Luminescent nanoparticles and method for preparing same
View Patent ↗Proposed are luminescent nanoparticles and a method of preparing the same. The luminescent nanoparticles include a core-shell composite and a polymer brush grafted on the surface of the composite, in which the composite is composed of a core containing porous silica nanoparticles and CsPbX 3 (X is a halogen) perovskite nanocrystal supported in the porous silica nanoparticles and a lead-containing silicate shell formed on the surface of the core.
1 . A luminescent nanoparticle comprising a composite and a polymer brush grafted on a surface of the composite, the composite comprising:
a core containing a porous silica nanoparticle, a CsPbX 3 perovskite nanocrystal supported in the porous silica nanoparticle and a lead-containing silicate shell formed on a surface of the core, wherein X is a halogen.
2 . The luminescent nanoparticle of claim 1 , wherein the porous silica nanoparticles have a size in a range of 100 to 500 nm and an average pore diameter in a range of 1 to 10 nm.
3 . The luminescent nanoparticle of claim 1 , wherein the polymer brush comprises an acrylic polymer prepared by an atom transfer radical polymerization (ATRP) reaction.
4 . The luminescent nanoparticle of claim 1 , wherein the halogen X is any one or a mixture of two or more selected from the group consisting of Br, Cl, and I.
5 . A method of preparing luminescent nanoparticles, the method comprising:
a) mixing and pulverizing porous silica nanoparticles, CsX, and PbX 2 , wherein X is a halogen;
b) calcining a pulverized mixture to prepare a composite;
c) modifying a surface of the composite with a halogen group-containing silane compound; and
d) grafting a polymer brush on the surface-modified composite, wherein the composite comprises: a core containing porous silica nanoparticles, and CsPbX 3 perovskite nanocrystals supported in the porous silica nanoparticles; and a lead-containing silicate shell formed on a surface of the core, wherein X is a halogen.
6 . The method of claim 5 , wherein the calcining is performed in a range of 300° C. to 1000° C.
7 . The method of claim 6 , wherein the calcining is performed for 1 to 10 hours.
8 . The method of claim 5 , wherein the halogen group-containing silane compound is any one or a mixture of two or more selected from the group consisting of 3-(2-bromoisobutyloxy)propyldimethylchlorosilane, 3-(2-bromoisobutyloxy)propyldichloromethylsilane, 3-(2-bromoisobutyloxy)propyltrichlorosilane, 3-(methoxydimethylsilylpropyl)-2-bromo-2-methylpropionate, 3-(dimethoxymethylsilylpropyl)-2-bromo-2-methylpropionate, 3-(trimethoxysilylpropyl)-2-bromo-2-methylpropionate, (3-(2-bromoisobutyryl)propyl)dimethylethoxysilane, (3-(2-bromoisobutyryl)propyl)methyldiethoxysilane, (3-(2-bromoisobutyryl)propyl)triethoxysilane, (3-(2-bromopropionyl) propyl)dimethylchlorosilane, (3-(2-bromopropionyl)propyl)trichlorosilane, (3-(2-bromopropionyl)propyl)dimethylmethoxysilane, (3-(2-bromopropionyl)propyl)dimethylethoxysilane, and (3-(2-bromopropionyl)propyl)triethoxysilane.
9 . The method of claim 5 , wherein the polymer brush is prepared by an atom transfer radical polymerization (ATRP) reaction.
10 . The method of claim 9 , wherein the grafting is performed by reacting a modified composite, an acrylic monomer, a metal catalyst, and a ligand.
11 . The method of claim 5 , wherein a weight ratio of the porous silica nanoparticles to CsX and PbX 2 is in a range of 1:0.1 to 1:10.
12 . The method of claim 5 , wherein a molar ratio of CsX to PbX 2 is in a range of 1 to 10:1.
13 . The method of claim 5 , wherein the porous silica nanoparticles have a size in a range of 100 to 500 nm and an average pore diameter in a range of 1 to 10 nm.