Method for upgrading low-value and waste fats, oils, and greases
The present technology provides a method that includes contacting a composition with a caustic solution to produce a caustic-treated composition; combining the caustic-treated composition with silica particles to produce a slurry; and removing the silica particles from the slurry to produce a treated composition; wherein the composition includes one or more of animal fats, animal oils, plant fats, plant oils, vegetable fats, vegetable oils, greases, and used cooking oil and the composition includes: at least about 10 wppm of total metals, at least about 8 wppm of phosphorus, at least about 10 wppm of chlorine, at least about 10 wppm of sulfur, at least about 20 wppm of nitrogen, at least about 5 wt. % of free fatty acids; and has an acid number from about 10 mg KOH/g to about 150 mg KOH/g, and the silica particles has a particle size from about 10 microns to about 50 microns, a BET surface area from about 200 m 2 /g to about 1000 m 2 /g.
1. A method comprising:
glycerolysis of a starting composition to provide a composition comprising about 5 wt. % to about 15 wt. % free fatty acids;
subsequent to glycerolysis, contacting the composition with a caustic solution to produce a first mixture;
separating from the first mixture a caustic-treated composition and producing an aqueous waste with a pH from about 2.0 to about 5.0;
combining the caustic-treated composition with silica particles to produce a slurry; and
removing the silica particles from the slurry to produce a treated composition;
wherein:
the composition comprises:
one or more of animal fats, animal oils, plant fats, plant oils, vegetable fats, vegetable oils, greases, and used cooking oil,
about 10 wppm or more of total metals;
about 8 wppm or more of phosphorus;
about 10 wppm or more of sulfur;
about 20 wppm or more of nitrogen; and
has an acid number from about 10 mg KOH/g to about 150 mg KOH/g;
the treated composition comprises:
a wt. % of free fatty acids about that of the composition; and
less total metals, phosphorus, sulfur, and nitrogen than the composition; and
the silica particles have an average particle size from about 10 microns to about 50 microns and a BET surface area from about 200 m 2 /g to about 1000 m 2 /g.
2. The method of claim 1 , wherein the composition comprises yellow grease, brown grease, floatation grease, poultry fat, inedible corn oil, used cooking oil, inedible tallow, floatation tallow, palm sludge oil, or a mixture of any two or more thereof.
3. The method of claim 1 , wherein the total metals comprise one or more members selected from the group consisting of As, Ca, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, Pb, Sr, and Zn.
4. The method of claim 1 , wherein the composition has an acid number from about 10 mg KOH/g to about 50 mg KOH/g.
5. The method of claim 1 , wherein the composition comprises about 5 wt. % to about 11 wt. % free fatty acids.
6. The method of claim 1 , wherein the composition comprises about 5 wt. % to about 10 wt. % free fatty acids.
7. The method of claim 1 , wherein the method further comprises an acid-degumming step prior to contacting the composition with a caustic solution.
8. The method of claim 1 , wherein the method further comprises an alkalinity reduction step prior to contacting the composition with a caustic solution.
9. The method of claim 1 , wherein the method does not comprise contacting the composition with bleaching clays.
10. The method of claim 1 , wherein the caustic solution comprises an aqueous ammonium hydroxide solution, aqueous potassium hydroxide solution, aqueous sodium hydroxide solution, or a combination of any two or more thereof.
11. The method of claim 1 , wherein the silica particles comprise amorphous silica particles.
12. The method of claim 1 , wherein the silica particles are combined with the caustic-treated composition about 0.1% (w/w) to about 0.8% (w/w) based on weight of the silica particles to weight of the caustic-treated composition.
13. The method of claim 1 , wherein the silica particles have an aqueous solution pH of about 2.0 to about 6.0.
14. The method of claim 1 , wherein the combining with silica particles is conducted at a temperature from about 150° F. to about 200° F., and the slurry is subjected to an absolute pressure from about 100 Torr to about 500 Torr.
15. The method of claim 1 , wherein the combining with silica particles is conducted in a continuous flow operation tank.
16. The method of claim 1 , wherein the combining with silica particles comprises a residence time from about 10 min to about 90 min.
17. The method of claim 1 , wherein the method further comprises combining the slurry with diatomaceous earth (DE), wherein a weight ratio of DE to silica particles is from about 0.1:1 to about 1.5:1.
18. The method of claim 1 , wherein the removing comprises filtering the slurry with one or more filters.
19. The method of claim 18 , wherein the one or more filters comprise pressure leaf filters, wherein the pressure leaf filters are optionally pre-coated with at least one or more of DE, cellulose, and perlite.
20. The method of claim 1 , wherein the composition comprises 5 wt. % to about 10 wt. % free fatty acids; and the treated composition comprises:
less than 10 wppm of total metals;
less than 5 wppm of phosphorus;
less than 5 wppm of chlorine;
less than 5 wppm of sulfur;
less than 100 wppm of nitrogen; and
has an acid number from 10 mg KOH/g to about 20 mg KOH/g.