Power storage device binder composition, power storage device electrode slurry, power storage device electrode, and power storage device
A binder composition for an electrical storage device includes a polymer (A) and a liquid medium (B), where with respect to 100 mass % in total of repeating units contained in the polymer (A), the polymer (A) contains 15 mass % to 60 mass % of a repeating unit (a1) derived from a conjugated diene compound and 1 mass % to 10 mass % of a repeating unit (a2) derived from an unsaturated carboxylic acid. In the binder composition, the following characteristics are satisfied: tan δ (loss elastic modulus/storage elastic modulus) in dynamic viscoelasticity of the polymer (A) has one peak top in a range of from −40° C. to less than 50° C. (tan δ(Tp1)), and has one peak top in a range of from 50° C. to 150° C. (tan δ(Tp2)), and the following relationship is satisfied tan δ(Tp2)/tan δ(Tp1)≥0.5.
1 . A binder composition for an electrical storage device, comprising:
a polymer (A); and
a liquid medium (B),
wherein, with respect to 100 mass % in total of repeating units contained in the polymer (A), the polymer (A) contains:
15 mass % to 60 mass % of a repeating unit (a1) derived from a conjugated diene compound; and
1 mass % to 10 mass % of a repeating unit (a2) derived from an unsaturated carboxylic acid,
wherein tan δ (loss elastic modulus/storage elastic modulus) in dynamic viscoelasticity of the polymer (A) has one peak top in a range of from −40° C. or more to less than 50° C., and has one peak top in a range of from 50° C. or more to 150° C. or less, and
wherein, when the tan δ at the peak top in the range of from −40° C. or more to less than 50° C. is represented by tan δ(Tp1), and the tan δ at the peak top in the range of from 50° C. or more to 150° C. or less is represented by tan δ(Tp2), a relationship of the following expression (1) is satisfied,
tan δ( Tp 2)/tan δ( Tp 1)≥0.5 (1).
2 . The binder composition for an electrical storage device according to claim 1 ,
wherein the polymer (A) further contains 35 mass % to 75 mass % of a repeating unit (a3) derived from an aromatic vinyl compound, and
wherein a total amount of the repeating unit (a1), the repeating unit (a2), and the repeating unit (a3) is 80 mass % or more.
3 . The binder composition for an electrical storage device according to claim 1 ,
wherein the polymer (A) contains at least one of a repeating unit (a4) derived from an unsaturated carboxylic acid ester or a repeating unit (a5) derived from an α,β-unsaturated nitrile compound, and
wherein a total amount of the repeating unit (a1), the repeating unit (a2), the repeating unit (a4), and the repeating unit (a5) is 65 mass % or more.
4 . The binder composition for an electrical storage device according to claim 1 , wherein the polymer (A) has a Martens hardness of 15 MPa or more, which is calculated using a picoindenter.
5 . The binder composition for an electrical storage device according to claim 1 ,
wherein the polymer (A) is polymer particles, and
wherein the polymer particles have a number average particle diameter of 50 nm or more and 500 nm or less.
6 . The binder composition for an electrical storage device according to claim 1 , wherein the liquid medium (B) is water.
7 . A slurry for an electrical storage device electrode, comprising:
the binder composition for an electrical storage device of claim 1 ; and
an active material.
8 . The slurry for an electrical storage device electrode according to claim 7 , wherein the active material is a silicon material.
9 . An electrical storage device electrode, comprising:
a current collector; and
an active material layer formed on a surface of the current collector by applying and drying the slurry for an electrical storage device electrode of claim 7 .
10 . An electrical storage device, comprising the electrical storage device electrode of claim 9 .