LITHIUM ION BATTERY, BATTERY MODULE, BATTERY PACK AND POWER CONSUMING DEVICE
The present application provides a lithium ion battery, comprising an electrode assembly and an electrolyte comprising a fluorosulfonate and/or difluorophosphate substance. The lithium ion battery has a gas generation area coefficient during formation, defined as α, with α=M×S/200; wherein M is in the range of 5 mg/cm 2 -100 mg/cm 2 ; S is the specific surface area of the negative electrode material on the negative electrode current collector and is in the range of 0.1 m 2 /g-10 m 2 /g; the lithium ion battery has a gas venting path coefficient defined as β, with β=100/L, wherein L is in the range of L≥50 mm; the mass percentage content w % of the fluorosulfonate and/or difluorophosphate substance in the electrolyte and α and β meet the equation 0.01≤w×β/α≤20.
1 . A lithium ion battery, comprising:
an electrode assembly, wherein the electrode assembly comprises a negative electrode current collector and a negative electrode material provided on at least one surface of the negative electrode current collector; and
an electrolyte, comprising a fluorosulfonate and/or difluorophosphate substance;
wherein the lithium ion battery has a gas generation area coefficient during formation defined as α, with α=M×S/200, equation (I),
in the equation (I), M is the loading of the negative electrode material per unit area of the negative electrode current collector, in mg/cm 2 , and M is in the range of 5 mg/cm 2 -100 mg/cm 2 ,
in the equation (I), S is the specific surface area of the negative electrode material on the negative electrode current collector, in m 2 /g, and S is in the range of 0.1 m 2 /g-10 m 2 /g,
and the lithium ion battery has a gas venting path coefficient defined as β, with β=100/L, equation (II),
in the equation (II), L is the width of the area coated with the negative electrode material on the surface of the negative electrode current collector, in mm, and L is in the range of L≥50 mm,
wherein the mass percentage content w % of the fluorosulfonate and/or difluorophosphate substance in the electrolyte, the gas generation area coefficient during formation α of the lithium ion battery, and the gas venting path coefficient β of the lithium ion battery satisfy 0.01≤w×β/α≤20, formula (III).
2 . The lithium ion battery according to claim 1 , wherein
the fluorosulfonate has a structural formula of (FSO 3 ) y M y+ , wherein M y+ is selected from one of Li + , Na + , K + , Rb + , Cs + , Mg 2+ , Ca 2+ , Ba 2+ , Al 3+ , Fe 2+ , Fe 3+ , Ni 2+ and Ni 3+ .
3 . The lithium ion battery according to claim 1 , wherein
the difluorophosphate has a structural formula of (F 2 PO 2 ) y M y+ , wherein M y+ is selected from one of Li + , Na + , K + , Rb + , Cs + , Mg 2+ , Ca 2+ , Ba 2+ , Al 3+ , Fe 2+ , Fe 3+ , Ni 2+ and Ni 3+ .
4 . The lithium ion battery according to claim 1 , wherein
the mass percentage content w % of the fluorosulfonate and/or difluorophosphate substance in the electrolyte is in the range of 0.01%-11%, optionally 0.5%-10%, and further optionally 0.5%-5%.
5 . The lithium ion battery according to claim 1 , wherein
the loading M of the negative electrode material per unit area of the negative electrode current collector is in the range of 11 mg/cm 2 -80 mg/cm 2 , optionally 11 mg/cm 2 -50 mg/cm 2 .
6 . The lithium ion battery according to claim 1 , wherein
the specific surface area S of the negative electrode material on the negative electrode current collector is in the range of 0.5 m 2 /g-5 m 2 /g.
7 . The lithium ion battery according to claim 1 , wherein
the width L of the area coated with the negative electrode material on the negative electrode current collector is in the range of 50 mm≤L≤200 mm, optionally 50 mm≤L≤100 mm.
8 . The lithium ion battery according to claim 1 , wherein
the electrolyte comprises fluoroethylene carbonate and/or 1,3-propane sultone.
9 . The lithium ion battery according to claim 1 , wherein
the negative electrode material has a porosity of 10%-40%.
10 . A battery module,
comprising a lithium ion battery according to claim 1 .
11 . A battery pack,
comprising a lithium ion battery according to claim 1 .
12 . The lithium ion battery according to claim 2 , wherein
the mass percentage content w % of the fluorosulfonate and/or difluorophosphate substance in the electrolyte is in the range of 0.01%-11%, optionally 0.5%-10%, and further optionally 0.5%-5%.
13 . The lithium ion battery according to claim 3 , wherein
the mass percentage content w % of the fluorosulfonate and/or difluorophosphate substance in the electrolyte is in the range of 0.01%-11%, optionally 0.5%-10%, and further optionally 0.5%-5%.
14 . The lithium ion battery according to claim 2 , wherein
the loading M of the negative electrode material per unit area of the negative electrode current collector is in the range of 11 mg/cm 2 -80 mg/cm 2 , optionally 11 mg/cm 2 -50 mg/cm 2 .
15 . The lithium ion battery according to claim 3 , wherein
the loading M of the negative electrode material per unit area of the negative electrode current collector is in the range of 11 mg/cm 2 -80 mg/cm 2 , optionally 11 mg/cm 2 -50 mg/cm 2 .
16 . The lithium ion battery according to claim 2 , wherein
the specific surface area S of the negative electrode material on the negative electrode current collector is in the range of 0.5 m 2 /g-5 m 2 /g.
17 . The lithium ion battery according to claim 3 , wherein
the specific surface area S of the negative electrode material on the negative electrode current collector is in the range of 0.5 m 2 /g-5 m 2 /g.
18 . The lithium ion battery according to claim 2 , wherein
the width L of the area coated with the negative electrode material on the negative electrode current collector is in the range of 50 mm≤L≤200 mm, optionally 50 mm≤L≤100 mm.
19 . The lithium ion battery according to claim 2 , wherein
the electrolyte comprises fluoroethylene carbonate and/or 1,3-propane sultone.
20 . The lithium ion battery according to claim 2 , wherein
the negative electrode material has a porosity of 10%-40%.