and/or at least partially disposed on the optional NOx adsorber coating according to (ii.2) and extending over at least 70% of the substrate axial length of the second substrate, the DOC coating comprising a platinum group metal component and a non-zeolitic oxidic material comprising one or more of alumina, silica, zirconia and titania.
7. The system of claim 1 , wherein the DOC component is arranged downstream of the gas heating component.
8. The system of claim 7 , wherein the DOC component is comprised in
(iii) a catalyst comprising
(iii.1) a third substrate which comprises an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end of the third substrate, and a plurality of passages defined by internal walls of the third substrate extending therethrough;
(iii.2) a first DOC coating disposed on the surface of the internal walls of the third substrate over at least 70% of the substrate axial length of the third substrate, the first DOC coating comprising a platinum group metal component and a non-zeolitic oxidic material comprising one or more of alumina, silica, zirconia and titania; and
(iii.3) optionally a second DOC coating at least partially disposed on the first DOC coating and extending over at least 20% of the substrate axial length of the third substrate, the second DOC coating comprising a platinum group metal component and a non-zeolitic oxidic material comprising one or more of alumina, silica, zirconia and titania.
9. The system of claim 7 , wherein
(ii) the gas heating component comprises
(ii.1) a second substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end of the second substrate, and a plurality of passages defined by internal walls of the second substrate extending therethrough;
wherein the inlet end of the second substrate according to (ii.1) and the outlet end of the first substrate according to (i.1) are coupled to allow gas exiting from the passages of the first substrate according to (i.1) to enter the passages of the second substrate according to (ii.1);
wherein the inlet end of the third substrate according to (iii.1) and the outlet end of the second substrate according to (ii.1) are coupled to allow gas exiting from the passages of the second substrate to enter the passages of the third substrate according to (iii.1);
wherein the internal walls of the second substrate according to (ii.1) are thermally conductive to allow heating thereof for heating of exhaust gas flowing through the passages of the second substrate.
10. The system of claim 9 , wherein the gas heating component according to (ii) further comprises
(ii.2) a first DOC coating disposed on the surface of the internal walls of the second substrate according to (ii.1) over at least 50% of the substrate axial length of the second substrate according to (ii.1), the first DOC coating comprising a platinum group metal component and a non-zeolitic oxidic material comprising one or more of alumina, silica, zirconia and titania;
(ii.3) optionally a second DOC coating at least partially disposed on the first DOC coating according to (ii.2) and extending over at least 50% of the substrate axial length of the second substrate according to (ii.1), the second DOC coating comprising a platinum group metal component and a non-zeolitic oxidic material comprising one or more of alumina, silica, zirconia and titania.
11. The system of claim 8 , wherein the SCR component is comprised in
(iv) a selective catalytic reduction (SCR) catalyst comprising
(iv.1) a fourth substrate comprising an inlet end, an outlet end, and a substrate axial length extending from the inlet end to the outlet end of the fourth substrate;
(iv.2) a selective catalytic reduction (SCR) coating disposed on the fourth substrate according to (iv.1);
wherein the inlet end of the fourth substrate according to (iv.1) and either:
a) the outlet end of the second substrate, where the second substrate comprises an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end of the second substrate, and a plurality of passages defined by internal walls of the second substrate extending therethrough; wherein the inlet end of the second substrate and the outlet end of the first substrate are coupled to allow exhaust gas exiting from the passages of the first substrate to enter the passages of the second substrate; wherein the internal walls of the second substrate are thermally conductive to allow heating thereof for heating of exhaust gas flowing through the passages of the second substrate, or
b) the outlet end of the third substrate;
are coupled to allow exhaust gas exiting from the passages of the second substrate or exiting from the passages of the third substrate to enter the fourth substrate.
12. A process for preparing a system for the treatment of an exhaust gas of a diesel combustion engine, comprising
(1) providing an NOx adsorber component, a diesel oxidation catalyst (DOC) component, a selective catalytic reduction (SCR) component, a gas heating component, and a reductant injector,
wherein the NOx adsorber component is comprised in
(i) a catalyst which comprises
(i.1) a first substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end of the first substrate, and a plurality of passages defined by internal walls of the first substrate extending therethrough;
(i.2) an NOx adsorber coating being said NOx adsorber component, said coating being disposed on the surface of the internal walls of the first substrate over at least 50% of the substrate axial length of the first substrate, the NOx adsorber coating comprising a platinum group metal component and a 10-membered ring pore zeolitic material having a framework type selected from the group consisting of FER, TON, MTT, SZR, MWW, AEL, HEU, AFO, a mixture of two or more thereof and a mixed type of two or more thereof;
(2) arranging the NOx adsorber component upstream of the gas heating component;
(3) arranging the reductant injector upstream of the SCR component;
(4) arranging the gas heating component upstream of the reductant injector;
(5) arranging the DOC component upstream of the reductant injector;
(6) arranging the DOC component and the gas heating component in directly consecutive order.
13. A system for the treatment of an exhaust gas of a diesel combustion engine obtainable or obtained by a process according to claim 12 .
14. A method for the treatment of an exhaust gas of a diesel combustion engine, comprising providing an exhaust gas from a diesel combustion engine and passing said exhaust gas through a system according to claim 1 .