ELECTRODES FOR ENERGY STORAGE DEVICES
An electrode for an energy storage device is disclosed. The electrode includes an active layer. The active layer includes a network of high aspect ratio carbon elements defining void spaces within the network, a plurality of electrode active material particles disposed in the void spaces within the network, and a polymeric additive, the polymeric additive being at least one of (i) selected from a family of polyamides, or (ii) a modified polyamide or derivative of a polyamide.
1 . An electrode, comprising:
an active layer comprising:
a network of high aspect ratio carbon elements defining void spaces within the network;
a plurality of electrode active material particles disposed in the void spaces within the network; and
a polymeric additive, the polymeric additive being at least one of (i) selected from a family of polyamides, or (ii) a modified polyamide or derivative of a polyamide.
2 . The electrode of claim 1 , wherein network of high aspect ratio carbon elements comprises:
a first set of carbon nanotubes, wherein the first set of carbon nanotubes comprises a plurality of first carbon nanotubes or a plurality of bundles of first carbon nanotubes; and
a second set of carbon nanotubes, wherein:
the second set of carbon nanotubes comprise a plurality of second carbon nanotubes or a plurality of bundles of second carbon nanotubes; and
the second set of carbon nanotubes has one or more properties different from the first set of carbon nanotubes.
3 . The electrode of claim 2 , wherein the first set of carbon nanotubes comprises multi-wall carbon nanotubes.
4 . The electrode of claim 2 , wherein the second set of carbon nanotubes comprises single-wall carbon nanotubes.
5 . The electrode of claim 2 , wherein:
the first set of carbon nanotubes comprises multi-wall carbon nanotubes;
the second set of carbon nanotubes comprises single-wall carbon nanotubes; and
a ratio of an amount by weight of the first set of carbon nanotubes to the second set of carbon nanotubes is about 2:1. +
6 . The electrode of claim 1 , wherein the network of high aspect ratio carbon elements comprises a set of multi-wall carbon nanotubes.
7 . The electrode of claim 6 , wherein the active layer comprises between 0.25% and 1.5% of multi-wall carbon nanotubes by weight of the active layer.
8 . The electrode of claim 6 , wherein the active layer comprises between 0.2% and 2% of multi-wall carbon nanotubes by weight of the active layer.
9 . The electrode of claim 6 , wherein the multi-wall carbon nanotubes are branched carbon nanotubes.
10 . The electrode of claim 6 , wherein the multi-wall carbon nanotubes are branched, interdigitated, entangled and/or share common walls.
11 . An energy storage device comprising:
an electrolyte; and
the electrode of claim 5 , wherein wetted with the electrolyte the multi-wall nanotubes comprised in the first set of carbon nanotubes swell more than the single-wall carbon nanotubes comprised in the second set of carbon nanotubes.
12 . The electrode of claim 5 , wherein the multi-wall carbon nanotubes comprise:
an average diameter of between 6 nm and 10 nm;
an average wall thickness of between 6 nm and 7 nm; and
an average length of about 16 micron.
13 . The electrode of claim 5 , wherein the single-wall carbon nanotubes comprise:
an average diameter of between 1 nm and 2 nm;
an average length of about 5 micron.
14 . The electrode of claim 5 , wherein the single-wall carbon nanotubes comprise:
an average diameter of between 3 nm and 5 nm; and
an average length of at least 200 micron.
15 . The electrode of claim 5 , wherein the single-wall carbon nanotubes comprise:
an average diameter of between 3 nm and 5 nm; and
an average length of between 7 and 8 micron.
16 . The electrode of claim 5 , wherein the single-wall carbon nanotubes comprise on average 1 or 2 layers of walls.
17 . The electrode of claim 5 , wherein the single-wall carbon nanotubes comprise:
an average diameter of between 5 nm and 6 nm;
an average length of between 7 and 8 micron.
18 . The electrode of claim 5 , wherein the single-wall carbon nanotubes comprise:
a range of lengths between 1 nm and 34 nm;
an average length of between 7 and 8 micron.
19 . The electrode of claim 5 , wherein after wetted with an electrolyte an average thickness of the electrode increases less than 10%.
20 . The electrode of claim 5 , wherein a first average aspect ratio of the first set of carbon nanotubes is larger than a second average aspect ratio of the second set of carbon nanotubes.