INSULATING SLURRY AND PREPARATION METHOD THEREOF, POSITIVE ELECTRODE PLATE, SECONDARY BATTERY, BATTERY MODULE, BATTERY PACK, AND ELECTRIC APPARATUS
This application provides an insulating slurry and a preparation method thereof, a positive electrode plate, a secondary battery, a battery module, a battery pack, and an electric apparatus. The insulating slurry may include a resin, an inorganic filler, and an organic solvent, where the resin is selected from polyfluorinated olefin resins prepared in a suspension polymerization method, and the inorganic filler is a two-dimensional inorganic material. In this application, both a coating velocity of the insulating slurry and safety performance of the secondary battery can be improved.
1 . An insulating slurry, comprising a resin, an inorganic filler, and an organic solvent, wherein
the resin is selected from polyfluorinated olefin resins prepared by using a suspension polymerization method, and the inorganic filler is a two-dimensional inorganic material; and
optionally, the two-dimensional inorganic material has a layered, flake-like, or thin plate-like morphology.
2 . The insulating slurry according to claim 1 , wherein
based on a total mass of the insulating slurry, a mass percentage w 1 of the resin is 1%-5%, a mass percentage w 2 of the inorganic filler is 5%-35%, and a mass percentage w 3 of the organic solvent is 60%-94%; and
optionally, w 1 /w 2 is 0.05-1.
3 . The insulating slurry according to claim 1 , wherein viscosity of the insulating slurry at 25° C. is 1000-20000 cps.
4 . The insulating slurry according to claim 1 , wherein
a number-average molecular weight of the resin is 600000-1500000;
crystallinity of the resin is 30%-60%; and/or
a melting point of the resin is 150-180° C.
5 . The insulating slurry according to claim 4 , wherein the resin is selected from at lest one of polyvinylidene fluoride resin, polyvinyl fluoride resin, polytetrafluoroethylene resin, vinylidene fluoride-hexafluoropropyene copolymer resin, vinylidene fluoride-trifluoroethylene copolymer resin, vinylidene fluoride-chlorotrifluoroethylene copolymer resin, vinylidene fluoride-tetrafluoroethylene copolymer resin, and vinylidene fluoride-tetrafluoroethylene-hexafluoropropylene copolymer resin.
6 . The insulating slurry according to claim 1 , wherein the two-dimensional inorganic material is selected from at least one of layered silicate and a two-dimensional molecular sieve;
optionally, the layered silicate comprises at least one of mica powder, fluorophlogopite powder, talc powder, hydrotalcite, and a hydrotalcite-like compound; and
optionally, the two-dimensional molecular sieve comprises at least one of an MWW-type, an SAPO-type, an FER-type, and a PLS-n-type molecular sieve.
7 . The insulating slurry according to claim 1 , wherein
a median particle size by volume D v 50 of the two-dimensional inorganic material is 0.5-10 μm; and/or
a diameter-thickness ratio of the two-dimensional inorganic material is greater than or equal to 50:1.
8 . The insulating slurry according to claim 1 , wherein the organic solvent comprises at least one of N-methylpyrrolidone, triethyl phosphate, dimethyl sulfoxide, N,N-dimethylformamide, and N,N-dimethylacetamide.
9 . The insulating slurry according to claim 1 , wherein a mass percentage of an emulsifier in the insulating slurry is less than or equal to 1/1000000.
10 . A preparation method of insulating slurry, comprising:
dispersing an organic solvent and an inorganic filler to obtain a first slurry; and
adding resin particles to the obtained first slurry in a dispersed state, and obtaining the insulating slurry after dispersion; wherein
the inorganic filler is a two-dimensional inorganic material, and the resin particles are selected from polyfluorinated olefin resins prepared by using a suspension polymerization method.
11 . The method according to claim 10 , wherein based on a total mass of the insulating slurry, a mass percentage of the resin particles is 1%-5%, a mass percentage of the inorganic filler is 5%-35%, and a mass percentage of the organic solvent is 60%-94%.
12 . The method according to claim 10 , wherein
in the dispersing step, a dispersion linear velocity is 20-100 m/s, and dispersion time is 15-120 min; and/or
in the adding step, a dispersion linear velocity is 20-100 m/s, and dispersion time is 120-480 min.
13 . The method according to claim 10 , wherein the method further comprises:
filtering the obtained insulating slurry.
14 . The method according to claim 10 , wherein the resin particles are primary particles, and a median particle size by volume D v 50 of the primary particles is 20-150 μm.
15 . A positive electrode plate, comprising:
a positive electrode current collector;
a positive electrode active material layer, located on at least part of a surface of the positive electrode current collector; and
an insulating coating, located on the surface of the positive electrode current collector and abutting an edge of the positive electrode active material layer along a length direction of the positive electrode current collector, wherein
the insulating coating is a layer formed by drying the insulating slurry according to claim 1 .
16 . The positive electrode plate according to claim 15 , wherein
a thickness of the insulating coating is 2-150 μm; and/or
a width of the insulating coating is 0.1-15 mm.
17 . A secondary battery, comprising the positive electrode plate according to claim 15 .
18 . A battery module, comprising the secondary battery according to claim 17 .
19 . A battery pack, comprising the secondary battery according to claim 17 .
20 . An electric apparatus, comprising the secondary battery according to claim 17 .