Processes for producing high-purity trifluoroiodomethane
The present disclosure provides a method for purifying trifluoroiodomethane. The method includes providing a process stream comprising trifluoroiodomethane, organic impurities, and acid impurities; reacting the process stream with a basic aqueous solution, the basic aqueous solution comprising water and at least one base selected from the group of an alkali metal carbonate and an alkali metal hydroxide; and separating at least some of the organic impurities from the process stream.
1 . A method for purifying trifluoroiodomethane, the method comprising:
providing a process stream comprising trifluoroiodomethane, organic impurities, and acid impurities;
reacting the process stream with a basic aqueous solution, the basic aqueous solution comprising water and an alkali metal carbonate, wherein a concentration of the alkali metal carbonate in the basic aqueous solution is from about 0.5 wt. % to about 5 wt. %; and
separating at least some of the organic impurities from the process stream.
2 . The method of claim 1 , wherein the alkali metal carbonate comprises sodium carbonate.
3 . The method of claim 1 , wherein in the reacting step, a temperature of the process stream is from about 5° C. to about 80° C. and a pressure of the process stream is from about 1 psig to about 100 psig.
4 . The method of claim 1 , wherein in the providing step, the organic impurities include methyl iodide, and a concentration of the methyl iodide in the process stream, in GC area % area% of total organic compounds, is reduced by from about 1% to about 70% by the reacting step.
5 . The method of claim 1 , further comprising an additional step of drying to remove at least some of the water from the process stream immediately after the reacting step.
6 . The method of claim 5 , wherein after the reacting step, the drying step, and the separation step, the process stream includes at least about 99 wt. % trifluoroiodomethane, less than about 50 ppm methyl iodide, less than about 100 ppm water, and less than about 20 ppm acid impurities.
7 . A method for purifying trifluoroiodomethane, the method comprising:
providing a process stream comprising trifluoroiodomethane, organic impurities, and acid impurities;
contacting the process stream in the liquid phase with an acid reactive active agent comprising an adsorbent; and
separating at least some of the organic impurities from the process stream.
8 . The method of claim 7 , wherein the acid reactive active agent comprises an alumina adsorbent.
9 . The method of claim 7 , wherein in the contacting step, the process stream is in a liquid phase, a temperature of the process stream is from about −50° C. to about 50° C. and a pressure of the process stream is from about 1 psig to about 100 psig.
10 . The method of claim 7 , wherein in the contacting step, the process stream is in a gas phase, a temperature of the process stream is from about −20° C. to about 60° C. and a pressure of the process stream is from about 1 psig to about 100 psig.
11 . The method of claim 7 , wherein the contacting step precedes the separation step.
12 . The method of claim 7 , further comprising an additional step of drying to remove at least some of the water from the process stream immediately after the contacting step.
13 . The method of claim 12 , wherein after the contacting step, the drying step, and the separation step, the process stream includes at least about 99 wt. % trifluoroiodomethane, less than about 50 ppm methyl iodide, less than about 100 ppm water, and less than about 20 ppm acid impurities.
14 . A method for purifying trifluoroiodomethane, the method comprising:
providing a process stream comprising trifluoroiodomethane, organic impurities comprising methyl iodide, and acid impurities;
reacting the process stream with a basic aqueous solution, the basic aqueous solution comprising water and an alkali metal hydroxide, wherein a concentration of the alkali metal hydroxide in the basic aqueous solution is from about 0.01 wt. % to about 0.5 wt. % 5 wt.%; wherein a temperature of the process stream is from about 5° C. to about 80° and a pressure of the process stream is from about 1 psig to about 100 psig; and a concentration of the methyl iodide in the process stream, in GC area % of total organic compounds, is reduced by at least about 5%; and
separating at least some of the organic impurities from the process stream.
15 . The method of claim 14 , wherein the alkali metal hydroxide includes potassium hydroxide.
16 . The method of claim 14 , wherein in the reacting step, a temperature of the process stream is from about 5° C. to about 80° C. and a pressure of the process stream is from about 1 psig to about 100 psig.
17 . The method of claim 14 , wherein in the providing step, the organic impurities include methyl iodide, and a the concentration of the methyl iodide in the process stream, in GC area % area% of total organic compounds, is reduced by from about 1% 5% to about 70% by the reacting step.
18 . The method of claim 14 , further comprising an additional step of drying to remove at least some of the water from the process stream immediately after the reacting step.
19 . The method of claim 18 , wherein after the reacting step, the drying step, and the separation step, the process stream includes at least about 99 wt. % trifluoroiodomethane, less than about 50 ppm methyl iodide, less than about 100 ppm water, and less than about 20 ppm acid impurities.
20. The method of claim 14 , wherein a concentration of the alkali metal hydroxide in the basic aqueous solution is from about 0.01 wt.% to about 2 wt.%.
21. The method of claim 14 , wherein a concentration of the alkali metal hydroxide in the basic aqueous solution is from about 0.01 wt.% to about 1 wt.%.
22. The method of claim 14 , wherein a concentration of the alkali metal hydroxide in the basic aqueous solution is from about 0.01 wt.% to about 0.5 wt.%.
23. The method of claim 14 , wherein a concentration of the alkali metal hydroxide in the basic aqueous solution is from about 0.1 wt.% to about 5 wt.%.
24. The method of claim 14 , wherein a concentration of the alkali metal hydroxide in the basic aqueous solution is from about 0.1 wt.% to about 2 wt.%.
25. The method of claim 14 , wherein a concentration of the alkali metal hydroxide in the basic aqueous solution is from about 0.1 wt.% to about 1 wt.%.
26. The method of claim 14 , wherein a concentration of the alkali metal hydroxide in the basic aqueous solution is from about 0.1 wt.% to about 0.5 wt.%.