IP Library Granted Patent US 11,919,070
Granted Patent B2
US 11,919,070 · App. 18/083,748 · Granted Mar 5, 2024

Fabrication of metallic parts by additive manufacturing

Inventor: Michael T. Stawovy (Cleveland Heights, OH)
Assignee: H.C. STARCK SOLUTIONS COLDWATER, LLC
B22D7/005B21C1/02B22F3/02B22F3/24B22F5/12B22F10/25B22F10/38B23K9/044B23K9/24B23K9/295B23K15/0086B23K15/0093B32B15/01B33Y10/00B33Y70/00B33Y80/00C22C27/04F27D11/08B22F10/00B22F10/20B22F2301/20B23K2103/08Y02P10/25
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Quick Facts
Patent No.
US 11,919,070
App. No.
18/083,748
Granted
Mar 5, 2024
Kind
B2
Abstract

In various embodiments, wire composed at least partially of arc-melted refractory metal material is utilized to fabricate three-dimensional parts by additive manufacturing.

Claims (33)

1. A method of fabricating a three-dimensional part comprising a metallic material, the method comprising:

(a) providing a wire comprising arc-melted metallic material, wherein the wire is produced by a process comprising (i) in a processing ambient comprising a vacuum or one or more inert gases, arc-melting a feed electrode comprising the metallic material to thereby form a billet, and (ii) mechanically deforming the billet into wire having a diameter less than a diameter of the billet;

(b) translating a tip of the wire relative to a platform;

(c) while the tip of the wire is being translated, melting the tip of the wire with an energy source to form a molten bead, whereby the bead cools to form at least a portion of a layer of a three-dimensional part; and

(d) repeating steps (b) and (c) one or more times to produce the three-dimensional part,

wherein the three-dimensional part comprises the metallic material.

2. The method of claim 1 , wherein the metallic material comprises at least one of niobium, tantalum, rhenium, tungsten, or molybdenum.

3. The method of claim 1 , wherein a concentration within the wire of at least one of sodium, calcium, antimony, magnesium, phosphorous, or potassium is less than 5 ppm by weight.

4. The method of claim 1 , wherein a concentration of oxygen within the wire is less than 20 ppm by weight.

5. The method of claim 1 , wherein a density of the three-dimensional part is greater than 97% of a theoretical density of the metallic material.

6. The method of claim 1 , wherein in step (c) the energy source comprises an electron beam and/or a laser beam.

7. A method of fabricating a three-dimensional part comprising a metallic material, the method comprising:

(a) providing a wire comprising arc-melted metallic material;

(b) translating a tip of the wire relative to a platform;

(c) while the tip of the wire is being translated, melting the tip of the wire with an energy source to form a molten bead, whereby the bead cools to form at least a portion of a layer of a three-dimensional part; and

(d) repeating steps (b) and (c) one or more times to produce the three-dimensional part,

wherein the three-dimensional part comprises the metallic material, and the wire is produced by a process comprising:

compacting powder to form a feed electrode, the powder comprising the metallic material;

arc-melting the feed electrode in a processing ambient comprising a vacuum or one or more inert gases, thereby forming a billet; and

mechanically deforming the billet into wire having a diameter less than a diameter of the billet.

8. The method of claim 7 , wherein the metallic material comprises at least one of niobium, tantalum, rhenium, tungsten, or molybdenum.

9. The method of claim 7 , wherein a concentration within the wire of at least one of sodium, calcium, antimony, magnesium, phosphorous, or potassium is less than 5 ppm by weight.

10. The method of claim 7 , wherein a concentration of oxygen within the wire is less than 20 ppm by weight.

11. The method of claim 7 , wherein a density of the three-dimensional part is greater than 97% of a theoretical density of the metallic material.

12. The method of claim 7 , wherein in step (c) the energy source comprises an electron beam and/or a laser beam.

13. The method of claim 7 , wherein mechanically deforming the billet comprises at least one of drawing, rolling, swaging, extruding, or pilgering.

14. The method of claim 7 , wherein the wire-production process comprises sintering the compacted powder at a temperature greater than 900° C.

15. The method of claim 7 , wherein the wire-production process comprises providing the powder by a process comprising at least one of plasma densification or plasma atomization.

16. The method of claim 7 , wherein the wire-production process comprises:

hydrogenating metal to form a metal hydride;

mechanically grinding the metal hydride into a plurality of particles; and

dehydrogenating the metal hydride particles.

17. The method of claim 1 , wherein mechanically deforming the billet comprises at least one of drawing, rolling, swaging, extruding, or pilgering.

Assignments (5)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2026
From: H.C. STARCK SOLUTIONS COLDWATER, LLC
To: ELMET TECHNOLOGIES, LLC
Reel/Frame 073679/0616 →
SECURITY INTEREST Recorded Nov 6, 2023
From: H.C. STARCK SOLUTIONS COLDWATER, LLC; H.C. STARCK SOLUTIONS EUCLID, LLC
To: WELLS FARGO BANK, NATIONAL ASSOCIATION
Reel/Frame 065472/0843 →
CHANGE OF NAME Recorded Nov 1, 2023
From: COLDWATER FACILITY HOLDING, LLC
To: H.C. STARCK SOLUTIONS COLDWATER, LLC
Reel/Frame 065415/0744 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 31, 2023
From: H.C. STARCK INC.
To: COLDWATER FACILITY HOLDING, LLC
Reel/Frame 065402/0530 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 18, 2023
From: STAWOVY, MICHAEL THOMAS
To: H.C. STARCK INC.
Reel/Frame 063684/0978 →