Lithographic printing plate precursor
A lithographic printing plate precursor is disclosed including a support and a coating comprising a photopolymerisable layer including a polymerisable compound and a photoinitiator, characterized in that the coating comprises a hydrophilic adhesion promoting copolymer including at least one monomeric unit according to Formula I and at least one monomeric unit according to Formula II; and at least one group and/or moiety including a phosphor atom.
1 . A lithographic printing plate precursor including, on a support, a coating comprising a photopolymerisable layer including a polymerisable compound, a photoinitiator, and an adhesion promoting compound,
characterised in that the coating further comprises a hydrophilic substrate adhesive polymer including at least one monomeric unit according to Formula I, at least one monomeric unit according to Formula II, and at least one group and/or moiety including at least one phosphor atom;
wherein
L represents O;
n and m independently represent an integer greater than 0;
R represents hydrogen; and
R 1 and R 2 each independently represent an optionally substituted linear, branched, or cyclic alkyl group, and
wherein the at least one group and/or moiety including at least one phosphor atom is at least one group of Formula V that is an endgroup of the backbone of the hydrophilic substrate adhesive polymer, at least one moiety of Formula VI that is randomly present in the backbone of the hydrophilic substrate adhesive polymer, or a combination thereof;
wherein
a represents 0 or 1;
R4 represents-OH or a methyl group;
b and c independently represent 0 or 1; and
* denotes the linking position to the monomeric unit according to Formula I and/or Formula II.
2 . The printing plate precursor of claim 1 , wherein
R 1 and R 2 each independently represent a methyl or ethyl group.
3 . The printing plate precursor of claim 1 , wherein the at least one group and/or moiety including at least one phosphor atom is at least one moiety of Formula VI that is randomly present in the backbone of the hydrophilic substrate adhesive polymer.
4 . The printing plate precursor of claim 2 , wherein the at least one group and/or moiety including at least one phosphor atom is at least one moiety of Formula VI that is randomly present in the backbone of the hydrophilic substrate adhesive polymer.
5 . The printing plate precursor of claim 1 , wherein the at least one group and/or moiety including at least one phosphor atom is at least one group of Formula V that is an endgroup of the backbone of the hydrophilic substrate adhesive polymer.
6 . The printing plate precursor of claim 2 , wherein the at least one group and/or moiety including at least one phosphor atom is at least one group of Formula V that is an endgroup of the backbone of the hydrophilic substrate adhesive polymer.
7 . The printing plate precursor of claim 1 , wherein the hydrophilic substrate adhesive polymer is a block-copolymer including alternating sequences of blocks consisting of monomeric units according to Formula I and monomeric units according to Formula II.
8 . The printing plate precursor of claim 2 , wherein the hydrophilic substrate adhesive polymer is a block-copolymer including alternating sequences of blocks consisting of monomeric units according to Formula I and monomeric units according to Formula II.
9 . The printing plate precursor of claim 1 , wherein the at least one monomeric unit according to Formula II and the at least one group and/or moiety including at least one phosphor atom are represented by Formula VII:
wherein R′ represents hydrogen;
o represents an integer between 1 and 100; and
p and q each independently represent an integer between 0 and 500.
10 . The printing plate precursor of claim 1 , wherein the hydrophilic substrate adhesive polymer further includes a monomeric unit derived from an acrylate, a methacrylate, styrene, an acrylamide, a methacrylamide, or a maleimide.
11 . The printing plate precursor of claim 2 , wherein the hydrophilic substrate adhesive polymer further includes a monomeric unit derived from an acrylate, a methacrylate, styrene, an acrylamide, a methacrylamide, or a maleimide.
12 . The printing plate precursor of claim 1 , wherein the hydrophilic substrate adhesive polymer is present in the coating in an amount of 5 to 100 mg/m 2 .
13 . The printing plate precursor of claim 2 , wherein the hydrophilic substrate adhesive polymer is present in the coating in an amount of 5 to 100 mg/m 2 .
14 . The printing plate precursor of claim 1 , wherein the hydrophilic substrate adhesive polymer has a weight average molecular weight below 100000.
15 . The printing plate precursor of claim 1 , wherein the coating comprises above the photopolymerisable layer a toplayer and the hydrophilic substrate adhesive polymer is present in the toplayer.
16 . The printing plate precursor of claim 15 , wherein the hydrophilic substrate adhesive polymer is present in both the photopolymerisable layer and the toplayer.
17 . A method for making a printing plate precursor including the steps of
a. coating on a support (i) a photopolymerisable layer including a polymerisable compound, a photoinitiator, and an adhesion promoting compound, and (ii) a substrate adhesive polymer as defined in claim 11 , and
b. drying the precursor.
18 . A method for making a printing plate including the steps of
a. image-wise exposing the printing plate precursor as defined in claim 1 to heat and/or IR radiation whereby a lithographic image consisting of image areas and non-image areas is formed,
b. developing the exposed precursor.
19 . The method of claim 18 , wherein the precursor is developed by mounting the precursor on a plate cylinder of a lithographic printing press and rotating the plate cylinder while feeding dampening liquid and/or ink to the precursor.