POSITIVE ELECTRODE PLATE AND ELECTROCHEMICAL DEVICE
The present invention relates to a positive electrode plate and an electrochemical device. The positive electrode plate comprises a current collector, a positive active material layer and a safety coating disposed between the current collector and the positive active material layer, and wherein the safety coating comprises a polymer matrix, a conductive material and an inorganic filler and wherein when the safety coating and the positive active material layer are collectively referred as a film layer, the film layer has an elongation of 30% or more and wherein the polymer matrix of the safety coating is fluorinated polyolefin and/or chlorinated polyolefin having a crosslinked structure. The positive electrode plate may improve the safety performance during nail penetration of the electrochemical device such as capacitor, primary battery or secondary battery and the like.
1 . A positive electrode plate comprising a current collector, a positive active material layer and a safety coating disposed between the current collector and the positive active material layer, and wherein the safety coating comprises a polymer matrix, a conductive material and an inorganic filler and wherein when the safety coating and the positive active material layer are collectively referred as a film layer, the film layer has an elongation of 30% or more, and wherein the polymer matrix of the safety coating is fluorinated polyolefin and/or chlorinated polyolefin having a crosslinked structure.
2 . The positive electrode plate as claimed in claim 1 , wherein the fluorinated polyolefin and/or chlorinated polyolefin is selected from at least one of polyvinylidene fluoride (PVDF), carboxylic acid modified PVDF, acrylic acid modified PVDF, polyvinylidene chloride (PVDC), carboxylic acid modified PVDC, acrylic acid modified PVDC, PVDF copolymer, PVDC copolymer.
3 . The positive electrode plate as claimed in claim 1 , wherein the conductive material is selected from at least one of a conductive carbon-based material, a conductive metal material, and a conductive polymer material,
wherein the conductive carbon-based material is selected from at least one of conductive carbon black, acetylene black, graphite, graphene, carbon nanotubes, carbon nanofibers;
the conductive metal material is selected from at least one of Al powder, Ni powder, and gold powder; and
the conductive polymer material is selected from at least one of conductive polythiophene, conductive polypyrrole, and conductive polyaniline.
4 . The positive electrode plate as claimed in claim 1 , wherein the inorganic filler is selected from at least one of a metal oxide, a non-metal oxide, a metal carbide, a non-metal carbide, and an inorganic salt, or at least one of a conductive carbon coating modified above material, a conductive metal coating modified above material or a conductive polymer coating modified above material.
5 . The positive electrode plate as claimed in claim 1 , wherein the inorganic filler of the safety coating is at least one of magnesium oxide, aluminum oxide, titanium dioxide, zirconium oxide, silicon dioxide, silicon carbide, boron carbide, calcium carbonate, aluminum silicate, calcium silicate, potassium titanate, barium sulfate, lithium cobalt oxide, lithium nickel manganese cobalt oxide, lithium nickel manganese aluminium oxide, lithium iron phosphate, lithium vanadium phosphate, lithium cobalt phosphate, lithium manganese phosphate, lithium manganese iron phosphate, lithium iron silicate, lithium vanadium silicate, lithium cobalt silicate, lithium manganese silicate, spinel lithium manganese oxide, spinel lithium nickel manganese oxide, and lithium titanate, or a conductive carbon coating modified above material, a conductive metal coating modified above material, a conductive polymer coating modified above material or at least one of a conductive carbon coating modified above material, a conductive metal coating modified above material or a conductive polymer coating modified above material.
6 . The positive electrode plate as claimed in claim 1 , wherein the inorganic filler has an average particle diameter D of 100 nm≤D≤10 μm.
7 . The positive electrode plate as claimed in claim 1 , wherein the inorganic filler has a specific surface area (BET) of not more than 500 m 2 /g.
8 . The positive electrode plate as claimed in claim 1 , wherein in the safety coating, relative to the total weight of the inorganic filler, the polymer matrix and the conductive filler,
the inorganic filler is present in an amount of 35 wt % to 75 wt %;
the conductive material is present in an amount of 5 wt % to 25 wt %; and
the inorganic filler is present in an amount of from 10 wt % to 60 wt %.
9 . The positive electrode plate as claimed in claim 1 , wherein the weight ratio of the polymer matrix to the conductive material is 3 or more and 8 or less.
10 . The positive electrode plate as claimed in claim 1 , wherein the current collector is a metal current collector and the current collector has an elongation at breaks that fulfills 0.8%≤δ≤4%.
11 . The positive electrode plate as claimed in claim 1 , wherein the current collector is a porous current collector.
12 . The positive electrode plate as claimed in claim 1 , wherein the film layer has a single side thickness of 30 μm˜80 μm.
13 . The positive electrode plate as claimed in claim 1 , wherein there is a binding force between the film layer and the current collector of 10 N/m or more.
14 . An electrochemical device comprising the positive electrode plate as claimed in claim 1 , which is a capacitor, a primary battery or a secondary battery.