NEGATIVE ELECTRODE PLATE, SECONDARY BATTERY, BATTERY MODULE, BATTERY PACK, AND ELECTRIC APPARATUS
A negative electrode plate includes a negative electrode current collector and active material layers disposed on at least one surface of the negative electrode current collector. The active material layers include a first active material layer and a second active material layer disposed on a surface of the first active material layer. The first active material layer includes a first active material, the second active material layer includes a second active material, and the active material layers satisfy α×CW 2 ≤CW 1 . α = d 2 d 1 is a relative factor of layer spacings and 1≤α≤1.12. d 1 and d 2 are layer spacings corresponding to d002 peaks of the first and second active materials, respectively, in units of nm. CW 1 and CW 2 are masses per unit area of the first and second active material layers, respectively, in units of g/m 2 .
1 . A negative electrode plate, comprising:
a negative electrode current collector; and
active material layers disposed on at least one surface of the negative electrode current collector, the active material layers comprising:
a first active material layer comprising a first active material; and
a second active material layer disposed on a surface of the first active material layer and comprising a second active material;
wherein:
the active material layers satisfy α×CW 2 ≤CW 1 ;
α is a relative factor of layer spacings, wherein
α
=
d
2
d
1
and 1≤α≤1.12;
d 1 is a layer spacing corresponding to a d002 peak of the first active material, in units of nm;
d 2 is a layer spacing corresponding to a d002 peak of the second active material, in units of nm;
CW 1 is mass per unit area of the first active material layer disposed on the negative electrode current collector, in units of g/m 2 ; and
CW 2 is mass per unit area of the second active material layer disposed on the negative electrode current collector, in units of g/m 2 .
2 . The negative electrode plate according to claim 1 , wherein:
CW
1
CW
2
is inversely proportional to
d
1
×
Da
50
d
2
×
Db
50
,
and
0.2
≤
CW
2
CW
2
+
CW
1
≤
0.45
;
Da50 is a volume median particle size of the first active material, in units of μm; and
Db50 is a volume median particle size of the second active material, in units of μm.
3 . The negative electrode plate according to claim 2 , wherein the volume median particle size Da50 of the first active material and the volume median particle size Db50 of the second active material satisfy
0.2
≤
Db
50
Da
50
≤
0.8
.
4 . The negative electrode plate according to claim 1 , wherein the active material layers satisfy
CW
2
≥
3
17
α
×
CW
1
.
5 . The negative electrode plate according to claim 4 , wherein a volume median particle size Da50 of the first active material and a volume median particle size Db50 of the second active material satisfy
0.2
≤
Db
50
Da
50
≤
0.8
.
6 . The negative electrode plate according to claim 4 , wherein:
the layer spacing d 1 corresponding to the d002 peak of the first active material is within a range of 0.335-0.3362 nm, and the layer spacing d 2 corresponding to the d002 peak of the second active material is within a range of 0.3356-0.38 nm.
7 . The negative electrode plate according to claim 4 , wherein a volume median particle size Da50 of the first active material is within a range of 8-20 μm, and a volume median particle size Db50 of the second active material is within a range of 4-12 μm.
8 . The negative electrode plate according to claim 4 , wherein the mass per unit area CW 1 of the first active material layer disposed on the negative electrode current collector is within a range of 80-200 g/m 2 , and the mass per unit area CW 2 of the second active material layer disposed on the negative electrode current collector is within a range of 10-110 g/m 2 .
9 . The negative electrode plate according to claim 1 , wherein:
the first active material is a natural graphite or artificial graphite material, and/or
the second active material is an artificial graphite material.
10 . The negative electrode plate according to claim 1 , wherein:
soft carbon or hard carbon is contained in the first active layer and/or the second active layer.
11 . A secondary battery, comprising:
a negative electrode plate comprising:
a negative electrode current collector; and
active material layers disposed on at least one surface of the negative electrode current collector, the active material layers comprising:
a first active material layer comprising a first active material; and
a second active material layer disposed on a surface of the first active material layer and comprising a second active material;
wherein:
the active material layers satisfy α×CW 2 ≤CW 1 ;
α is a relative factor of layer spacings, wherein
α
=
d
2
d
1
and 1≤α≤1.12;
d 1 is a layer spacing corresponding to a d002 peak of the first active material, in units of nm;
d 2 is a layer spacing corresponding to a d002 peak of the second active material, in units of nm;
CW 1 is mass per unit area of the first active material layer disposed on the negative electrode current collector, in units of g/m 2 ; and
CW 2 is mass per unit area of the second active material layer disposed on the negative electrode current collector, in units of g/m 2 .
12 . A battery pack comprising the secondary battery according to claim 11 .
13 . An electric apparatus comprising the secondary battery according to claim 11 .
14 . A battery module comprising:
a secondary battery comprising a negative electrode plate comprising:
a negative electrode current collector; and
active material layers disposed on at least one surface of the negative electrode current collector, the active material layers comprising:
a first active material layer comprising a first active material; and
a second active material layer disposed on a surface of the first active material layer and comprising a second active material;
wherein:
the active material layers satisfy a α×CW 2 ≤CW 1 ;
α is a relative factor of layer spacings, wherein
α
=
d
2
d
1
and 1≤α≤1.12;
d 1 is a layer spacing corresponding to a d002 peak of the first active material, in units of nm;
d 2 is a layer spacing corresponding to a d002 peak of the second active material, in units of nm;
CW 1 is mass per unit area of the first active material layer disposed on the negative electrode current collector, in units of g/m 2 ; and
CW 2 is mass per unit area of the second active material layer disposed on the negative electrode current collector, in units of g/m2.