LITHIUM-ION BATTERY, BATTERY MODULE, BATTERY PACK AND POWERED DEVICE
A lithium-ion battery includes an electrode assembly and an electrolyte solution. The electrode assembly includes a negative electrode sheet, a separator and a positive electrode sheet, which are wound into a wound structure in a winding direction. The wound structure includes an arc bending portion. The arc bending portion includes a first bending portion and a second bending portion. A corner lithium plating coefficient β of the lithium-ion battery is set to satisfy 0.015≤ β=R/(R+L) ≤0.95, wherein R is a minimum curvature radius of a convex surface of a negative electrode current collector of the first bending portion, and L is a shortest distance between the convex surface of the negative electrode current collector of the first bending portion and a concave surface of a positive electrode current collector of the second bending portion.
1 . A lithium-ion battery, comprising:
an electrode assembly and an electrolyte solution for impregnating the electrode assembly, wherein
the electrode assembly comprises a negative electrode sheet, a separator and a positive electrode sheet, and the negative electrode sheet, the separator and the positive electrode sheet are wound into a wound structure in a winding direction, and wherein the wound structure comprises an arc bending portion;
the arc bending portion comprises a first bending portion and a second bending portion;
the first bending portion is an innermost arc bending portion formed by winding the negative electrode sheet, and comprises a negative electrode current collector and a negative electrode material layer located on a convex surface of the negative electrode current collector;
the second bending portion is located on an outer side of the first bending portion and adjacent to the first bending portion with the separator being therebetween, and comprises a positive electrode current collector and a positive electrode material layer located on a concave surface of the positive electrode current collector;
wherein a corner lithium plating coefficient β of the lithium-ion battery satisfies a first formula of
β
=
R/
R+L
,
0.015≤β≤0.95, R is a minimum curvature radius of the convex surface of the negative electrode current collector of the first bending portion, and
L is a shortest distance between the convex surface of the negative electrode current collector of the first bending portion and the concave surface of the positive electrode current collector of the second bending portion:
wherein the electrolyte solution contains a fluorosulfonate salt and/or a difluorophosphate salt substance; and
a percentage mass content w% of the fluorosulfonate salt and/or the difluorophosphate salt substance in the electrolyte solution and the corner lithium plating coefficient β satisfy a second formula of.
0.01
≤
w
×
β
≤
20
.
2 . The lithium-ion battery according to claim 1 , wherein 0.02≤w×β≤5.
3 . The lithium-ion battery according to claim 1 , wherein 0.15≤β≤0.8.
4 . The lithium-ion battery according to claim 1 , wherein a range of R is 2 µm to 5000 µm.
5 . The lithium-ion battery according to claim 1 , wherein a range of L is 20 µm to 900 µm.
6 . The lithium-ion battery according claim 1 , wherein
a structural formula of the fluorosulfonate salt is (FSO 3 ) x M x+ , wherein M x+ is selected from one or two more of Li + , Na + K + , Rb + , Cs + , Mg 2+ , Ca 2+ , Ba 2+ , Al 3+ , Fe 2+ , Fe 3+ , Ni 2+ and Ni 3+ , and
a structural formula of the difluorophosphate salt is (F 2 PO 2 ) y M y+ , wherein M y+ is selected from one or two more of Li + , Na + , K + , Rb + , Cs + , Mg 2+ , Ca 2+ , Ba 2+ , Al 3+ , Fe 2+ , Fe 3+ , Ni 2+ and Ni 3+ .
7 . The lithium-ion battery according to claim 1 , wherein a percentage mass content w% of the fluorosulfonate salt and/or the difluorophosphate salt substance in the electrolyte solution has a range of 0.02% to 25%.
8 . The lithium-ion battery according to claim 1 , wherein the electrolyte solution further contains fluoroethylene carbonate and/or 1,3-propanesultone, and a percentage mass content of the fluoroetbylene carbonate and/or 1,3-propanesultone in the electrolyte solution is 0.01% to 15%.
9 . The lithium-ion battery according to claim 1 , wherein a porosity of the negative electrode active layer is 20% to 50%.
10 . The lithium-ion battery according to claim 4 , wherein the range of R is 50 µm to 500 µm.
11 . The lithium-ion battery according to claim 5 , wherein the range of L is 50 µm to 500 µm.
12 . The lithium-ion battery according to claim 7 , wherein the percentage mass content w% of the fluorosulfonate salt and/or the difluorophosphate salt substance in the electrolyte solution has a range of 0.02% to 20%.
13 . The lithium-ion battery according to claim 12 , wherein the percentage mass content w% of the fluorosulfonate salt and/or the difluorophosphate salt substance in the electrolyte solution has a range of 0.05% to 10%.
14 . The lithium-ion battery according to claim 13 , wherein the percentage mass content w% of the fluorosulfonate salt and/or the difluorophosphate salt substance in the electrolyte solution has a range of 0.1 % to 5%.
15 . The lithium-ion battery according to claim 8 , wherein the percentage mass content of the fluoroethylene carbonate and/or 1,3-propanesultone in the electrolyte solution is 0.1% to 2%.
16 . The lithium-ion battery according to claim 9 , wherein the porosity of the negative electrode active layer is 30% to 50%.
17 . A battery module, comprising one or more of the lithium-ion battery according to claim 1 .
18 . A battery pack, comprising one or more of the battery module according to claim 17 .