Method for identifying foil position in power storage device and method for calculating inter-foil distance in power storage device
A method for identifying a foil position in a power storage device includes: analyzing the power storage device by X-ray CT analysis to obtain an X-ray absorbed amount at each position; acquiring an on-path X-ray absorbed amount at each on-path position on a specific imaginary line passing through an electrode sheet; and identifying a foil position of an electrode foil through which the specific imaginary line passes, based on the on-path X-ray absorbed amount. The foil position identifying includes fitting to determine an approximate curve that changes to fit a change in the on-path X-ray absorbed amount in a fitting region and generates a single peak in the fitting region, and estimating a foil position of a single electrode foil from the on-path position corresponding to the single peak of the determined approximate curve.
1. A method for identifying a foil position in a power storage device provided with an electrode sheet including an electrode foil, the method comprising:
analyzing the power storage device by X-ray CT analysis using irradiation of an X-ray to obtain an X-ray absorbed amount at each of a plurality of positions in the power storage device;
acquiring, based on the obtained X-ray absorbed amount, an on-path X-ray absorbed amount that is the X-ray absorbed amount at each of on-path positions on a specific imaginary line passing through the electrode sheet of the power storage device; and
identifying, based on the acquired on-path X-ray absorbed amount, a foil position of the electrode foil of the electrode sheet which the specific imaginary line passes through,
wherein the identifying includes:
fitting to determine an approximate curve that changes to fit a change in the on-path X-ray absorbed amount in a fitting region of the specific imaginary line, the fitting region including a single electrode foil that is the electrode foil, and further that generates a single peak in the fitting region; and
estimating the foil position of the single electrode foil from the on-path position corresponding to the single peak of the determined approximate curve within the fitting region of the specific imaginary line.
2. The method for identifying a foil position in a power storage device according to claim 1 , wherein
the specific imaginary line is an imaginary line that passes in a straight line and perpendicularly through the electrode foil of the electrode sheet which the specific imaginary line passes through,
the electrode sheet includes electrode layers provided one on each surface of the electrode foil, the electrode layers having the same thickness, and
the approximate curve determined in the fitting is a curved line symmetric about the on-path position corresponding to the single peak.
3. The method for identifying a foil position in a power storage device according to claim 2 , wherein
the electrode sheet includes a plurality of one-polarity electrode sheets, which are positive electrode sheets or negative electrode sheets,
the electrode foil includes a plurality of one-polarity electrode foils, which are positive electrode foils or negative electrode foils,
the specific imaginary line passes through the plurality of one-polarity electrode foils,
the identifying includes performing the fitting and the estimating on each of the one-polarity electrode foils to identify the foil position of each of the one-polarity electrode foils, and
the method further includes estimating a foil position of another-polarity electrode foil located between the one-polarity electrode foils adjacent to each other, from a pair of the identified foil positions of the adjacent one-polarity electrode foils.
4. A method for calculating an inter-foil distance, the method comprising:
by use of the foil position of the electrode foil identified by the method for identifying a foil position in the power storage device according to claim 3 ,
calculating an inter-foil distance between the electrode foils of the same polarity, adjacently located with the electrode foil of a different polarity interposed therebetween, or between the electrode foils of mutually different polarities, adjacently located to each other.
5. A method for calculating an inter-foil distance, the method comprising:
by use of the foil position of the electrode foil identified by the method for identifying a foil position in the power storage device according to claim 2 ,
calculating an inter-foil distance between the electrode foils of the same polarity, adjacently located with the electrode foil of a different polarity interposed therebetween, or between the electrode foils of mutually different polarities, adjacently located to each other.
6. The method for identifying a foil position in a power storage device according to claim 1 , wherein
the electrode sheet includes a plurality of one-polarity electrode sheets, which are positive electrode sheets or negative electrode sheets,
the electrode foil includes a plurality of one-polarity electrode foils, which are positive electrode foils or negative electrode foils,
the specific imaginary line passes through the plurality of one-polarity electrode foils,
the identifying includes performing the fitting and the estimating on each of the one-polarity electrode foils to identify the foil position of each of the one-polarity electrode foils, and
the method further includes estimating a foil position of another-polarity electrode foil located between the one-polarity electrode foils adjacent to each other, from a pair of the identified foil positions of the adjacent one-polarity electrode foils.
7. A method for calculating an inter-foil distance, the method comprising:
by use of the foil position of the electrode foil identified by the method for identifying a foil position in the power storage device according to claim 6 ,
calculating an inter-foil distance between the electrode foils of the same polarity, adjacently located with the electrode foil of a different polarity interposed therebetween, or between the electrode foils of mutually different polarities, adjacently located to each other.
8. A method for calculating an inter-foil distance, the method comprising:
by use of the foil position of the electrode foil identified by the method for identifying a foil position in the power storage device according to claim 1 ,
calculating an inter-foil distance between the electrode foils of the same polarity, adjacently located with the electrode foil of a different polarity interposed therebetween, or between the electrode foils of mutually different polarities, adjacently located to each other.