Catalyst with magnetic ferrite support material
The present disclosure provides a catalyst composition comprising a catalytically active platinum group metal (PGM) component disposed on or impregnated in a magnetic ferrite support material, wherein the magnetic ferrite support material is capable of inductive heating in response to an applied alternating electromagnetic field. Further provided are catalyst articles comprising such compositions, and components comprising such catalyst articles, and further comprising a conductor associated with the catalyst article for receiving current and generating an alternating electromagnetic field in response thereto, wherein the conductor is positioned such that the generated alternating electromagnetic field is applied to at least a portion of the catalyst composition, inductively heating the catalyst composition directly at the catalytic site. Also provided are exhaust gas treatment systems including such components and/or articles, and methods of treating emissions utilizing such components and systems.
1. A catalyst composition comprising:
a catalytically active platinum group metal (PGM) component; and
a magnetic ferrite support material, wherein the magnetic ferrite support material is capable of inductive heating in response to an applied alternating magnetic field, wherein the active platinum group metal is disposed or impregnated on the magnetic ferrite support material,
wherein the magnetic ferrite support material satisfies at least one of the following:
(i) the magnetic ferrite support material comprises iron, nickel, and zinc, and wherein a nickel/zinc molar ratio is from 1/99 to 99/1,
(ii) the magnetic ferrite support material comprises iron, cobalt, and zinc, wherein a cobalt/zinc molar ratio is from 1/99 to 99/1, or
(iii) the magnetic ferrite support material has the molecular formula Co 0.5 Zn 0.5 Fe 2 O 4 , Ni 0.5 Zn 0.5 Fe 2 O 4 , or Y 3 Fe 5 O 12 .
2. The catalyst composition of claim 1 , wherein the magnetic ferrite support material comprises one or more elements chosen from zinc, cobalt, nickel, yttrium, manganese, copper, barium, strontium, scandium, and lanthanum.
3. The catalyst composition of claim 1 , wherein the magnetic ferrite support material comprises iron and yttrium.
4. The catalyst composition of claim 1 , wherein the magnetic ferrite support material is calcined at a temperature of 400° C. to 1200° C. for an hour or more.
5. The catalyst composition of claim 1 , wherein the magnetic ferrite support material is in the form of particles having an average particle size from 40 nm to 1 μm.
6. The catalyst composition of claim 1 , wherein the catalytically active PGM component is platinum, palladium, rhodium, or a combination thereof.
7. The catalyst composition of claim 1 , wherein the magnetic ferrite support material has a Brunauer-Emmett-Teller (BET) surface area of less than 100 m 2 /g.
8. The catalyst composition of claim 1 , wherein a coercivity of the magnetic ferrite support material is from 1 kA/m to 20 kA/m.
9. The catalyst composition of claim 1 , configured as a diesel oxidation catalyst (DOC), a catalyzed soot filter (CSF) catalyst, a lean NOx trap (LNT) catalyst, an ammonia oxidation (AMOx) catalyst, or a three-way catalyst (TWC).
10. A catalytic article for treatment of exhaust gas emissions from an internal combustion engine, comprising:
a substrate in the form of a flow-through substrate or a wall-flow filter, having the catalyst composition of claim 1 deposited thereon,
the catalytic article adapted for use as a diesel oxidation catalyst (DOC), catalyzed soot filter (CSF), lean NOx trap (LNT), selective catalytic reduction (SCR) catalyst, ammonia oxidation (AMOx) catalyst, or three-way catalyst (TWC).
11. An emission control system comprising:
the catalytic article of claim 10 ;
a conductor for receiving current and generating an alternating magnetic field in response thereto, the conductor positioned such that the generated alternating magnetic field is applied to at least a portion of the catalyst composition;
an electric power source electrically connected to the conductor for supplying alternating current thereto;
a temperature sensor positioned to measure a temperature of gases entering the catalytic article; and
a controller in communication with the temperature sensor, the controller adapted for control of the current supplied to the conductor, such that the controller energizes the conductor with current when heating of the catalytic article is desired.
12. A method of treating exhaust gas emissions from an internal combustion engine, comprising passing the exhaust gas emissions through the emission control system of claim 11 , wherein the internal combustion engine is a gasoline engine, diesel engine, hybrid electric, or natural gas engine.
13. A catalyst for fixed bed reactor design comprising a catalyst bed having the catalyst composition of claim 1 .
14. A fixed bed catalyst system comprising:
the catalyst of claim 13 ; and
a conductor for receiving current and generating an alternating magnetic field in response thereto, the conductor positioned such that the generated alternating magnetic field is applied to at least a portion of the catalyst composition.
15. A method for producing the catalyst composition of claim 1 , the method comprising:
heating the magnetic ferrite support material at a temperature of 600° C. or greater for an hour or more; and
combining the heated magnetic ferrite support material with the catalytic material.