Positive Electrode Material for Electric Device, Positive Electrode for Electric Device and Electric Device Using Positive Electrode Material for Electric Device
A means for enhancing capacity performance and charge-discharge rate capability of an electric device uses a positive electrode active material containing sulfur. In the positive electrode material for an electric device, which contains a conductive material having pores, solid electrolyte, and a positive electrode active material containing sulfur, at least a part of the solid electrolyte and at least a part of the positive electrode active material are to be placed on the inner surface of the pores.
1 . A positive electrode material for an electric device comprising:
a conductive material being in particle form and having pores;
a solid electrolyte; and
a positive electrode active material containing sulfur,
wherein at least a part of the solid electrolyte and at least a part of the positive electrode active material are placed, on an inner surface of the pores, to be in contact with each other.
2 . A positive electrode material for an electric device comprising:
a conductive material having pores;
a solid electrolyte; and
a positive electrode active material containing sulfur,
wherein at least a part of the solid electrolyte and at least a part of the positive electrode active material are placed, on an inner surface of the pores, to be in contact with each other (where a positive electrode material for an electric device which contains an ionic liquid is excluded).
3 . The positive electrode material for an electric device according to claim 1 , wherein the pores are filled with a continuous phase including the positive electrode active material, and a dispersed phase of the solid electrolyte is placed in the continuous phase.
4 . The positive electrode material for an electric device according to claim 1 , wherein a ratio of a count number of elements derived only from the solid electrolyte to a count number of all elements is 0.10 or more in a cross-sectional image of the conductive material observed by TEM-EDX.
5 . The positive electrode material for an electric device according to claim 1 , wherein the conductive material is a carbon material.
6 . The positive electrode material for an electric device according to claim 1 , wherein a pore volume of the conductive material is 1.0 mL/g or more.
7 . The positive electrode material for an electric device according to claim 1 , wherein an average pore size of the conductive material is 50 nm or less.
8 . The positive electrode material for an electric device according to claim 1 , wherein the solid electrolyte is a sulfide solid electrolyte.
9 . The positive electrode material for an electric device according to claim 1 , wherein the solid electrolyte contains an alkali metal atom and a phosphorus atom and/or a boron atom.
10 . The positive electrode material for an electric device according to claim 9 , wherein the alkali metal atom is lithium.
11 . A positive electrode for an electric device comprising the positive electrode material for an electric device according to claim 1 .
12 . An electric device comprising the positive electrode for an electric device according to claim 11 .
13 . The electric device according to claim 12 , wherein the electric device is an all-solid lithium-ion secondary battery.