Quantum dot films utilizing multi-phase resins
Multi-phase polymer films containing quantum dots (QDs) are described herein. The films have domains of primarily hydrophobic polymer and domains of primarily hydrophilic polymer. QDs, being generally more stable within a hydrophobic matrix, are dispersed primarily within the hydrophobic domains of the films. The hydrophilic domains tend to be effective at excluding oxygen.
1. A light emitting device comprising:
a primary light source; and
a panel comprising a quantum dot (QD)-containing composition disposed between gas barrier sheets, wherein
the QD-containing composition is a cured emulsion having a plurality of domains of a first resin contained within a continuous domain of a second resin, and
quantum dots are dispersed in the first resin.
2. The light emitting device of claim 1 , wherein the primary light source is a backlight unit (BLU).
3. The light emitting device of claim 1 , wherein the first resin is selected from the group consisting of a poly(methyl(meth)acrylate), a poly(ethyl(meth)acrylate), a poly(n-propyl(meth)acrylate), a poly(butyl(meth)acrylate), a poly(n-pentyl(meth)acrylate), a poly(n-hexyl(meth)acrylate), a poly(cyclohexyl(meth)acrylate), a poly(2-ethyl hexyl(meth)acrylate), a poly(octyl(meth)acrylate), a poly(isooctyl(meth)acrylate), a poly(n-decyl(meth)acrylate), a poly(isodecyl(meth)acrylate), a poly(lauryl(meth)acrylate), a poly(hexadecyl(meth)acrylate), a poly(octadecyl(meth)acrylate), a poly(isobornyl(meth)acrylate), a poly(isobutylene), a polystyrene, a poly(divinyl benzene), a polyvinyl acetate, a polyisoprene, a polycarbonate, a polyacrylonitrile, a hydrophobic cellulose based polymer, a silicone resin, a poly(dimethyl siloxane), a poly(vinyl ether), and a polyester.
4. The light emitting device of claim 3 , wherein the first resin is a poly(lauryl(meth)acrylate).
5. The light emitting device of claim 1 , wherein the second resin is selected from the group consisting of an epoxy-based resin, a polyurethane-based resin, a hydrophilic (meth)acrylate, a polyvinyl alcohol, a poly(ethylene-co-vinyl alcohol), a polyvinyl dichloride, a silicone, a polyimide, a polyester, a polyvinyl, a polyamide, an enphenolic, a cyanoacrylate, gelatin, a sodium silicate, and poly(vinylpyrrolidone) (PVP).
6. The light emitting device of claim 5 , wherein the second resin is an epoxy-based resin, a polyurethane-based resin.
7. The light emitting device of claim 6 , wherein the polyurethane-based resin is a polyurethane acrylate resin.
8. The light emitting device of claim 6 , wherein the first resin is a poly(lauryl(meth)acrylate).
9. The light emitting device of claim 1 , wherein the quantum dots are InP/ZnS quantum dots.
10. The light emitting device of claim 1 , wherein at least one of the first resin and the second resin further comprises a light scattering agent dispersed therein.
11. The light emitting device of claim 1 , wherein at least one of the first resin and the second resin further comprises a chemical antioxidant dispersed therein.
12. The light emitting device of claim 1 , wherein a refractive index of the first resin and a refractive index of the second resin differ by less than about 5%.
13. The light emitting device of claim 12 , wherein the refractive index of the first resin and the refractive index of the second resin differ by less than about 5%.
14. The light emitting device of claim 1 , wherein the first resin further comprises a refractive index modifier dispersed therein.