Compositions comprising alkylated diphenylamines with improved properties
The present invention relates to a composition comprising alkylated diphenylamines of the structural formulas (I), (II), (III), and (IV), to industrial products such as additive blends, engine oils, and polymer compositions comprising the mixture of alkylated diphenylamines, and to the use of the mixture as an additive such in industrial products such as additive blends, engine oils and polymer compositions: wherein R is a branched C 4 -C 16 -alkyl group, and wherein the total amount of tetra-alkylated diphenylamines of the structural formula (IV) is in the range from 0.20 to 3.5 wt. %, based on the total weight of alkylated diphenylamines of the structural formula (I), (II), (III), and (IV) in the composition.
1. A composition comprising alkylated diphenylyamines of the structural formulas (I), (II), (III), and (IV):
wherein R is a branched alkyl group having the formula —C 9 H 19 , and
wherein the total amount of tetra-nonyl diphenylamines is in the range from 0.20 to 3.5 wt.-%, based on the total weight of alkylated diphenylamines of the structural formula (I), (II), (III), and (IV) in the composition.
2. The composition according to claim 1 , wherein the total amount of monoalkylated diphenylamines of the structural formula (I) is in the range from 10 to 35 wt.-%, based on the total weight of alkylated diphenylamines of the structural formula (I), (II), (III), and (IV) in the composition.
3. The composition according to claim 1 , wherein the total amount of dialkylated diphenylamines of the structural formula (II) is in the range from 60 to 85 wt.-%, based on the total weight of alkylated diphenylamines of the structural formula (I), (II), (III), and (IV) in the composition.
4. The composition according to claim 1 , wherein the total amount of trialkylated diphenylamines of the structural formula (III) is in the range from 1 to 10 wt.-%, based on the total weight of alkylated diphenylamines of the structural formula (I), (II), (III), and (IV) in the composition.
5. The composition according to claim 1 , wherein the composition further comprises less than 1 wt.-% of non-alkylated diphenylamine, based on the total weight of alkylated diphenylamines of the structural formula (I), (II), (III), and (IV) in the composition.
6. The composition according to claim 1 , wherein at least one of the following conditions (α1) to (α6) is fulfilled:
(α1) the composition has a kinematic viscosity (determined at a temperature of 40° C. according to ASTM D 445) in the range from 100 to 1000 cSt;
(α2) the composition has a Gardner colour (determined according to ASTM D 1544) of less than 15 Gardner;
(α3) the composition has water content (determined according to ASTM E 203) of less than 0.1 wt.-%;
(α4) the composition has a nitrogen content (determined according to ASTM D 2896) in the range from 3.2 to 3.8%;
(α5) the composition has a specific gravity (determined at a temperature of 25° C. according to ASTM D 1298) in the range from 0.930 to 0.980;
(α6) the composition has a total base number (TBN) (determined according to ASTM D 2896) in the range of 125 to 160 mg KOH/g.
7. The composition according to claim 1 , wherein the total amount of alkylated diphenylamines of the structural formula (I), (II), (III), and (IV) is at least 98 wt.-%, based on the total weight of the composition.
8. The composition according to claim 1 , wherein the composition is an additive blend.
9. The composition according to claim 8 , wherein the total amount of alkylated diphenylamines of the structural formula (I), (II), (III), and (IV) is in the range from 0.01 to 30 wt.-%, based on the total weight of the additive blend.
10. The composition according to claim 1 , wherein the composition is an engine oil comprising at least one base oil.
11. The composition according to claim 10 , wherein the total amount of alkylated diphenylamines of the structural formula (I), (II), (III), and (IV) is in the range from 0.01 to 5 wt.-%, based on the total weight of the engine oil.
12. The composition according to claim 1 , wherein the composition is a polymer composition comprising a polymer.
13. The composition according to claim 12 , wherein the total amount of alkylated diphenylamines of the structural formula (I), (II), (III), and (IV) is in the range from 0.01 to 1 wt.-%, based on the total weight of the polymer composition.
14. Use of the composition according to claim 1 as an additive in additive blends, engine oils, or polymer compositions.