ADHESIVE COMPOSITION FOR FOLDABLE DISPLAY AND ADHESIVE FILM FOR FOLDABLE DISPLAY COMPRISING CURED PRODUCT THEREOF
An adhesive composition for a foldable display containing a (meth)acrylate-based polymer and an adhesive film comprising a cured product of the adhesive composition, which provide excellent folding properties even under sub-zero temperature conditions, and thus may be easily applied to a foldable display, are provided.
1 . An adhesive composition for a foldable display containing a (meth)acrylate-based polymer which is a reaction product of a monomer mixture containing:
a first monomer comprising at least one of a first acrylate-based monomer containing an alkyl group having 12 to 14 carbon atoms, and a first methacrylate-based monomer containing an alkyl group having 14 to 16 carbon atoms;
a second monomer comprising at least one of a second acrylate-based monomer containing an alkyl group having 3 to 10 carbon atoms, and a second methacrylate-based monomer containing an alkyl group having 8 to 12 carbon atoms; and
a (meth)acrylate-based monomer containing a polar functional group.
2 . The adhesive composition of claim 1 , wherein the first monomer is contained in an amount of 20 parts by weight to 60 parts by weight based on 100 parts by weight of the monomer mixture.
3 . The adhesive composition of claim 1 , wherein the second monomer is contained in an amount of 35 parts by weight to 80 parts by weight based on 100 parts by weight of the monomer mixture.
4 . The adhesive composition of claim 1 , wherein the (meth)acrylate-based monomer containing the polar functional group is contained in an amount of 1 part by weight to 4 parts by weight based on 100 parts by weight of the monomer mixture.
5 . The adhesive composition of claim 1 , wherein a weight ratio between the first monomer and the (meth)acrylate-based monomer containing the polar functional group is 1:0.025 to 1:0.1.
6 . The adhesive composition of claim 1 , wherein a weight ratio between the first monomer and the second monomer is 1:0.5 to 1:4.
7 . The adhesive composition of claim 1 , wherein a weight ratio between the (meth)acrylate-based monomer containing the polar functional group and the second monomer is 1:10 to 1:85.
8 . The adhesive composition of claim 1 , wherein the (meth)acrylate-based monomer containing the polar functional group contains a carboxylic acid group.
9 . The adhesive composition of claim 1 , further containing an epoxy-based crosslinking agent.
10 . The adhesive composition of claim 9 , wherein the epoxy-based crosslinking agent is contained in an amount of 0.01 parts by weight to 0.1 parts by weight based on 100 parts by weight of the (meth)acrylate-based polymer.
11 . The adhesive composition of claim 1 , wherein the (meth) acrylate-based polymer has a weight-average molecular weight of 1,500,000 to 2,500,000 g/mol.
12 . An adhesive film for a foldable display comprising an adhesive layer comprising a cured product of the adhesive composition for a foldable display according to claim 1 .
13 . The adhesive film of claim 12 , wherein the adhesive layer has a storage modulus of 100,000 Pa or lower as measured at -20° C.
14 . The adhesive film of claim 12 , wherein the adhesive layer has a storage modulus of 10,000 Pa or higher as measured at 25° C.