Rechargeable battery and method for manufacturing positive plate of rechargeable battery
A method for manufacturing a positive plate of a rechargeable battery includes producing an insulation protective paste forming an insulation protective layer of the positive plate, the insulation protective paste including insulation particles, a binder, and a solvent and having a pH adjusted corresponding to a zeta potential at which the insulation particles do not aggregate, producing a positive composite material paste forming a positive composite material layer of the positive plate, the positive composite material paste including a positive active material, a conduction support, a binder, and a solvent, and a pH adjuster being added to the positive composite material paste to adjust a pH corresponding to a zeta potential at which the insulation particles aggregate, and simultaneously coating a positive current collector of the positive plate with the positive composite material paste and the insulation protective paste disposed adjacent to an end of the positive composite material paste.
1 . A method for manufacturing a positive plate of a rechargeable battery, wherein
the rechargeable battery includes an electrode body including the positive plate, a negative plate, and a separator that are stacked on one another,
the negative plate includes a negative current collector and a negative composite material layer formed on the negative current collector, and
the positive plate includes a positive current collector, a positive composite material layer formed on the positive current collector, and an insulation protective layer formed on the positive current collector adjacent to the positive composite material layer at a position opposed to an end of the negative composite material layer, the method comprising:
producing an insulation protective paste that forms the insulation protective layer, the insulation protective paste including insulation particles, a binder, and a solvent and having a pH adjusted corresponding to a zeta potential at which the insulation particles do not aggregate;
producing a positive composite material paste that forms the positive composite material layer, the positive composite material paste including a positive active material, a conduction support, a binder, and a solvent, and a pH adjuster being added to the positive composite material paste to adjust a pH corresponding to a zeta potential at which the insulation particles aggregate; and
simultaneously coating the positive current collector with the positive composite material paste and the insulation protective paste so that the insulation protective paste is disposed adjacent to an end of the positive composite material paste.
2 . The method according to claim 1 , wherein
the insulation particles include boehmite, and
the pH of the insulation protective paste is adjusted to 10 to 12.
3 . The method according to claim 2 , wherein
the boehmite of the insulation protective paste has an average particle size of 1 to 3 μm, and
the insulation protective paste is a dispersant-free insulation protective paste.
4 . The method according to claim 2 , wherein an amount of sodium (Na) contained in the insulation protective paste is 50 to 500 ppm.
5 . The method according to claim 1 , wherein the pH adjuster includes acetic acid.
6 . The method according to claim 1 , wherein the pH of the positive composite material paste is adjusted to 7 to 9.
7 . The method according to claim 1 , wherein the positive composite material paste has an acidity of 300 to 800 ppm.