Golf ball components formed from hydroxyurethane compositions
Thermoplastic and thermoset compositions including hydroxyurethane linkages, golf ball components formed using such thermoplastic or thermoset compositions, and golf balls including such golf components.
1. A golf ball, comprising:
a core; and
a cover, wherein the cover is formed from a composition comprising hydroxyurethane linkages and urethane linkages, wherein the ratio of hydroxyurethane linkages to urethane linkages ranges from 50:1 to 2:1, and wherein the composition comprises a first reaction product of at least one cyclic carbonate and at least one amine-terminated component and a second reaction product of an isocyanate-containing component and an isocyanate-reactive component.
2. The golf ball of claim 1 , wherein the first reaction product further comprises a chain extender.
3. The golf ball of claim 2 , wherein the chain extender comprises a diamide-diamine.
4. The golf ball of claim 1 , wherein the cyclic carbonate comprises a five-membered cyclic carbonate, a six-membered cyclic carbonate, or a combination thereof.
5. The golf ball of claim 1 , wherein the amine-terminated component comprises two primary functional amines at each end of a polyether polyol backbone.
6. The golf ball of claim 5 , wherein the polyether polyol comprises polyoxytetramethylene glycol (PTMEG), polyoxyethylene glycol (PEG), polyethylene propylene glycol, polyoxypropylene glycol (PPG), or mixtures thereof.
7. The golf ball of claim 1 , further comprising a layer disposed between the core and the cover.
8. The golf ball of claim 7 , wherein the layer comprises an ionomer material.
9. A golf ball, comprising:
a core; and
a cover, wherein the cover is formed from a composition comprising hydroxyurethane linkages and urea linkages, wherein the ratio of hydroxyurethane linkages to urea linkages ranges from 50:1 to 2:1, and wherein the composition comprises a first reaction product of at least one cyclic carbonate, at least one amine-terminated component, and an amine-terminated chain extender, and a second reaction product of an isocyanate-containing component and an isocyanate-reactive component.
10. The golf ball of claim 9 , wherein the amine-terminated chain extender comprises a diamine-diamide.
11. The golf ball of claim 9 , wherein the cyclic carbonate comprises trimethylene carbonate, 5-(2-propenyl)-1,3-dioxan-2-one, 1,2-bis[3-(1,3-dioxan-2-one-5-yl)-propylthio]ethane, divinyl benzene dicyclocarbonate, or a combination thereof.
12. The golf ball of claim 9 , wherein the amine-terminated component comprises two primary amine functional groups.
13. The golf ball of claim 9 , further comprising a layer disposed between the core and the cover.
14. The golf ball of claim 13 , wherein the layer comprises an ionomer material.
15. A method of forming a golf ball, comprising the steps of:
providing a golf ball sub-assembly comprising at least one core layer;
forming a first reaction product comprising hydroxyurethane linkages from the reaction product of a cyclic carbonate, an amine-terminated component comprising two primary amine functional groups, and a chain extender;
adding an isocyanate-containing component to the first reaction product to form a second reaction product comprising hydroxyurethane and urethane and/or urea linkages; and
forming a cover disposed about the sub-assembly, the cover comprising the second reaction product.
16. The method of claim 15 , wherein the step of forming a first reaction product comprises providing a cyclic carbonate comprises a five-membered cyclic carbonate, a six-membered cyclic carbonate, or a combination thereof.
17. The method of claim 15 , wherein the isocyanate-containing component is a blocked isocyanate.
18. The method of claim 17 , wherein the step of adding further comprises the step of exposing the isocyanate groups to crosslinking.
19. The method of claim 15 , wherein the step of forming a first reaction product comprises providing an amine-terminated component comprising two primary amine functional groups at the ends of a polyol backbone.
20. The method of claim 15 , wherein the second reaction product comprises a ratio of hydroxyurethane linkages to urethane and/or urea linkages of 50:1 to 2:1.