Process and burner apparatus for acid regeneration
A burner, process and furnace are provided for regenerating a spent acid stream or other sulfur-containing stream by decomposing the spent sulfuric acid stream and/or other sulfur-containing stream to recover sulfur dioxide from the stream. The burner includes a burner body, and at least one spent acid feed passage positioned at least partially within the burner body or other sulfur-containing feed passage positioned at least partially within the burner body. At least one fuel feed passage may be positioned at least partially within the burner body. A related process and furnace are also provided.
1 . A burner for a furnace, comprising:
a burner body;
at least one combustion fuel feed passage positioned at least partially within the burner body;
an air inlet in fluid communication with the burner body; and
at least one spent sulfuric acid feed passage positioned at least partially within the burner body.
2 . The burner of claim 1 , wherein the at least one spent sulfuric acid feed passage comprises at least one spent sulfuric acid feed injector positioned at least partially within the burner body.
3 . The burner of claim 1 , wherein the at least one combustion fuel feed passage comprises at least one combustion fuel feed injector positioned at least partially within the burner body.
4 . The burner of claim 1 , wherein the air inlet comprises an oxygen-enriched air inlet.
5 . The burner of claim 1 , wherein the at least one spent sulfuric acid feed passage is positioned at least partially within the at least one combustion fuel feed passage.
6 . The burner of claim 5 , further comprising an air inlet in fluid communication with the burner body.
7 . The burner of claim 6 , wherein the air inlet comprises an oxygen-enriched air inlet.
8 . The burner of claim 5 , comprising more than one spent sulfuric acid feed injector at least partially positioned within the combustion fuel feed passage.
9 . The burner of claim 8 , further comprising at least one of (i) more than one spent sulfuric acid feed injector positioned at least partially within the burner body, (ii) more than one combustion fuel feed injector positioned at least partially within the burner body, or (iii) more than one air feed injector positioned at least partially within the burner body.
10 . The burner of claim 1 , wherein the air inlet comprises an oxygen-enriched air inlet.
11 . The burner of claim 1 , further comprising at least one air feed passage at least partially positioned within the burner body.
12 . The burner of claim 11 , wherein the at least one air feed passage comprises at least one oxygen-enriched air injector.
13 . The burner of claim 11 , further comprising i) more than one spent sulfuric acid feed injector positioned at least partially within the burner body, (ii) more than one combustion fuel feed injector positioned at least partially within the burner body, and (iii) more than one air feed injector positioned at least partially within the burner body.
14 . The burner of claim 1 , further comprising a spent acid supply field adapted for use with the burner body for supplying at least one additional spent acid feed to the furnace.
15 . A process for decomposing at least one of a spent sulfuric acid feed comprising:
supplying a combustion fuel to a furnace interior through at least one combustion fuel feed passage that is at least partially positioned within a burner body, the at least one combustion fuel feed passage having an end opening into an atmosphere at the furnace interior;
supplying atmospheric combustion air or oxygen-enriched atmospheric combustion air into the furnace interior through an air feed passage at least partially positioned within the burner body; and
supplying at least one of the spent sulfuric acid feed into the furnace interior through a spent sulfuric acid feed passage that is at least partially positioned within the burner body, the at least one spent sulfuric acid feed passage having an end opening into the atmosphere at the furnace interior.
16 . The process of claim 15 , further comprising decomposing the at least one spent sulfuric acid feed in the furnace interior.
17 . The process of claim 15 , wherein the step of supplying the at least one spent sulfuric acid feed into the furnace interior comprises injecting the at least one spent sulfuric acid feed into the furnace interior with at least one spent sulfuric acid injector at least partially positioned within the burner body.
18 . The process of claim 15 , further comprising supplying at least one spent sulfuric acid feed into the furnace interior through the spent sulfuric acid feed passage, and supplying at least one combustion fuel feed into the interior of the furnace through the combustion fuel feed passage and that surrounds the spent sulfuric acid feed passage, wherein the combustion fuel feed supplied to the furnace interior forms a shroud surrounding the at least one spent sulfuric acid feed supplied to the furnace interior.
19 . The process of claim 15 , further comprising supplying at least one other sulfur-containing feed into the furnace interior through the other sulfur-containing feed passage, and supplying at least one combustion fuel feed into the interior of the furnace through the combustion fuel feed passage and that surrounds the other sulfur-containing feed passage, wherein the combustion fuel feed supplied to the furnace interior forms a shroud surrounding the at least one other sulfur-containing feed supplied to the furnace interior.
20 . The process of claim 15 , further comprising supplying pure oxygen directly into the furnace interior through a pure oxygen injector in direct fluid communication with the furnace interior.
21 . The process of claim 15 , further comprising supplying additional spent acid feed directly into the furnace interior through an injector field in direct fluid communication with the furnace interior.
22 . A furnace, comprising:
a housing having at least one side wall and an interior; and at least one burner engaged with a side wall of the furnace and in fluid communication with the interior of the furnace, the at least one burner comprising:
a burner body;
at least one combustion fuel feed passage positioned at least partially within the burner body;
at least one atmospheric air passage positioned at least partially within the burner body or at least one oxygen-enriched atmospheric air passage at least partially positioned within the burner body; and
at least one spent sulfuric acid feed passage positioned at least partially within the burner body.
23 . The furnace of claim 22 , wherein the at least one spent sulfuric acid feed passage comprises at least one spent sulfuric acid feed injector at least partially positioned within the burner body.
24 . The furnace of claim 22 , further comprising at least one pure oxygen injector in direct fluid communication with the interior of the furnace.
25 . The furnace of claim 22 , further comprising a spent sulfuric acid injector field in direct fluid communication with the interior of the furnace.