Composition for improving softness of tissue and/or towel products
A composition for improving softness of tissue and/or towel products includes lignocellulosic fibers; water; and a hydrophobic softener that includes the reaction product of: (1) at least one di- and/or poly-amine, (2) at least one chain extender having at least two carboxyl groups; and (3) at least one hydrophobic end-capper. The reaction product comprises a hydrophobic substitution of at least about 25 mole percent of the hydrophobic end-capper based on a total number of moles of active amine sites of the reaction product. In addition, a method of improving softness of tissue and/or towel products includes combining the lignocellulosic fibers, the water, and the hydrophobic softener; and creating the tissue and/or towel products.
1 . A composition for improving softness of tissue and/or towel products, said composition comprising:
A. lignocellulosic fibers;
B. water; and
C. a hydrophobic softener comprising the reaction product of reactants consisting of:
(1) at least one di- and/or poly-amine;
(2) at least one chain extender having at least two carboxyl groups; and
(3) at least one hydrophobic end-capper chosen from a fatty acid, an ester of a fatty acid, a fatty acid chloride, a fatty alkyl halide, an epoxide of a hydrocarbon, a carboxylic acid anhydride of a hydrocarbon, and combinations thereof, any one or more of which has from 4 to about 40 carbon atoms, and
wherein the reaction product comprises a hydrophobic substitution of at least about 25 mole percent of the hydrophobic end-capper based on a total number of moles of active amine sites of the reaction product.
2 . The composition of claim 1 wherein the at one least di- and/or poly-amine is chosen from polyalkyleneamines, polyalkyleneimines, and combinations thereof.
3 . The composition of claim 1 wherein the at least one di- and/or poly-amine is chosen from diethylenetriamine (DETA), triethylenetetramine (TETA), tetraethylenepentamine (TEPA), pentaethylenehexamine (PEHA), dipropylenetriamine (DPTA), tripropylenetetramine (TPTA), tetrapropylenepentamine (TPPA), pentapropylenehexamine (PPHA), and dihexmethylenetriamine (DHMTA), methylbisaminopropylamine (MBAPA), hexamethylenediamine, and ethylenediamine and combinations thereof.
4 . The composition of claim 1 wherein the at least one di- and/or poly-amine is chosen from polyethylenepolyamines, polyalkylenepolyamines, and combinations thereof.
5 . The composition of claim 1 wherein the at least one di- and/or poly-amine is diethylenetriamine (DETA).
6 . The composition of claim 1 wherein the at least one chain extender is chosen from oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, azelaic acid, sebacic acid, dodecanedioic acid, C36 dimer acids, dimethyl glutarate, diesters thereof, and combinations thereof.
7 . The composition of claim 1 wherein the at least one chain extender is chosen from adipic acid, dimethyl glutarate, and combinations thereof.
8 . The composition of claim 1 wherein the at least one hydrophobic end-capper is the fatty acid having about 12 to about 20 carbon atoms.
9 . The composition of claim 8 wherein the fatty acid is chosen from caprylic acid, pelargonic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, linoleic acid, oleic acid, and combinations thereof.
10 . The composition of claim 8 wherein the fatty acid is chosen from stearic acid, oleic acid, and combinations thereof.
11 . The composition of claim 1 wherein (1), (2), and (3) are reacted in a molar ratio of about (1 to 3):about 1:about (0.9 to 4).
12 . The composition of claim 1 wherein the hydrophobic softener further comprises an imidazoline cyclization adduct of (1), (2), and (3).
13 . The composition of claim 1 that is free of a non-ionic surfactant.
14 . A method of improving softness of tissue and/or towel products, said method comprising the steps of:
A. providing lignocellulosic fibers;
B. providing water;
C. providing a hydrophobic softener;
D. combining the lignocellulosic fibers, the water, and the hydrophobic softener; and
E. creating the tissue and/or towel products using the combination of the lignocellulosic fibers, the water, and the hydrophobic softener;
wherein the hydrophobic softener comprises the reaction product of reactants consisting of:
(1) at least one di- and/or poly-amine;
(2) at least one chain extender having at least two carboxyl groups; and
(3) at least one hydrophobic end-capper chosen from a fatty acid, an ester of a fatty acid, a fatty acid chloride, a fatty alkyl halide, an epoxide of a hydrocarbon, a carboxylic acid anhydride of a hydrocarbon, and combinations thereof, any one or more of which has from 4 to about 40 carbon atoms, and
wherein the reaction product comprises a hydrophobic substitution of at least about 25 mole percent of the hydrophobic end-capper based on a total number of moles of active amine sites of the reaction product.
15 . The method of claim 14 wherein the step of combining is further defined as combining the water and the hydrophobic softener with the lignocellulosic fibers that are dispersed in process water.
16 . The method of claim 14 wherein the step of combining is further defined as spraying the water and the hydrophobic softener onto the lignocellulosic fibers.
17 . The method of claim 16 wherein the lignocellulosic fibers are in the form of a wet-web of fibers.
18 . The method of claim 16 wherein the lignocellulosic fibers are disposed on a drier.
19 . The method of claim 14 wherein the hydrophobic softener further comprises an imidazoline cyclization adduct.
20 . A method of improving softness of tissue and/or towel products, said method comprising the steps of:
A. providing lignocellulosic fibers;
B. providing water;
C. providing a hydrophobic softener;
D. combining the lignocellulosic fibers, the water, and the hydrophobic softener; and
E. creating the tissue and/or towel products using the combination of the lignocellulosic fibers, the water, and the hydrophobic softener;
wherein the hydrophobic softener comprises the reaction product of reactants consisting of:
(1) at least one di- and/or poly-amine;
(2) at least one chain extender having at least two carboxyl groups; and
(3) at least one hydrophobic end-capper chosen from a fatty acid, an ester of a fatty acid, a fatty acid chloride, a fatty alkyl halide, an epoxide of a hydrocarbon, a carboxylic acid anhydride of a hydrocarbon, and combinations thereof, any one or more of which has from 4 to about 40 carbon atoms,
wherein the reaction product comprises a hydrophobic substitution of at least about 25 mole percent of the hydrophobic end-capper based on a total number of moles of active amine sites of the reaction product, and
wherein the hydrophobic softener further comprises an imidazoline cyclization adduct that is present in an amount of about 5 to about 95 mol % based on a total number of moles of the reaction product.